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公开(公告)号：US20230026153A1
公开(公告)日：2023-01-26
申请号：US17838063
申请日：2022-06-10
申请人： UOP LLC
发明人： Xi Zhao , Avram M. Buchbinder , J.W. Adriaan Sachtler , Wei Pan , John A. Karch
摘要： A de-hydrogenation catalyst and its use in dehydrogenation of hydrocarbons. The catalyst has low cracking activity and comprises gallium or gallium and platinum on an essentially non-acidic and amorphous alumina-phosphate or silica-alumina-phosphate support with an empirical chemical composition of [Al2O3][SiO2]Y[P2O5]Z, wherein Y is between 0 and 0.2 and Z is between 0.01 and 1.1, with a BET surface area above 50 m2/g, as measured by N2 adsorption experiment.
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公开(公告)号：US11384293B2
公开(公告)日：2022-07-12
申请号：US16807880
申请日：2020-03-03
申请人： SUNCOR ENERGY INC.
发明人： Tom Corscadden , Darius Ramesat , Frank David Guffey , Shunlan Liu , Greg Diduch
摘要： A process that catalytically converts olefinic (Alkenes, typically liquid at standard temperature and pressure) material in thermally cracked streams to meet olefin content specifications for crude oil transport pipelines. A thermally cracked stream or portion of a thermally cracked stream is selectively reacted to reduce the olefin content within a reactor operating at specific, controlled conditions in the presence of a catalyst and the absence of supplemental hydrogen. The process catalyst is comprised of a blend of select catalyzing metals supported on an alumina, silica or shape selective zeolite substrate together with appropriate pore acidic components.
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公开(公告)号：US11236262B2
公开(公告)日：2022-02-01
申请号：US16708567
申请日：2019-12-10
发明人： Stephen D. Matza , Martha T. Smith , Jack G. Frost
摘要： A method and system remove hydrogen sulfide from a sour liquid. In an embodiment, the method for removing hydrogen sulfide from a hydrocarbon containing fluid includes contacting a methylmorpholine-N-oxide solution with the sour liquid. The method also includes allowing the methylmorpholine-N-oxide to react with the hydrogen sulfide to remove the hydrogen sulfide.
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公开(公告)号：US20210040400A1
公开(公告)日：2021-02-11
申请号：US17080209
申请日：2020-10-26
申请人： GAPS TECHNOLOGY, LLC
发明人： Cliffton Lee ROE , Linda SCHWEITZER
摘要： A treatment composition for remediating for remediating H2S and other contaminant(s) in contaminated liquids, comprising: 0.1-10.0 weight % collectively of at least one hydroxide compound; 0.01-3.0 weight % collectively of at least one organic acid selected from a group consisting of fulvic acid and humic acid; 0.01-10.0 wt % of a chelating agent; and at least 75% weight of water.
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公开(公告)号：US10550337B2
公开(公告)日：2020-02-04
申请号：US16254089
申请日：2019-01-22
申请人： GAPS TECHNOLOGY, LLC
发明人： Cliffton Lee Roe , Linda Schweitzer
IPC分类号： C02F1/50 , C02F1/66 , C10G19/02 , C10G29/02 , C10G29/04 , C10G29/20 , C10G53/12 , C02F103/36 , C02F101/10 , C02F103/18 , C02F103/10
摘要： A treatment process for remediating a contaminated liquid containing more than 5 ppm hydrogen sulfide (H2S) and substantially without formation of precipitate, includes steps of steps of adding an aqueous solution containing at least one hydroxide compound at a collective concentration of 35-55 wt % to the contaminated liquid to achieve a concentration of 125-5000 ppm of the hydroxide compounds in the contaminated liquid, adding at least one organic acid and to the liquid to achieve a concentration of 0.01-10 ppm in the contaminated liquid, and dispersing the aqueous solution and the at least one organic acid in the contaminated liquid and allowing the aqueous solution and the at least one organic acid to react with the contaminated liquid for a period of time until a concentration of hydrogen sulfide in the contaminated liquid is reduced to ≤5 ppm.
