公开(公告)号：US20030148152A1

公开(公告)日：2003-08-07

申请号：US10239557

申请日：2003-02-03

发明人： Patrick John Morrisey

IPC分类号： H01M008/18 ,  H01M008/20

CPC分类号： H01M8/188 ,  Y02E60/528 ,  Y02P70/56

摘要： A method of operating a regenerative fuel cell which comprises two half-cells separated by a cation-exchange membrane, there being a halogen/halide electrolyte in one half of the cell, a sulfide/polysulfide in the other half of the cell and cations in both halves of the cell which act as charge carriers therebetween, wherein the state of charge of the sulfide/polysulfide electrolyte is in the range of from 1.8 to 2.5 for at least a part of the charge/discharge cycle over a plurality of cycles.

摘要翻译： 一种再生式燃料电池的运行方法，包括由阳离子交换膜隔开的两个半电池，一半电池中存在卤素/卤化物电解质，另一半电池中存在硫化物/多硫化物，阳离子在 作为其间的电荷载流子的电池的两半，其中硫化物/多硫化物电解质的电荷在多个循环中的至少一部分充电/放电循环的1.8至2.5的范围内。

公开(公告)号：US20030143456A1

公开(公告)日：2003-07-31

申请号：US10226751

申请日：2002-08-22

发明人： Michael Kazacos ,  Maria Skyllas Kazacos

IPC分类号： H01M008/20

CPC分类号： B60L11/1879 ,  B60L11/1822 ,  B60L2240/545 ,  H01M8/188 ,  H01M8/20 ,  H01M10/36 ,  Y02E60/528 ,  Y02P70/56 ,  Y02T10/7005 ,  Y02T10/705 ,  Y02T10/7072 ,  Y02T90/124 ,  Y02T90/14

摘要： Disclosed is a method for preparing a high energy density (HED) electrolyte solution for use in an all-vanadium redox cell, a high energy density electrolyte solution, in particular an all-vanadium high energy density electrolyte solution, a redox cell, in particular an all-vanadium redox cell, comprising the high energy density electrolyte solution, a redox battery, in particular an all-vanadium redox battery, comprising the HED electrolyte solution, a process for recharging a discharged or partially discharged redox battery, in particular an all-vanadium redox battery, comprising the HED electrolyte solution, a process for the production of electricity from a charged redox battery, and in particular a charged all-vanadium redox battery, comprising the HED electrolyte, a redox battery/fuel cell and a process for the production of electricity from a redox battery/fuel cell. A method for stabilising an electrolyte solution for use in a redox cell, in particular for stabilising an electrolyte solution for use in an all-vanadium redox cell, a stabilised electrolyte solution, in particular an all-vanadium stabilised electrolyte solution, a redox cell, in particular an all-vanadium redox cell, comprising the stabilised electrolyte solution, a redox battery, in particular an all-vanadium redox battery, comprising the stabilised electrolyte solution, a process for recharging a discharged or partially discharged redox battery, in particular an all-vanadium redox battery, comprising the stabilised electrolyte solution, and a process for the production of electricity from a charged redox battery, and in particular a charged all-vanadium redox battery, comprising the stabilised electrolyte solution are disclosed. Also disclosed are a redox battery/fuel cell and a process for the production of electricity from a redox battery/fuel cell.

公开(公告)号：US20020112968A1

公开(公告)日：2002-08-22

申请号：US09873202

申请日：2001-06-05

申请人： CHIYODA CORPORATION

发明人： Yoshimi Shiroto ,  Ataru Wakabayashi

IPC分类号： H01M008/20 ,  C01G031/00 ,  C01G033/00 ,  C22B034/20 ,  C25B001/00

CPC分类号： H01M8/188 ,  C01G31/00 ,  C22B3/08 ,  C22B7/001 ,  C22B7/007 ,  C22B34/225 ,  H01M4/5825 ,  Y02E60/528 ,  Y02P10/214 ,  Y02P10/23 ,  Y02P10/234 ,  Y02P20/129 ,  Y02P70/56

