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公开(公告)号:US11565984B2
公开(公告)日:2023-01-31
申请号:US17577173
申请日:2022-01-17
申请人: Honda Motor Co. Ltd.
发明人: Kohtaro Hashimoto
IPC分类号: C07C1/24 , C01B32/05 , C01B32/40 , B01J19/24 , C07C29/151 , C07C51/12 , C07C45/68 , C07F3/02 , C07C29/132 , C25B1/04 , C25B15/08 , C25B9/17 , C07C45/41
摘要: Production apparatus of triptane includes: carbon dioxide recovery unit configured to recover carbon dioxide from air; hydrogen generation unit configured to electrolyze water by renewable electricity to generate hydrogen; carbon monoxide generation unit configured to generate carbon monoxide from recovered carbon dioxide and hydrogen generated; methanol generation unit configured to generate methanol from carbon monoxide generated and hydrogen generated; acetic acid generation unit configured to generate acetic acid by reacting methanol generated with recovered carbon dioxide or with carbon monoxide generated; acetone generation unit configured to generate acetone and carbon dioxide from acetic acid generated; pinacolone generation unit configured to generate pinacolone from acetone generated; Grignard reagent generation unit configured to generate Grignard reagent from methanol generated; trimethyl butanol generation unit configured to generate 2,3,3-trimethyl-2-butanol by reacting pinacolone generated with Grignard reagent generated; and triptane generation unit configured to generate 2,2,3-trimethylbutane from 2,3,3-trimethyl-2-butanol generated.
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公开(公告)号:US20220185763A1
公开(公告)日:2022-06-16
申请号:US17543877
申请日:2021-12-07
发明人: Akihiro Baba , Takeshi Kinsho , Naoki Ishibashi , Yusuke Nagae
IPC分类号: C07C69/587 , C07C45/41 , C07C67/08 , C07C67/475
摘要: The present invention relates to a process for preparing a 3-isopropenyl-6-heptenal compound of the following formula (2): wherein R1 represents a hydrogen atom or a methyl group, the process comprising: subjecting a 3-isopropenyl-6-heptenoate ester compound of the following formula (1): wherein R1 is as defined above, and R2 represents a monovalent hydrocarbon group having 1 to 10 carbon atoms, to a reduction reaction with a reducing agent to form the 3-isopropenyl-6-heptenal compound (2).
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公开(公告)号:US11180437B2
公开(公告)日:2021-11-23
申请号:US17203097
申请日:2021-03-16
申请人: SOOCHOW UNIVERSITY
发明人: Shilei Zhang , Yujian Mao
摘要: Disclosed is a method for preparing a 1,3-dicarbonyl compound based on a metal hydride/palladium compound system. The method includes the following steps: suspending a palladium compound and a metal hydride in a solvent under the protection of nitrogen, then adding an electron-deficient olefin compound, reacting same at 0° C.-100° C. for 0.3 to 10 hours, then adding a saturated ammonium chloride aqueous solution to stop the reaction, and then subjecting same to extraction, evaporation until dryness, and column chromatography purification to obtain the 1,3-dicarbonyl compound. The hydride and palladium compound catalysts used by the present invention are reagents easily obtained in a laboratory. Compared to a common hydrogen hydrogenation method, the method is easier to operate, and has a higher safety, mild conditions, and a high reaction yield.
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公开(公告)号:US11162033B2
公开(公告)日:2021-11-02
申请号:US16623188
申请日:2018-06-15
申请人: Neste Oyj
发明人: Sami Toppinen , Pekka Nurmi
IPC分类号: C10G3/00 , B01J21/04 , B01J21/06 , B01J23/883 , B01J35/10 , C07C45/41 , C10G45/58 , C10L1/08 , B01J29/85 , C10G67/02 , C11C1/04 , C10M105/04 , C10M105/06 , C10M169/04 , B01D3/14 , C07C51/44 , C10M177/00 , C11C1/10 , C10N30/00 , C10N20/00 , C10N30/02 , C10N30/04 , C10N30/10 , C10N30/12 , C10N30/14 , C10N30/16 , C10N70/00
摘要: Methods are disclosed for producing renewable base oil and a diesel oil from low-value biological oils. Low-value biological oils containing free fatty acids and fatty acid esters can be processed into a renewable base oil and a renewable diesel oil by first separating at least part of the saturated free fatty acids from the feedstock and then processing separately this saturated free acid feed in a ketonisation reaction followed by hydrodeoxygenation and hydroisomerisation reactions to yield a renewable base oil stream. The remaining free fatty acid depleted feed may be processed in a separate hydrodeoxygenation and hydroisomerisation step to yield a renewable diesel stream.