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公开(公告)号：US10519386B2
公开(公告)日：2019-12-31
申请号：US15527110
申请日：2016-05-24
发明人： Ashok V Joshi
IPC分类号： C10G32/02 , C10G29/04 , C25C3/02 , C25C3/04 , C10G21/28 , C10G25/00 , C10G25/12 , C10G21/06 , C10G21/08
摘要： Applying a sufficient quantity of an Alkali metal or an Alkaline earth metal to a fluid in a stripping process loop 106 to form a first intermediary compound and thereby, to strip the undesired element from the process fluid 102. The first intermediary compound 130 is processed in a recovery process loop 110 to recover the Alkali metal or Alkaline earth metal. The recovered Alkali metal or Alkaline earth metal is then re-introduced to an additional quantity of process fluid to strip and clean the undesired element from the additional quantity of the process fluid. A recovery process loop 110 may include either or both of a chemical substitution process, and an electrolytic process, effective to separate the Alkali metal or Alkaline earth metal from the undesired element or another compound.
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公开(公告)号：US10160921B2
公开(公告)日：2018-12-25
申请号：US15901550
申请日：2018-02-21
发明人： Jan Dierickx
摘要： A system for removing oxygenates from a hydrocarbon stream includes a caustic wash unit comprising a plurality of caustic wash loops, and a hydrogenation reactor. The hydrogenation reactor is configured to receive a first gaseous stream from a first caustic wash loop of the plurality of caustic wash loops and pass a second gaseous stream from the hydrogenation reactor to a second caustic wash loop of the plurality of caustic wash loops, wherein the hydrogenation reactor comprises a sulfided catalyst.
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公开(公告)号：US09926498B2
公开(公告)日：2018-03-27
申请号：US15164576
申请日：2016-05-25
发明人： Jan Dierickx
CPC分类号： C10G55/06 , B01D53/1462 , B01J8/18 , C10G29/04 , C10G70/02 , C10G2300/202 , C10G2300/207
摘要： A method of removing oxygenates from a hydrocarbon stream comprises passing a hydrocarbon stream to a caustic tower having a plurality of loops, contacting the hydrocarbon stream with a sulfided catalyst between a first loop of the plurality of loops and a second loop of the plurality of loops to produce a reaction product, passing the reaction product to the second loop, removing at least a portion of the hydrogen sulfide in the second loop of the caustic tower to produce a product stream, and separating the product stream into a plurality of hydrocarbon streams in a separation zone located downstream of the caustic tower. The hydrocarbon stream comprises hydrocarbons, oxygen containing components, and sulfur containing compounds. At least a portion of the sulfur compounds react in the presence of the sulfided catalyst to produce hydrogen sulfide in the reaction product.
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9.发明授权公开(公告)号：US09555396B2
公开(公告)日：2017-01-31
申请号：US13558081
申请日：2012-07-25
IPC分类号： C07C7/148 , B01J23/06 , C10G29/04 , C10G29/16 , B01J37/06 , B01J23/00 , B01J21/04 , B01J37/08
摘要： The process provided herein is concerned with disposal of oxidized sulfur compounds formed by oxidative desulfurization. The process uses solid base catalyst in the presence of a caustic solution or solid base catalyst pretreated with a base and eliminates the need to separate the sulfones from the hydrocarbon streams and recover the hydrocarbons.
摘要翻译： 本文提供的方法涉及通过氧化脱硫形成的氧化硫化合物的处理。 该方法在用碱处理的苛性碱溶液或固体碱催化剂存在下使用固体碱催化剂，并且不需要将烃与烃流分离并回收烃。
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公开(公告)号：US20160369176A9
公开(公告)日：2016-12-22
申请号：US13770610
申请日：2013-02-19
发明人： John Howard Gordon
IPC分类号： C10G29/04
CPC分类号： C10G29/04 , C10G75/02 , C10G2300/203
摘要： Corrosion of ferrous material such as steel or stainless steel is a problem in oil pipelines, oil storage tanks, and the piping and process equipment at oil refineries, and this corrosion may be reduced by reducing the TAN value of the oil feedstock that is used/transported within the ferrous material. This TAN value may be reduced by reacting the oil feedstock with an alkali metal, thereby forming a de-acidified alkali metal. The de-acidified alkali metal has a TAN value of less than or equal to 1 mgKOH/g.
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