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公开(公告)号:US20240326029A1
公开(公告)日:2024-10-03
申请号:US18711894
申请日:2022-11-21
申请人: BASF SE
发明人: Trees Maria DE BAERDEMAEKER , Andrei-Nicolae PARVULESCU , Joaquim Henrique TELES , Jaroslaw Michael MORMUL , Toshiyuki YOKOI , Feiyu QIN
CPC分类号: B01J29/7049 , B01J37/06 , B01J37/08 , B01J37/12 , C01B39/46 , C01P2002/72 , C01P2002/82 , C01P2002/84 , C01P2004/03
摘要: The present invention relates to a specific process for the preparation of a zeolitic material, wherein the framework structure of the zeolitic material comprises Si, O, and a tetravalent ele-ment M other than Si, wherein M is selected from the group consisting of Ti, Sn, Zr, Ge, and mixtures of two or more thereof. Further, the present invention relates to a zeolitic material obtainable or obtained by said process, the zeolitic material itself and its use. In addition thereto, the present invention relates to a molding comprising said zeolitic material.
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2.
公开(公告)号:US20240174523A1
公开(公告)日:2024-05-30
申请号:US18551419
申请日:2022-03-22
申请人: BASF Corporation
发明人: Xiaoduo Qi , Lihua Shi , Vivek Vattipalli , Yu Dai , Mingming Wei , Haitao Liu , Jin Li
IPC分类号: C01B39/46 , B01D53/94 , B01J29/072
CPC分类号: C01B39/46 , B01D53/9418 , B01J29/072 , B01D2255/20738 , B01D2255/50 , B01D2255/9207 , B01D2257/40 , B01D2258/01 , C01P2002/60
摘要: The present invention relates to a process for preparing an aluminosilicate zeolite having AFT framework structure, which includes (1) providing a synthesis mixture comprising (A) a source for Al2O3, (B) a source for SiO2, (C1) a source for first organic structure directing agent comprising a N, N, N, N′, N′, N′-hexaethyl alkylenediammonium cation, and optionally a source for second organic structure directing agent comprising a cation selected from (C2-i) quaternary ammonium cations of formula (I), (C2-ii) piperidinium cations of formula (II), and (C2-iii) pyrrolidinium cations of formula (III), and (2) subjecting the synthesis mixture to crystallization conditions to form an AFT zeolite, wherein the formula (I), (II) and (III) are as defined in the description and claims. The present invention also relates to an SCR catalyst composition comprising an aluminosilicate zeolite having AFT framework structure and a promoter metal, and use of the aluminosilicate zeolite for selective catalytic reduction of nitrogen oxides.
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公开(公告)号:US20230339766A1
公开(公告)日:2023-10-26
申请号:US18342828
申请日:2023-06-28
申请人: NGK INSULATORS, LTD.
IPC分类号: C01B39/46
CPC分类号: C01B39/46 , C01P2002/78 , C01P2002/74 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2002/72
摘要: In an RHO-type zeolite, in a case where a peak at a lattice spacing of 9.96 to 11.25 Å in a measurement using a powder X-ray diffraction method is assumed as a reference peak and an intensity of the reference peak is assumed as 100, a relative intensity of a peak at a lattice spacing of 4.59 to 4.85 Å is 150 to 300, a relative intensity of a peak at a lattice spacing of 3.55 to 3.64 Λ is 200 to 500, and a relative intensity of a peak at a lattice spacing of 2.98 to 3.06 Å is 100 to 200.
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公开(公告)号:US20230051097A1
公开(公告)日:2023-02-16
申请号:US17786782
申请日:2020-12-23
发明人: Danny VERBOEKEND , Martin D'HALLUIN
摘要: The present invention relates to processes for the preparation of mesoporous zeolites by post-synthetic technologies, the properties of resulting materials, and the use of the resulting materials as catalysts in the refining and petrochemical industry.
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公开(公告)号:US20230049498A1
公开(公告)日:2023-02-16
申请号:US17911820
申请日:2021-03-11
发明人: Mayuko SUWA , Hidekazu GOTO
摘要: Provided are: a hydrocarbon adsorbent capable of adsorbing hydrocarbons, storing the adsorbed hydrocarbons up to a relatively high temperature, and desorbing the adsorbed and stored hydrocarbons at a relatively high temperature; an exhaust gas purifying catalyst composition using the same; an exhaust gas purifying catalyst; and a method for treating an exhaust gas. The hydrocarbon adsorbent comprises a zeolite having an MRT-type framework structure. The hydrocarbon adsorbent comprises a small-pore zeolite having a total desorption amount ZD1 of propylene desorbed at 50° C. or higher and lower than 300° C. being 3.5 mmol/g or less and a total desorption amount ZD2 of propylene desorbed at 300° C. or higher and 500° C. or lower being 0.5 mmol/g or more, per 1 g by mass of the small-pore zeolite, when adsorbing propylene at 50° C. and then heating from 50° C. to 500° C. under the condition of 10° C./min by a temperature-programmed desorption method.
