公开(公告)号：US20230025624A1

公开(公告)日：2023-01-26

申请号：US17776824

申请日：2020-11-12

申请人： thyssenkrupp Industrial Solutions AG ,  thyssenkrupp AG

发明人： Nicolai ANTWEILER ,  Karsten BUEKER

IPC分类号： C01B3/28 ,  C09C1/50 ,  B01J6/00

摘要： A process for producing hydrogen and pyrolytic carbon from hydrocarbons may involve converting hydrocarbons into hydrogen and carbon in a reactor at temperatures of 1000° C. or more. The reactor may include two electrodes spaced apart from one another in a flow direction of the hydrocarbons. In a region of the reactor between the electrodes an inert gas component is supplied over an entire reactor cross section. The reactor contains carbon particles in the region between the two electrodes. By introducing an inert gas component over the entire reactor cross section, deposition of carbon in this region of the reactor inner wall is prevented, thus effectively inhibiting the formation of conductivity bridges on the reactor inner wall.

公开(公告)号：US10099923B2

公开(公告)日：2018-10-16

申请号：US15504982

申请日：2015-08-13

申请人： BASF SE

发明人： Otto Machhammer ,  Grigorios Kolios ,  Andreas Bode ,  Hans-Juergen Maass

IPC分类号： C01B3/24 ,  C01B3/28 ,  C01B31/18 ,  C01B5/00

摘要： The invention relates to a process for producing synthesis gas (5) in which hydrocarbon (2) is decomposed thermally in a first reaction zone (11) to hydrogen and carbon, and hydrogen formed is passed from the first reaction zone (Z1) into a second action zone (Z2) in order to be reacted therein with carbon dioxide (4) to give water and carbon monoxide. The characteristic feature here is that energy required for the thermal decomposition of the hydrocarbon is supplied to the first reaction zone (Z1) from the second reaction zone (Z2).

公开(公告)号：US09938144B2

公开(公告)日：2018-04-10

申请号：US14827496

申请日：2015-08-17

申请人： LINDE AKTIENGESELLSCHAFT ,  BASF SE

发明人： Hans-Jurgen Maass ,  Otto Machhammer ,  Andreas Bode ,  Grigorios Kolios

IPC分类号： C01B3/30 ,  C01B31/18 ,  C01B3/24 ,  C01B3/28 ,  C10J3/18 ,  C10J3/20 ,  C10K3/02

CPC分类号： C01B3/30 ,  C01B3/24 ,  C01B3/28 ,  C01B32/40 ,  C01B2203/0216 ,  C01B2203/0272 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/0822 ,  C01B2203/0838 ,  C01B2203/085 ,  C01B2203/1235 ,  C01B2203/148 ,  C01B2203/84 ,  C10J3/18 ,  C10J3/20 ,  C10K3/026 ,  Y02P20/128 ,  Y02P20/129 ,  Y02P20/146

摘要： The invention relates to a process for producing synthesis gas, in which carbon and hydrogen are obtained from hydrocarbon by thermal decomposition. At least a portion of the carbon obtained by the thermal decomposition is reacted, and at least a portion of the hydrogen obtained is reacted with carbon dioxide by a reverse water-gas shift reaction to give carbon monoxide and water. Carbon obtained by the thermal hydrocarbon decomposition is used as fuel in a power plant operation wherein the carbon is combusted to produce electrical power, and carbon dioxide formed in the combustion of the carbon is used in the reverse water-gas shift reaction.

公开(公告)号：US20150321912A1

公开(公告)日：2015-11-12

申请号：US14651862

申请日：2013-12-12

申请人： BASF SE ,  LINDE AG

发明人： Otto MACHHAMMER ,  Wolfgang Alois HORMUTH ,  Christian SCHNEIDER ,  Andreas BODE ,  Volker GOEKE ,  Hans-Juergen MASS ,  Matthias KERN ,  Dirk KLINGLER ,  Rene KOENIG ,  Philipp BRUEGGEMANN ,  Jens BERNNAT ,  Grigorios KOLIOS

IPC分类号： C01B3/28

CPC分类号： C01B3/28 ,  B01J8/00 ,  B01J19/00 ,  B01J2208/00415 ,  B01J2219/00135 ,  C01B2203/0272 ,  C01B2203/0866

摘要： The invention relates to a method of carrying out heat-consuming processes, wherein the total energy required averaged over a year for the heat-consuming process originates from at least two different energy sources, where one of the energy sources is an electric energy source whose power varies in the range from 0 to 100% of the total power required, and three different energy modes can individually provide the total power required for the heat-consuming process: (i) exclusively electric energy, (ii) a mixture of electric energy and at least one further nonelectric energy source or (iii) exclusively nonelectric energy, where the changeover time in which the change from one energy mode to another energy mode is completed is not more than 30 minutes.

