METAL ORGANIC FRAMEWORK AND GAS ADSORBING MATERIAL

    公开(公告)号:US20250059056A1

    公开(公告)日:2025-02-20

    申请号:US18756470

    申请日:2024-06-27

    Inventor: Yoshio OHASHI

    Abstract: The present disclosure provides a novel metal organic framework and a gas adsorbing material containing the metal organic framework. The metal organic framework in one aspect of the embodiment contains zinc (Zn) and at least one ligand selected from 4-methylimidazole (4-MeIm), imidazole (Im), and benzimidazole (BzIm). When a mole ratio of the 4-MeIm, Im, and BzIm is x:y:z (4-MeIm:Im:BzIm), the mole ratio x:y:z falls within a polygonal region (including on a boundary line) having the following vertices in a ternary composition diagram: A (1:0:0), B (0.608:0.392:0), C (0.407:0.441:0.152), D (0.278:0.496:0.226), E (0:0.613:0.387), F (0:0.388:0.612), G (0.221:0.277:0.502), H (0.455:0.117:0.428), and I (0.563:0:0.437).

    HYDROCARBON ADSORBENT
    8.
    发明申请

    公开(公告)号:US20230049498A1

    公开(公告)日:2023-02-16

    申请号:US17911820

    申请日:2021-03-11

    Abstract: Provided are: a hydrocarbon adsorbent capable of adsorbing hydrocarbons, storing the adsorbed hydrocarbons up to a relatively high temperature, and desorbing the adsorbed and stored hydrocarbons at a relatively high temperature; an exhaust gas purifying catalyst composition using the same; an exhaust gas purifying catalyst; and a method for treating an exhaust gas. The hydrocarbon adsorbent comprises a zeolite having an MRT-type framework structure. The hydrocarbon adsorbent comprises a small-pore zeolite having a total desorption amount ZD1 of propylene desorbed at 50° C. or higher and lower than 300° C. being 3.5 mmol/g or less and a total desorption amount ZD2 of propylene desorbed at 300° C. or higher and 500° C. or lower being 0.5 mmol/g or more, per 1 g by mass of the small-pore zeolite, when adsorbing propylene at 50° C. and then heating from 50° C. to 500° C. under the condition of 10° C./min by a temperature-programmed desorption method.

    IZM-5 CRYSTALLISED SOLID AND METHOD FOR PREPARING SAME

    公开(公告)号:US20220250925A1

    公开(公告)日:2022-08-11

    申请号:US17622339

    申请日:2020-06-16

    Abstract: The present invention relates to a crystallised solid, called IZM-5, comprising a chemical composition expressed on an anhydrous base, in terms of mole, and defined by the following general formula: SnaZnbS8: cR, wherein R represents at least one nitrogenous organic species; S sulphur, “a” is the molar amount of tin, denoted Sn, between 0.1 and 5; “b” is the molar amount of zinc, denoted Zn, between 0.2 and 8; “c” is the molar amount of the nitrogenous organic species R between 0 and 4.

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