摘要:
This invention provides processes and systems for converting biomass into high-carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.
摘要:
A method is provided for the production of titanium-aluminum-vanadium alloy products directly from a variety of titanium and vanadium bearing ores that reduces the processing steps significantly as compared to current Ti—Al—V alloy production methods.
摘要:
This invention provides processes and systems for converting biomass into high-carbon biogenic reagents that are suitable for a variety of commercial applications. Some embodiments employ pyrolysis in the presence of an inert gas to generate hot pyrolyzed solids, condensable vapors, and non-condensable gases, followed by separation of vapors and gases, and cooling of the hot pyrolyzed solids in the presence of the inert gas. Additives may be introduced during processing or combined with the reagent, or both. The biogenic reagent may include at least 70 wt %, 80 wt %, 90 wt %, 95 wt %, or more total carbon on a dry basis. The biogenic reagent may have an energy content of at least 12,000 Btu/lb, 13,000 Btu/lb, 14,000 Btu/lb, or 14,500 Btu/lb on a dry basis. The biogenic reagent may be formed into fine powders, or structural objects. The structural objects may have a structure and/or strength that derive from the feedstock, heat rate, and additives.
摘要:
In one aspect, the present invention is directed to methods and apparatuses for recovering target metals from scrap. In some embodiments, the methods comprise dissolving a portion of a mixed metal scrap into a molten salt to form a molten salt and metal mixture, the scrap including a target metal species and at least one contaminant metal species; bubbling a gas through the molten salt and metal mixture to form a gas and metal vapor mixture comprising target metal vapors; and condensing at least a portion of the target metal vapors. In some embodiments, the apparatuses comprise a housing; a divider at least partially disposed within the housing, the divider forming at least a first chamber, a second chamber, and a fluid conduit between the first and second chambers; a top wall cooperating with a lower housing wall and at least one of the plurality of side walls to enclose the second chamber; a plurality of gas inlets disposed in the second chamber; and a gas outlet in fluid communication with the second chamber.
摘要:
Apparatus, systems and methods for carbothermically producing aluminum are disclosed. The systems may include a reactor and an electrical supply. The reactor may include a plurality of side-entering electrodes and a top-entering electrode. The electrical supply may be operable to supply multiphase current to the side-entering electrodes and/or the top-entering electrodes. The electrodes may be in communication with a molten bath of the reactor, and the multiphase current supplied thereto may be passed through the bath to heat the reactor. The amount of current supplied to various electrode sets may be adjusted to facilitate tailored heating of the molten bath.
摘要:
A mass of solid aluminium carbide containing product is produced by injecting particulate alumina into a bath (30) of molten aluminium metal; and injecting carbonaceous material, consisting of, containing or yielding carbon, into the bath (30). The bath (30) of molten aluminium metal is maintained at a superheated temperature to heat and react carbon with molten aluminium to produce solid aluminium carbide which mixes with alumina to form a mass (36) containing entrapped gas and entrapped molten aluminium metal and having a bulk or apparent density less than aluminium. The mass is allowed to accumulate as a mass of solid aluminium carbide containing product on the upper surface of the bath. The carbonaceous material is a hydrocarbon material or is produced by pyrolysis, decomposition or cracking of a hydrocarbon material.
摘要:
One aspect of the invention is a method for incorporating carbon homogeneously into aluminum materials. The first step is to apply a positive charge to molten aluminum. Next, a negative charge is applied to an organic compound. Under an inert atmosphere, the negatively charged organic compound is mixed with the positively charged molten aluminum while running electric current therethrough. An aluminum material with carbon homogeneously dispersed throughout is recovered.
摘要:
A graphite electrode for an electrothermic reduction furnace in which aluminum is produced by carbothermic reduction of alumina is rendered substantially gas-impermeable. The graphite electrode is consumed during furnace operation and electrode columns connected by graphite pins are fed continuously fed in from the top into the furnace. The coating of the electrode withstands a temperature of up to 300° C. and more over a period of several hours without oxidation. Since the coating enters the furnace compartment at least partially, it is configured so that it will not contaminate the hot melt. That is, the chemistry of the coating materials is similar to 1o the ingredients of the overall reaction or, at a minimum, the amount of foreign elements is very low. The coating is provided so that it does not increase the electrical contact resistance at the connection between the electrode columns and the electrode holding clamps. Where the electrode inlet area is cooled by water, the coating is insoluble in water.
摘要:
A process for electrochemically reducing a metal oxide, such as titania, in a solid state in an electrochemical cell that includes a bath of molten electrolyte, a cathode, and an anode, which process includes the steps of: a) applying a cell potential across the anode and the cathode that is capable of electrochemically reducing the metal oxide supplied to the molten electrolyte bath, b) continuously or semi-continuously feeding the metal oxide in powder and/or pellet form into the molten electrolyte bath, c) transporting the powders and/or pellets along a path within the molten electrolyte bath and reducing the metal oxide as the metal oxide powders and/or pellets move along the path, and d) continuously or semi-continuously removing metal from the molten electrolyte bath. Also disclosed and claims is an electrochemical cell for carrying out this process.
摘要:
In a process for the production of aluminium a molten alumina slag, containing combined carbon is circulated through one or more alternately arranged relatively low temperature zones where carbon is added to increase the combined carbon content of the slag by reaction with the alumina slag and high temperature zones where aluminium metal is released by reaction of aluminium carbide and alumina in the slag with consequent depletion of the combined carbon content. Alumina is supplied to the slag at one or more locations. The energy to drive the reactions is preferably supplied by resistance heating of the slag particularly in transit from a low temperature zone to a high temperature zone although usually additional energy is supplied to the slag in the return from a high temperature zone to the next low temperature zone.In most instances the aluminium-liberating reaction is carried out in an upwardly inclined passage and the gas evolved is employed to achieve the circulatory movement of the slag. It is a preferred feature to scrub the gas with carbon without admixed alumina to avoid formation of sticky aluminium oxycarbide in the carbon, which is subsequently added as process charge.