摘要翻译： 本发明涉及一种进行耗热过程的方法，其中对于耗热过程而言，平均一年以上的总能量源自至少两个不同的能源，其中一个能量源是电能源， 功率在所需总功率的0至100％的范围内变化，并且三种不同的能量模式可以单独地提供耗散过程所需的总功率：（i）专用电能，（ii）电能的混合 和至少一个另外的非电能源，或者（iii）唯一的非电能，其中从一个能量模式到另一个能量模式的改变的转换时间不超过30分钟。

公开(公告)号：US07432222B2

公开(公告)日：2008-10-07

申请号：US10978791

申请日：2004-11-01

申请人： Vasant Ramchandra Choudhary ,  Kartick Chandra Mondal ,  Ajit Singh Mamman

发明人： Vasant Ramchandra Choudhary ,  Kartick Chandra Mondal ,  Ajit Singh Mamman

IPC分类号： B01J23/00 ,  C01B3/26 ,  C01B3/28

CPC分类号： C01B3/386 ,  B01J21/066 ,  B01J23/002 ,  B01J23/83 ,  B01J35/1009 ,  B01J37/0201 ,  B01J2523/00 ,  C01B2203/0261 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1241 ,  Y02P20/142 ,  Y02P20/52 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/36 ,  B01J2523/3712 ,  B01J2523/847 ,  B01J2523/845

摘要： This invention discloses a high temperature stable, supported, non-noble metal catalyst, represented by a general formula: NiCoaCebMgcYdOx(y)/S, wherein S is a low surface area, macroporous, highly sintered, solid support comprising zirconium and hafnium oxides with less than 3 wt % silica and/or alumina having a surface area less than 1.0 m2/g and pore diameter greater than 0.1 micron, in the form of pellet, ring, monolith or granules; a is from 0.01 to 10; b is from 0.001 to 10; c is from 0.001 to 10; d is from 0.005 to 5; x is number of oxygen atoms required to fulfill the valance requirement of the metallic elements; and y is weight percent loading of the active catalyst mass, on the support, S, in the range from 0.7% to 70%. The invention also discloses a process for the partial oxidation of hydrocarbon(s) to syngas using the thermally stable catalyst.

摘要翻译： 本发明公开了一种高温稳定的，负载型的非贵金属催化剂，由以下通式表示：NiCo a S a B b Mg C y （y）/ S，其中S是低表面积，大孔，高度烧结的固体载体，其包含锆和氧化铪，具有小于3重量％的二氧化硅 和/或表面积小于1.0m 2 / g且孔径大于0.1微米的氧化铝，以颗粒，环，整料或颗粒的形式; a为0.01〜10; b为0.001〜10; c为0.001〜10; d为0.005〜5; x是满足金属元素的价格要求所需的氧原子数; y是活性催化剂物质在载体上的重量百分比，S在0.7％至70％的范围内。 本发明还公开了一种使用热稳定催化剂将烃部分氧化成合成气的方法。

公开(公告)号：US4726913A

公开(公告)日：1988-02-23

申请号：US70081

申请日：1987-07-06

申请人： John H. Brophy ,  Richard P. Manning

发明人： John H. Brophy ,  Richard P. Manning

IPC分类号： C07C2/82 ,  B01J8/24 ,  C01B3/34 ,  C07C1/00 ,  C07C11/04 ,  C07C11/24 ,  C07C67/00 ,  C01B3/28 ,  C01B3/30

CPC分类号： B01J8/245 ,  C01B3/344

摘要： Process for the production of synthesis gas and hydrocarbons in which a saturated hydrocarbon and an oxygen containing gas having a ratio of hydrocarbon to oxygen of greater than the stoichiometric ratio for complete combustion are introduced together with hydrogen into a bed of particulate material. The upward flow rate of the gases is sufficiently large to fluidize or to cause a spouting action of the bed material. The hydrocarbon, oxygen containing gas and hydrogen are ignited and reacted together and the products of the reaction are withdrawn.

摘要翻译： 用于生产合成气和烃的方法，其中将饱和烃和具有大于全部燃烧的化学计量比的烃与氧的含氧气体一起引入到颗粒材料床中。 气体的向上流速足够大以流化或引起床料的喷射作用。 烃，含氧气体和氢气被点燃并一起反应，反应产物被排出。

公开(公告)号：US4219535A

公开(公告)日：1980-08-26

申请号：US872587

申请日：1978-01-26

申请人： Yujiro Sugahara ,  Koichi Usui ,  Masahide Ogawa ,  Hideaki Kurosaki ,  Shigehisa Imafuku

发明人： Yujiro Sugahara ,  Koichi Usui ,  Masahide Ogawa ,  Hideaki Kurosaki ,  Shigehisa Imafuku

IPC分类号： C01B3/28 ,  C01B39/14 ,  C01B39/18 ,  C11D3/00 ,  C11D3/12 ,  C01B33/28 ,  C11D9/18

CPC分类号： C11D3/128 ,  C01B33/2815 ,  Y10S423/24

摘要： A detergent builder consisting essentially of an inorganic fine powder composed mainly of an alkali metal aluminosilicate having an X-ray diffraction pattern substantially the same as that of zeolite of the type A and having a degree of crystallization in the range of from 35 to 75%, wherein the inorganic fine powder has a primary particle size smaller than 1.mu. and a secondary particle size smaller than 4.mu., the inorganic fine powder has a buffer capacity (S) of at least 132 ml/100 g of solids, the buffer capacity being expressed by an amount of hydrochloric acid necessary for lowering the pH of a 1% aqueous dispersion of said inorganic fine powder from 9.0 to 6.75 when the dispersion is titrated with 0.4 N hydrochloric acid at a rate of 20 to 50 ml/hr, and wherein the inorganic fine powder has a calcium ion binding property (C. I.) of at least 70 mg/g as expressed as CaO.

