METAL-SEMICONDUCTOR HYBRID STRUCTURES, SYNTHESES THEREOF, AND USES THEREOF

    公开(公告)号:US20220410130A1

    公开(公告)日:2022-12-29

    申请号:US17899535

    申请日:2022-08-30

    摘要: Aspects of the present disclosure generally relate to semiconductor nanoparticles, metal-semiconductor hybrid structures, processes for producing semiconductor nanoparticles, processes for producing metal-semiconductor hybrid structures, and processes for producing conversion products. In an aspect is provided a process for producing a metal-semiconductor hybrid structure that includes introducing a first precursor comprising a metal from Group 11-Group 14 to an amine and an anion precursor to form a semiconductor nanoparticle comprising the Group 11-Group 14 metal; introducing a second precursor comprising a metal from Group 7-Group 11 to the semiconductor nanoparticle to form a metal-semiconductor mixture; and introducing the metal-semiconductor mixture to separation conditions to produce the metal-semiconductor hybrid structure. In another aspect is provided a metal-semiconductor hybrid structure that includes a first component comprising a metal from Group 11-Group 14 and an element from Group 15-Group 16; and a second component comprising a metal from Group 7-Group 11.

    POLYIONIC NANOCLAYS
    4.
    发明申请

    公开(公告)号:US20220305472A1

    公开(公告)日:2022-09-29

    申请号:US17656383

    申请日:2022-03-24

    摘要: Disclosed herein are organic-inorganic hybrid materials, in particular polyionic nanoclays, along with methods of making and using the same. The functionalized organic-inorganic hybrid materials are preferably of a phyllosilicate structure and comprise an octahedral ionic layer sandwiched between two tetrahedral layers, one or more charged chemical moieties covalently bonded to the tetrahedral layers, and optionally one or more counterions or functional groups associated with the hybrid materials. Methods of producing the same, by contacting a silane with a nucleophile and hydrolyzing the product thereof in the presence of a metal salt, are also provided.