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公开(公告)号:US11149206B2
公开(公告)日:2021-10-19
申请号:US16623210
申请日:2018-06-15
申请人: Neste Oyj
发明人: Jukka Myllyoja , Mika Kettunen , Rami Piilola
IPC分类号: C10G3/00 , B01J21/04 , B01J21/06 , B01J23/883 , B01J35/10 , C07C45/41 , C10G45/58 , C10L1/08 , B01J29/85 , C10G67/02 , C11C1/04 , C10M105/04 , C10M105/06 , C10M169/04 , B01D3/14 , C07C51/44 , C10M177/00 , C11C1/10 , C10N30/00 , C10N20/00 , C10N30/02 , C10N30/04 , C10N30/10 , C10N30/12 , C10N30/14 , C10N30/16 , C10N70/00
摘要: A number of different branched hydrocarbon compounds (formula I) having a star-like configuration (S) are prepared from renewable oils containing fatty acids or derivatives containing fatty acids. The branched hydrocarbon compounds may be isolated individually or in mixtures, and may be used as part of base oils, such as renewable base oils (RBOs). A process for preparing the branched hydrocarbon compounds of formula I involve conditions that favour a trimerisation reaction followed by hydrotreating conditions. The compounds of formula I may be made by catalytically treating renewable material in a process, and the compounds have desirable qualities relating to lubrication, cold flow as well as having a low Noack volatility.
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公开(公告)号:US11077433B2
公开(公告)日:2021-08-03
申请号:US16798954
申请日:2020-02-24
申请人: Provivi, Inc.
发明人: Keith M. Wampler , Peter Meinhold , Pedro Coelho , Vu Bui , Levente Ondi , Hasan Mehdi
IPC分类号: B01J31/22 , C07C29/147 , C07C67/08 , C07C67/343 , C07C45/41 , C07C6/04 , C07C67/293
摘要: In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.
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公开(公告)号:US20210188734A1
公开(公告)日:2021-06-24
申请号:US17121336
申请日:2020-12-14
摘要: The present disclosure relates to a method that includes a first treating of a first mixture that includes a carboxylic acid having between 2 and 12 carbon atoms, inclusively, to form a second mixture that includes a ketone having between 2 and 25 carbon atoms, inclusively, and a second treating of at least a first portion of the second mixture to form a first product that includes a paraffin having 8 or more carbon atoms.
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公开(公告)号:US20210155570A1
公开(公告)日:2021-05-27
申请号:US16613454
申请日:2018-05-17
申请人: Arkema France
摘要: A method for manufacturing 1,4-bis(4-phenoxybenzoyl)benzene, including: reacting terephthaloyl chloride with diphenyl ether in a reaction solvent and in the presence of a Lewis acid, so as to obtain a product mixture comprising a 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex; putting the product mixture in contact with a protic solvent, so as to obtain a first phase containing the Lewis acid and a second phase containing 1,4-bis(4-phenoxybenzoyl)benzene; heating at least the second phase up to a maximum temperature, followed by cooling the second phase down to a separation temperature; subjecting at least the second phase to a solid/liquid separation step at the separation temperature, so as to recover solid 1,4-bis(4-phenoxybenzoyl)benzene.
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公开(公告)号:US20200261898A1
公开(公告)日:2020-08-20
申请号:US16798954
申请日:2020-02-24
申请人: Provivi, Inc.
发明人: Keith M. Wampler , Peter Meinhold , Pedro Coelho , Vu Bui , Levente Ondi , Hasan Mehdi
IPC分类号: B01J31/22 , C07C67/293 , C07C6/04 , C07C45/41 , C07C67/343 , C07C67/08 , C07C29/147
摘要: In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.
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公开(公告)号:US20200181503A1
公开(公告)日:2020-06-11
申请号:US16623276
申请日:2018-06-15
申请人: Neste Oyj
发明人: Jukka MYLLYOJA , Sonja KOUVA , Jarno KOHONEN , Rami PIILOLA , Mika KETTUNEN , Jaana MAKKONEN , Meri HOVI
IPC分类号: C10G3/00 , C07C45/41 , C10G45/58 , C10L1/08 , B01J21/06 , B01J23/883 , B01J21/04 , B01J35/10
摘要: A method for producing a renewable base oil from a feedstock of biological origin includes providing a feedstock, the feedstock including: 2-95 wt % of a mixture of free fatty acids; 5-98 wt % fatty acid glycerols selected from mono-glycerides, di-glycerides and tri-glycerides of fatty acids; 0-50 wt % of one or more compounds selected from the list consisting of: fatty acid esters of the non-glycerol type, fatty amides and fatty alcohols; a major part of the feedstock being a mixture of free fatty acids and fatty acid glycerols; subjecting all or part of the feedstock to ketonisation reaction conditions where two free fatty acids react to yield a ketone stream, and subjecting the ketone stream to both hydrodeoxygenation and to hydroisomerisation reaction conditions, to yield a deoxygenated and isomerised base oil product stream containing the renewable base oil.
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