摘要： A process for the production of a vanadium compound from carbonaceous residues containing vanadium, which includes the steps of: (a) combusting the carbonaceous residues at a temperature of 500-690null C. in an oxygen-containing gas to form vanadium-containing combustion residues; (b) heating the vanadium-containing combustion residues at a temperature T in null C. under an oxygen partial pressure of at most T in kPa wherein T and P meet with the following conditions: log10(P)nullnull3.45null10null3nullTnull2.21 500nullTnull1300 to obtain a solid product containing less than 5% by weight of carbon and vanadium at least 80% of which is tetravalent vanadium oxide; (c) selectively leach tetravalent vanadium ion with sulfuring acid at pH in the range of 1.5-4; (d) separating a liquid phase from the leached mixture; (e) adding an alkaline substance to the liquid phase to adjust the pH thereof in the range of 4.5-7.5 and to selectively precipitate vanadium ion as a tetravalent vanadium compound; and (f) separating the precipitates.

摘要翻译： 一种从含有钒的碳质残渣中生产钒化合物的方法，其包括以下步骤：（a）在含氧气体中在500-690℃的温度下将含碳残余物燃烧以形成含钒燃烧 残留物 （b）在温度T℃下，在最高T（kPa）的氧分压下加热含钒燃烧残余物，其中T和P满足以下条件：<段落lv1 =“0”> < line-formula> log10（P）= - 3.45x10-3xT + 2.21 <段落lvl =“0”> 500 <= T <= 1300 得到含有小于5重量％的碳和钒的固体产物，其中至少80％是四价钒氧化物; （c）在pH为1.5-4的范围内用硫酸选择性浸出四价钒离子; （d）从浸出的混合物中分离液相; （e）向液相中加入碱性物质以将pH调节至4.5-7.5的范围内，并选择性地沉淀作为四价钒化合物的钒离子; 和（f）分离沉淀物。

公开(公告)号：US20040202915A1

公开(公告)日：2004-10-14

申请号：US10480116

申请日：2004-05-03

发明人： Hiroyuki Nakaishi ,  Takashi Kanno ,  Seiji Ogino ,  Takefumi Ito ,  Toshio Shigematsu ,  Nobuyuki Tokuda

IPC分类号： H01M008/02 ,  H01M008/20

CPC分类号： H01M8/0213 ,  H01M8/0221 ,  H01M8/0226 ,  H01M8/0273 ,  H01M8/188 ,  Y02E60/528

摘要： A cell frame for a redox-flow cell excellent in sealability between a frame member and a dipole sheet and a redox-flow cell having it are disclosed. The cell frame is composed of a dipole sheet (9) and a frame member (2A) attached to the periphery of the dipole sheet (9). The frame member (2A) contains 50 mass % or more of vinyl chloride. The dipole sheet is made of a conductive plastic containing 40-90 mass % of graphite and 10-60 mass % of a chlorinated organic compound. Chloride.

摘要翻译： 公开了一种用于框架构件和偶极片之间的密封性优异的氧化还原液流池的电池框和具有它的氧化还原流通池。 电池框架由偶极片（9）和附接到偶极子片（9）的周边的框架构件（2A）组成。 框架部件（2A）含有50质量％以上的氯乙烯。 偶极片由含有40-90质量％石墨和10-60质量％氯化有机化合物的导电塑料制成。 氯化物。

公开(公告)号：US20040170893A1

公开(公告)日：2004-09-02

申请号：US10480117

申请日：2004-04-15

发明人： Hiroyuki Nakaishi ,  Takashi Kanno ,  Seiji Ogino ,  Takefumi Ito ,  Toshio Shigematsu ,  Nobuyuki Tokuda

IPC分类号： H01M002/08 ,  H01M008/20

CPC分类号： H01M8/0278 ,  H01M8/0273 ,  H01M8/0289 ,  H01M8/188 ,  Y02E60/528

摘要： This invention provides a cell frame for a redox flow battery that prevents leakage of electrolyte out of the cell frame and also provides a good workability in assembling the redox flow battery. Also, this invention provides a redox flow battery using the cell frame. In the cell frame 30 for the redox flow battery 30 comprising a bipolar plate 21 and a frame 31 fitted around a periphery of the bipolar plate 21, the frame 31 has, on each side thereof, an inner seal and an outer seal to press-contact with a membrane and also seal electrolyte. The frame 31 has, on each side thereof, an inner seal groove 34 and an outer seal groove 35 for placing therein the inner seal and the outer seal, respectively, to prevent the electrolyte from leaking out, and O-rings are placed in the respective seal grooves.

