公开(公告)号：US11542447B2

公开(公告)日：2023-01-03

申请号：US17196314

申请日：2021-03-09

申请人： Saudi Arabian Oil Company

发明人： Omer Refa Koseoglu ,  Sohel Shaikh ,  Zhonglin Zhang

IPC分类号： C07C2/06 ,  C07C29/141 ,  C07C41/06 ,  C07C45/50 ,  C07D301/04 ,  C01G9/00 ,  C10G67/12 ,  C10G9/36 ,  C10G45/38 ,  C10G27/04

摘要： In accordance with one or more embodiments of the present disclosure, a method for producing epoxide gasoline blending components includes cracking, in a steam cracker, a hydrocarbon feed to form a first ethylene stream, a first propylene stream, and a C4 stream comprising isobutene and butadiene; reacting, in a methyl tertiary butyl ether (MTBE) unit, the C4 stream with a methanol stream to form MTBE and a butadiene-rich C4 stream; selectively hydrogenating, in a butadiene unit, the butadiene-rich C4 stream to form a butene-rich C4 stream including butene-1, cis-butene-2, and trans-butene-2; producing, in an isononanol unit, isononanol and an olefin-rich stream from the butene-rich C4 stream; and oxidizing the olefin-rich stream in an oxidation unit by combining the olefin-rich stream with an oxidant stream and a catalyst composition to produce the epoxide gasoline blending components.

公开(公告)号：US20220290058A1

公开(公告)日：2022-09-15

申请号：US17196314

申请日：2021-03-09

申请人： Saudi Arabian Oil Company

发明人： Omer Refa Koseoglu ,  Sohel Shaikh ,  Zhonglin Zhang

IPC分类号： C10G67/12 ,  C10G9/36 ,  C10G45/38 ,  C10G27/04

摘要： In accordance with one or more embodiments of the present disclosure, a method for producing epoxide gasoline blending components includes cracking, in a steam cracker, a hydrocarbon feed to form a first ethylene stream, a first propylene stream, and a C4 stream comprising isobutene and butadiene; reacting, in a methyl tertiary butyl ether (MTBE) unit, the C4 stream with a methanol stream to form MTBE and a butadiene-rich C4 stream; selectively hydrogenating, in a butadiene unit, the butadiene-rich C4 stream to form a butene-rich C4 stream including butene-1, cis-butene-2, and trans-butene-2; producing, in an isononanol unit, isononanol and an olefin-rich stream from the butene-rich C4 stream; and oxidizing the olefin-rich stream in an oxidation unit by combining the olefin-rich stream with an oxidant stream and a catalyst composition to produce the epoxide gasoline blending components.

公开(公告)号：US11174441B2

公开(公告)日：2021-11-16

申请号：US16166686

申请日：2018-10-22

申请人： SAUDI ARABIAN OIL COMPANY

发明人： Omer Refa Koseoglu

IPC分类号： C10G55/04 ,  C10G67/12 ,  C10G27/04 ,  C01B3/34 ,  C10G9/00

摘要： The invention is an integrated process for treating residual oil of a hydrocarbon feedstock. The oil is first subjected to delayed coking and then oxidative desulfurization. Additional, optional steps including hydrodesulfurization, and hydrocracking, may also be incorporated in to the integrated process.

公开(公告)号：US11111194B2

公开(公告)日：2021-09-07

申请号：US16249992

申请日：2019-01-17

申请人： NOVA Chemicals (International) S.A.

发明人： Vasily Simanzhenkov ,  Shahin Goodarznia ,  Christina Orta ,  Kamal Serhal ,  Eric Clavelle ,  Michael Koselek ,  Yoonhee Kim

IPC分类号： C07C5/48 ,  B01D53/00 ,  B01D5/00 ,  B01D53/26 ,  B01D53/22 ,  F25J3/02 ,  B01J8/02 ,  B01J8/06 ,  B01J8/18 ,  B01J19/24 ,  B01J8/26 ,  B01D53/14 ,  C10G70/00 ,  C10G27/04 ,  B01J4/00 ,  C10G11/04 ,  B08B9/00 ,  B08B9/027 ,  C11D11/00 ,  C10G75/00

摘要： Oxidative dehydrogenation is an alternative to the energy extensive steam cracking process presently used for the production of olefins from paraffins. Various embodiments of an oxidative dehydrogenation chemical complex designed to allow removal of sulfur containing contaminants that collect in the gas mixer unit and in the feed lines leading to the ODH reactor are disclosed herein.