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公开(公告)号:US11446626B2
公开(公告)日:2022-09-20
申请号:US16636735
申请日:2018-08-07
发明人: Samuel Valable , Svetlana Mintova Lazarova , Clément Anfray , Valentin Valtchev , Omar Touzani , Myriam Bernaudin
摘要: The present invention relates to a method for the preparation of a colloidal aqueous suspension of stable zeolite nanocrystals having framework structures comprising at least one cation selected from Gd, Fe, Cu and Ce, said structures being loaded with a gas selected from O2, CO2 and mixtures thereof, to the colloidal aqueous suspension of zeolite nanocrystals obtained by such a process, and to the use of said suspension in therapy, more particularly in cancer therapy and hypoxia-related diseases and/or in diagnosis.
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公开(公告)号:US20220250925A1
公开(公告)日:2022-08-11
申请号:US17622339
申请日:2020-06-16
摘要: The present invention relates to a crystallised solid, called IZM-5, comprising a chemical composition expressed on an anhydrous base, in terms of mole, and defined by the following general formula: SnaZnbS8: cR, wherein R represents at least one nitrogenous organic species; S sulphur, “a” is the molar amount of tin, denoted Sn, between 0.1 and 5; “b” is the molar amount of zinc, denoted Zn, between 0.2 and 8; “c” is the molar amount of the nitrogenous organic species R between 0 and 4.
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公开(公告)号:US20220226800A1
公开(公告)日:2022-07-21
申请号:US17574830
申请日:2022-01-13
摘要: This application relates to methods and systems for drying polyol starters, as well as reaction mixtures including such polyol starters, and the preparation of polymers derived from such polyol starters. In some embodiments, the present invention encompasses methods of drying a polyol initiator compound, the method including the step of contacting a composition comprising a polyol initiator compound with one or more molecular sieves.
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公开(公告)号:US20220219997A1
公开(公告)日:2022-07-14
申请号:US17612686
申请日:2020-05-20
申请人: TOTAL SE
发明人: Nicolas BARRIER , Philippe BOULLAY , Maxime DEBOST , Jean-Pierre GILSON , Julien GRAND , Delphine MINOUX , Svetlana MINTOVA , Nikolai NESTERENKO
摘要: The present disclosure relates to an RHO-type zeolite comprising caesium and M1 wherein M1 is selected from Na and/or Li remarkable in that it has a Si/Al molar ratio comprised between 1.2 and 3.0 as determined by 29Si magic angle spinning nuclear magnetic resonance, in that the RHO-type zeolite has a specific surface area comprised between 40 m2g−1 and 250 m2g−1 as determined by N2 adsorption measurements, in that the RHO-type zeolite being in the form of one or more nanoparticles with an average crystal size comprised between 10 nm and 400 nm as determined by scanning electron microscopy wherein said nanoparticles form monodispersed nanocrystals or form aggregates of nanocrystals having an average size ranging from 100 nm to 500 nm, as determined by scanning electron microscopy. Amorphous precursors, devoid of an organic structure-directing agent, as well as a method for preparation of these amorphous precursors in the absence of such organic structure-directing agent and method for preparation of the RHO-type zeolites, are alos described. Finally, the use of the RHO-type zeolite as a sorbent for carbon dioxide is also demonstrated.
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公开(公告)号:US20220212163A1
公开(公告)日:2022-07-07
申请号:US17617211
申请日:2020-05-20
申请人: TOTAL SE
发明人: Nicolas BARRIER , Philippe BOULLAY , Jean-Pierre GILSON , Julien GRAND , Delphine MINOUX , Svetlana MINTOVA , Nikolai NESTERENKO , Maxime DEBOST
摘要: The present disclosure relates to a chabazite-type zeolite, comprising at least two cages composed of 4- and 8-membered rings connected by one 6-membered double ring, remarkable in that it has a Si/Al molar ratio comprised between 1 and 15, in that it comprises caesium and potassium with a Cs/K molar ratio of at most 5.0 and in that it forms nanoparticles with an average crystal size comprised between 5 nm and 250 nm and with a specific surface area comprised between 50 m2g−1 and 200 m2g−1. Amorphous precursors, devoid of an organic structure-directing agent, as well as a method for preparation of these amorphous precursors in the absence of such organic structure-directing agent and method for preparation of the chabazite-type zeolite, are also described. Finally, the use of the chabazite-type zeolite as a sorbent for carbon dioxide is also demonstrated.
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