摘要翻译： 一种洗涤剂助洗剂，其基本上由主要由碱金属硅铝酸盐组成的无机细粉末组成，其具有与A型沸石基本上相同的X射线衍射图，其结晶度为35-75％ 其中无机细粉末的一次粒径小于1μm，二次粒径小于4μm，无机细粉末的缓冲能力（S）为至少132ml / 100g固体，缓冲能力 当用0.4N盐酸以20至50ml /小时的速率滴定分散体时，将所述无机细粉末的1％水分散体的pH降低至9.0至6.75所需的盐酸量表示，以及 其中所述无机细粉末的钙离子结合性（CI）为CaO表示为至少70mg / g。

公开(公告)号：US3284161A

公开(公告)日：1966-11-08

申请号：US25308563

申请日：1963-01-22

申请人： UNIVERSAL OIL PROD CO

发明人： POHLENZ JACK B ,  SCOTT NORMAN H

IPC分类号： C01B3/28 ,  C01B3/30 ,  C01B3/40 ,  C01B3/42 ,  C01B3/44

CPC分类号： C01B3/42 ,  C01B3/28 ,  C01B3/30 ,  C01B3/40 ,  C01B3/44 ,  C01B2203/0277 ,  C01B2203/0465 ,  C01B2203/0811 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1241

公开(公告)号：US08372311B2

公开(公告)日：2013-02-12

申请号：US13428522

申请日：2012-03-23

申请人： Michael Cheiky ,  Rajashekharam Malyala ,  Ronald A. Sills

发明人： Michael Cheiky ,  Rajashekharam Malyala ,  Ronald A. Sills

IPC分类号： C01B3/28 ,  C01B3/24

CPC分类号： C01B3/34 ,  C01B3/36 ,  C01B32/324 ,  C01B32/336 ,  C01B2203/0211 ,  C01B2203/025 ,  C01B2203/061 ,  C01B2203/062 ,  C10B53/02 ,  C10G1/02 ,  C10G2300/1011 ,  C10J3/62 ,  C10J2300/0916 ,  C10J2300/0976 ,  C10K3/00 ,  Y02E50/14 ,  Y02P20/145 ,  Y02P30/20

摘要： Biomass is processed through a biomass fractioning system that creates, through the application of selective temperature ramps and pressure shocks, a series of useful volatile components and BMF char, wherein the BMF char is reacted sacrificially with any one stream of methane, carbon dioxide, steam or oxygen to create highly pure synthesis gas with a controllable range of compositions. The resulting synthesis gas may be used in any desired manner, including conversion to oxygenates such as methanol and dimethyl ether, and to hydrocarbons.

摘要翻译： 通过生物质分馏系统处理生物质，通过应用选择性温度斜坡和压力冲击，产生一系列有用的挥发性组分和BMF炭，其中BMF炭与甲烷，二氧化碳，蒸汽 或氧气以产生具有可控范围的组合物的高纯度合成气。 所得合成气可以以任何所需的方式使用，包括转化为含氧化合物如甲醇和二甲醚，以及转化成烃。

公开(公告)号：US4767569A

公开(公告)日：1988-08-30

申请号：US70644

申请日：1987-07-06

申请人： John H. Brophy ,  Felix J. Weinberg

发明人： John H. Brophy ,  Felix J. Weinberg

IPC分类号： C01B3/44 ,  C01B3/28 ,  C01B3/30

CPC分类号： C01B3/44

摘要： Process for the production of synthesis gas and higher hydrocarbons in which a saturated hydrocarbon and an oxygen containing gas having a ratio of hydrocarbon to oxygen of greater than the stoichiometric ratio for complete combustion are introduced into a bed of an inert particulate material. The upward flow rate of the hydrocarbon/oxygen containing gas stream is sufficient to fluidize or to produce a spouting action of the bed material, whereby the particulate material is thrown up above the bed surface and subsequently falls back into the bed. The hydrocarbon and oxygen containing gas are ignited reacted together, and the products of the reaction withdrawn.

摘要翻译： 用于生产合成气和高级烃的方法，其中将饱和烃和具有大于完全燃烧的化学计量比的烃与氧的比例的含氧气体引入惰性颗粒材料的床中。 含烃/含氧气流的向上流速足以流化或产生床材料的喷射作用，由此将颗粒材料扔在床表面上方并随后落回床中。 点燃碳氢化合物和含氧气体一起反应，并将反应产物取出。