公开(公告)号：US20210230084A1

公开(公告)日：2021-07-29

申请号：US17140667

申请日：2021-01-04

申请人： SAUDI ARABIAN OIL COMPANY ,  BORESKOV INSTITUTE OF CATALYSIS

发明人： Omer Refa KOSEOGLU ,  Yaming Luisa JIN ,  Zinfer ISMAGILOV ,  Svetlana Letizia YASHNIK ,  Anton SALNIKOV ,  Mikhail KERZHENTSEV ,  Valentin PARMON

IPC分类号： C07C7/148 ,  B01J35/02 ,  B01J23/885 ,  B01J23/00 ,  B01J35/00 ,  B01D53/48 ,  B01D53/86 ,  C10G27/04 ,  B01J23/80 ,  B01J23/887 ,  B01J35/08 ,  B01J35/10 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08

摘要： A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide with a spinel formula, and crystals of ZnO, CuO, and at least one Group VIB metal oxide, and preferably, at least one acidic oxide of B, P. or Si, as well. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.

公开(公告)号：US20210139391A1

公开(公告)日：2021-05-13

申请号：US17153016

申请日：2021-01-20

申请人： Lummus Technology LLC

发明人： Raed Hasan Abudawoud ,  Anthony Crisci ,  David C. Grauer ,  William Michalak ,  Greg Nyce ,  Tim A. Rappold ,  Aihua Zhang ,  Richard Black ,  Peter Czerpak ,  Bipinkumar Patel ,  Guido Radaelli

IPC分类号： C07C2/12 ,  C07C2/42 ,  C07C2/10 ,  C07C15/067 ,  C07B37/10 ,  C07C27/10 ,  C07B41/02 ,  C07B41/04 ,  C07B37/04 ,  C07C9/14 ,  C07C29/04 ,  C10G50/00 ,  C10G29/20 ,  C10G27/04 ,  B01J8/06 ,  C10G29/22

摘要： The present disclosure provides petrochemical processing methods and systems, including ethylene conversion processes and systems, for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compounds, with reduced amount of unsaturated hydrocarbons.

公开(公告)号：US10703998B2

公开(公告)日：2020-07-07

申请号：US16166707

申请日：2018-10-22

申请人： SAUDI ARABIAN OIL COMPANY

发明人： Omer Refa Koseoglu

IPC分类号： C10G67/12 ,  C10G27/00 ,  C10G27/04

摘要： The invention is an integrated process for treating residual oil of a hydrocarbon feedstock. The oil is first subjected to hydrodemetallization and then gas phase oxidative desulfurization. Additional, optional steps including hydrodesulfurization, and hydrocracking, may also be incorporated in to the integrated process.

公开(公告)号：US10267230B2

公开(公告)日：2019-04-23

申请号：US13771444

申请日：2013-02-20

申请人： ROLLS-ROYCE PLC

发明人： John R. Budge

IPC分类号： B01J8/02 ,  B01J8/20 ,  F02C3/24 ,  C10G29/16 ,  F02C3/20 ,  C10G27/04 ,  C10G27/10 ,  C10G75/00 ,  B01J8/00 ,  C10L10/04

摘要： A fuel conditioning apparatus for de-oxygenating a liquid hydrocarbon fuel has a catalyst portion which, in turn, has an inlet portion and an outlet portion. A hydrocarbon fuel stream is fed through the inlet portion and into the catalyst portion where it passes over a catalytically active component. The catalytically active component promotes the reaction of the fuel with the dissolved oxygen in the fuel stream, converting it into less chemically reactive forms and thereby reducing the fuel's propensity to form carbonaceous deposits.

公开(公告)号：US10125319B2

公开(公告)日：2018-11-13

申请号：US13557931

申请日：2012-07-25

申请人： Omer Refa Koseoglu ,  Abdennour Bourane

发明人： Omer Refa Koseoglu ,  Abdennour Bourane

IPC分类号： C10C3/04 ,  C10G27/04 ,  C10G1/00

摘要： An integrated process is provided to produce asphalt and desulfurized oil. Sulfur molecules contained in heavy petroleum fractions, including organosulfur molecules, and in certain embodiments organonitrogen molecules are oxidized. The polar oxidized sulfur compounds shift from the oil phase to the asphalt phase.

公开(公告)号：US09944796B1

公开(公告)日：2018-04-17

申请号：US14628893

申请日：2015-02-23

申请人： PRI Asphalt Technologies, Inc.

发明人： Kenneth F. Grzybowski

IPC分类号： C08L95/00 ,  C08K3/08 ,  C08K3/10 ,  C08L91/06 ,  C08K3/32 ,  C08K5/01 ,  C10G27/04

CPC分类号： C08L95/00 ,  C08K3/08 ,  C08K3/10 ,  C08K3/32 ,  C08K5/01 ,  C08K2003/0856 ,  C08K2003/0893 ,  C08K2003/329 ,  C10G27/04

摘要： A asphalt binder modifier or a stand-alone asphalt binder and the method of making the asphalt binder or binder modifier are disclosed. The asphalt modifier or binder consisting of treated re-refined engine oil bottoms/VTB's treated by injecting air into re-refining engine oil bottoms/VTB's at temperatures between 150° F. and 550° F. The re-refined engine oil can be processed with ground tire rubber. The binder modifier was blended with various paving and roofing asphalts to form performance-enhanced modified asphalt binders used in paving, roofing, and industrial products.