摘要翻译： 本发明提供了一种用于氧化还原液流电池的电池框架，其防止电解液从电池框架中泄漏出来并且还提供了组装氧化还原液流电池的良好可操作性。 此外，本发明提供了使用电池框架的氧化还原液流电池。 在用于包括双极板21的氧化还原液流电池30的电池框架30和围绕双极板21的周边装配的框架31之间，框架31的每一侧均具有内密封件和外部密封件， 与膜接触并密封电解液。 框架31的每侧均具有用于分别在其中放置内密封件和外密封件的内密封槽34和外密封槽35，以防止电解液泄漏，并且O形环被放置在 各自的密封槽。

公开(公告)号：US20030096150A1

公开(公告)日：2003-05-22

申请号：US09989540

申请日：2001-11-21

申请人： The Boeing Company

发明人： Robert R. Rice ,  Jan Vetrovec

IPC分类号： H01M008/02 ,  H01M008/20

CPC分类号： H01M8/2455 ,  H01M8/1004 ,  H01M8/1009 ,  H01M8/1016

摘要： A fuel cell device for generation of electricity from a polar oxidizer liquid and a non-polar fuel fluid includes a cathode in contact with the polar oxidizer liquid; an anode in contact with the non-polar fuel fluid; and a separator for separating the polar oxidizer liquid from the non-polar fuel fluid. The separator is made from material that is lyophobic with respect to the oxidizer liquid, and has a plurality of apertures, which are appropriately sized and spaced to form a meniscus in each aperture. The meniscus forms a liquid heterointerface between the conductive polar oxidizer liquid and the non-polar fuel fluid providing a controlled contact surface for oxidation processes. The fuel side of the separator may be coated with a conductive material to form the anode, in electric contact with the perimeter of the meniscus, and the cathode may be formed on the oxidizer side of the separator.

摘要翻译： 用于从极性氧化剂液体和非极性燃料流体产生电力的燃料电池装置包括与极性氧化剂液体接触的阴极; 与非极性燃料流体接触的阳极; 以及用于将极性氧化剂液体与非极性燃料流体分离的分离器。 分离器由相对于氧化剂液体疏液的材料制成，并且具有多个孔，其适当尺寸和间隔以在每个孔中形成弯液面。 弯液面在导电极性氧化剂液体和非极性燃料流体之间形成液体异质界面，提供用于氧化过程的受控接触表面。 分隔器的燃料侧可以用导电材料涂覆以形成阳极，与弯液面的周边电接触，并且阴极可以形成在隔板的氧化剂侧上。

公开(公告)号：US20040234843A1

公开(公告)日：2004-11-25

申请号：US10487135

申请日：2004-07-13

发明人： Maria Skyllas-Kazacos

IPC分类号： H01M008/20 ,  H01M010/44

CPC分类号： H01M8/04186 ,  B60L50/64 ,  B60L2240/545 ,  H01M8/188 ,  H01M2300/0085 ,  Y02E60/528 ,  Y02T10/7005 ,  Y02T10/705

摘要： The invention relates to a redox flow cell containing a polyhalide/halide redox couple in the positive half-cell electrolyte and a V(III)/V(II) redox couple in the negative half-cell electrolyte. The invention also relates to a method of producing electricity by discharging the fully charged or partially charged redox flow cell, and a method of charging the discharged or partially discharged redox flow cell.

摘要翻译： 本发明涉及在正半电池电解质中含有多卤化物/卤化物氧化还原对的氧化还原流动电池和负半电池电解质中的V（III）/ V（II）氧化还原对。 本发明还涉及通过对完全充电的或部分充电的氧化还原液流池进行放电来产生电力的方法，以及对排出的或部分排出的氧化还原液流池进行充电的方法。

公开(公告)号：US20040151977A1

公开(公告)日：2004-08-05

申请号：US10475139

申请日：2003-10-17

发明人： Patrick John Morrisey ,  Norman John Ward

IPC分类号： H01M002/38 ,  H01M008/20

CPC分类号： H01M8/188 ,  H01M8/04186 ,  Y02E60/528

摘要： The present invention relates to a process for operating a regenerative fuel cell (RFC). The process involves circulating a first electrolyte (electrolyte 1) through the negative chamber of the cell and a second electrolyte (electrolyte 2) through the positive chamber of the cell. Electrolyte (1) contains sulfide during the discharge cycle of the cell. Electrolyte (2) contains bromine during the discharge cycle of the cell. Decreases in ph in the electrolyte are compensated by circulating a fraction of other electrolyte (1) or (2) through the positive chamber of an auxiliary cell. A fraction of electrolyte (2), which has been made free of bromine, is circulated in the negative chamber of the auxiliary cell.

摘要翻译： 本发明涉及一种用于操作再生燃料电池（RFC）的方法。 该方法包括使第一电解质（电解质1）循环通过电池的负室和通过电池的正室的第二电解质（电解质2）。 电解液（1）在电池的放电循环期间含有硫化物。 电解液（2）在电池放电循环中含有溴。 通过使一部分其他电解质（1）或（2）通过辅助电池的正室循环来补偿电解液中ph的减少。 已经不含溴的电解质（2）的一部分在辅助电池的负室中循环。

公开(公告)号：US20030228514A1

公开(公告)日：2003-12-11

申请号：US10170716

申请日：2002-06-14

申请人： Sunyen Co., Ltd.

发明人： Yu-Ta Tu ,  Show-Jong Yeh

IPC分类号： H01M008/20

CPC分类号： H01M8/20 ,  H01M4/44 ,  H01M4/661 ,  H01M10/26 ,  H01M10/36 ,  H01M2300/0011 ,  H01M2300/0014 ,  Y02E60/528 ,  Y02P70/56

摘要： In a secondary cell which generates a direct current when the positive electrode complex and the negative electrode complex thereof conduct a reversible redox reaction in the presence of an electrolyte, the positive electrode complex and the negative electrode complex are in a combination (represented by positive electrode complex/negative electrode complex) selected from the group consisting of lead/chromium complex, chromium complex/aluminum complex, and manganese complex/zinc complex. The secondary cell has relatively high capacitance and can be manufactured at low cost. Moreover, it provides more stable chemical reactions and can therefore be stably charged/discharged with large current and without risk of explosion.

摘要翻译： 在正电极复合体和负极络合物在电解质存在下进行可逆的氧化还原反应时，在产生直流电的二次电池中，正极复合体和负极复合体组合（由正极 复合/负极复合物），选自铅/铬络合物，铬络合物/铝络合物和锰络合物/锌络合物。 二次电池具有相对高的电容并且可以以低成本制造。 此外，它提供更稳定的化学反应，因此可以以大电流稳定地充放电，没有爆炸的危险。

公开(公告)号：US20030143443A1

公开(公告)日：2003-07-31

申请号：US10059693

申请日：2002-01-28

发明人： Joseph W. Tsang ,  Ravi Prasad

IPC分类号： H01M004/90 ,  H01M008/20

CPC分类号： H01M4/90 ,  H01M4/8605 ,  H01M4/92 ,  H01M8/065 ,  H01M8/1004

摘要： Two co-catalysts selected from the transitional metals can be employed in proton exchange membrane fuel cells to catalyze a borohydride anolyte, such that diatomic hydrogen produced on the surface of a particle of a first catalyst is diffused to an adjacent surface of a particle of a second catalyst. At the second catalyst the diatomic hydrogen is catalyzed to produce hydrogen ions, which are employed as the mobile ion transported across the electrolyte concurrent with the generation of electrical current. The apparatus operates without the accumulation of hydrogen gas, except as adhered to the surface of the two catalysts.

摘要翻译： 选择过渡金属的两种助催化剂可用于质子交换膜燃料电池中以催化硼氢化物阳极电解液，使得在第一催化剂的颗粒表面产生的双原子氢扩散到颗粒的相邻表面 第二催化剂。 在第二催化剂中，双原子氢被催化以产生氢离子，其被用作与产生电流同时运送到电解质上的可移动离子。 除了附着在两种催化剂的表面之外，该装置不会积聚氢气。