公开(公告)号：US12125977B2

公开(公告)日：2024-10-22

申请号：US17291624

申请日：2019-11-08

申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

发明人： Elena Molena ,  Christine Hamon ,  Silvia Rita Petricci ,  Giulia Piana ,  Federico Bella ,  Claudio Gerbaldi

IPC分类号： H01M10/0565 ,  H01M10/0525

CPC分类号： H01M10/0565 ,  H01M10/0525 ,  H01M2300/0082 ,  H01M2300/0085

摘要： The present invention relates to a solid electrolyte composition comprising:



a) at least one (per)fuoropolyether comprising a (per)fluoropolyoxyalkylene chain [chain (Rpf)] having two chain ends, wherein at least one chain end has formula (I):

—[CH(J)CH2O]na[CH2CH(J)O]na′—H  (I)

wherein each J is independently H, aryl, straight or branched alkyl, and na and na′, equal to or different from each other, are zero or an integer from 1 to 50, with the proviso that na+na′ is from 1 to 50;
b) a poly(alkylene oxide) comprising chains of formula (II):

R1B—[OCHR1A(CH2)jCHR2A]n—OR2B  (II)

wherein each of R1A and R2A is independently a hydrogen atom or a C1-C5 alkyl group, j is zero or an integer of 1 to 2, R1B and R2B is independently a hydrogen atom or a C1-C3 alkyl group, and n is an integer from 5 to 1000, and
c) at least one lithium salt.

公开(公告)号：US12125976B2

公开(公告)日：2024-10-22

申请号：US16586748

申请日：2019-09-27

申请人： Jae Kwang Kim

发明人： Jae Kwang Kim

IPC分类号： H01M10/0565 ,  H01M10/0525 ,  H01M10/0562

CPC分类号： H01M10/0565 ,  H01M10/0525 ,  H01M10/0562 ,  H01M2300/0068

摘要： A multi-layer structured composite electrolyte for a secondary battery and a secondary battery using the same are provided. The multi-layer structured composite electrolyte is made by laminating two or more layers of a composite electrolyte including a small amount of a liquid electrolyte in a mixture of a polymer and a ceramic material. The multi-layer structured composite electrolyte has the same stability as a solid electrolyte and has the same or better electrochemical properties as or than the liquid electrolyte. Since the multi-layer structured composite electrolyte of the present invention can be folded arbitrarily, the multi-layer structured composite electrolyte may be used in a wearable device.

公开(公告)号：US12125975B2

公开(公告)日：2024-10-22

申请号：US16524684

申请日：2019-07-29

申请人： TeraWatt Technology Inc.

发明人： Ken Ogata ,  Yang Yang ,  Hajime Hoshi ,  Masatsugu Nakano ,  Hiroshi Imoto

IPC分类号： H01M10/0565 ,  H01M10/0567 ,  H01M10/0568 ,  H01M50/411 ,  H01M50/449

CPC分类号： H01M10/0565 ,  H01M10/0567 ,  H01M10/0568 ,  H01M50/411 ,  H01M50/449 ,  H01M2300/0025 ,  H01M2300/0085 ,  H01M2300/0091

摘要： A phase-change electrolyte separator layer can include a non-reactive scaffold that has open spaces. A lithium liquid may be used that transitions into a lithium gel, the lithium liquid can include a mixture of a polymer additive, a cross-linker additive, a lithium salt; and a solvent. The lithium liquid with the polymer additive and the cross-linker additive can be filled into the open spaces within the non-reactive scaffold. The lithium liquid can then be converted into a lithium gel within the non-reactive scaffold following an application of heat while the lithium liquid is within the open spaces within the non-reactive scaffold.

公开(公告)号：US20240347769A1

公开(公告)日：2024-10-17

申请号：US18682316

申请日：2022-08-05

申请人： TDK CORPORATION

发明人： Shinya WATANABE

IPC分类号： H01M10/0565 ,  H01M4/131 ,  H01M4/86 ,  H01M10/052

CPC分类号： H01M10/0565 ,  H01M4/131 ,  H01M10/052 ,  H01M2004/8684

摘要： An all-solid-state battery includes: a laminate in which a positive electrode active material layer, a solid electrolyte layer, and a negative electrode active material layer are laminated in this order; a positive electrode current collector and a negative electrode current collector which sandwich the laminate in a laminating direction; an insulating sheet which surrounds the laminate between the positive electrode current collector and the negative electrode current collector; and a first adhesive sheet which bonds the insulating sheet and the positive electrode current collector or the insulating sheet and the negative electrode current collector, wherein a first through-hole is formed in the first adhesive sheet and the laminate is accommodated in the first through-hole when viewed from the laminating direction of the laminate.

公开(公告)号：US20240332612A1

公开(公告)日：2024-10-03

申请号：US18128933

申请日：2023-03-30

申请人： Rivian IP Holdings, LLC

发明人： Parameswara Rao CHINNAM ,  Saravanan KUPPAN ,  Ashwin Krishna MURALI ,  Inna GUREVITCH ,  Tzu-Ling CHEN ,  Ashish GOGIA

IPC分类号： H01M10/0565 ,  H01M10/0585

CPC分类号： H01M10/0565 ,  H01M10/0585 ,  H01M2300/0082

摘要： Particular embodiments may provide a solid polymer electrolyte. Specifically, disclosed herein are methods and systems that can include feeding polymer precursors and lithium salt to an extruder, kneading the polymer precursors and the lithium salt in the extruder to form a polyurethane that includes the lithium salt dispersed therein, and extruding the polyurethane to form a solid polymer electrolyte.

公开(公告)号：US12100805B2

公开(公告)日：2024-09-24

申请号：US16978765

申请日：2018-06-27

申请人： SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.

发明人： Qiao Shi ,  Qiujun Wang ,  Zhongbo Liu

IPC分类号： H01M10/0565 ,  H01M4/02 ,  H01M4/38 ,  H01M4/505 ,  H01M4/525 ,  H01M4/583 ,  H01M10/0525

CPC分类号： H01M10/0565 ,  H01M4/382 ,  H01M4/386 ,  H01M4/505 ,  H01M4/525 ,  H01M4/583 ,  H01M10/0525 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2300/0082

摘要： Provided is a polymer electrolyte for lithium ion battery and a polymer battery, comprising polyether polymer and lithium salt, wherein the molar ratio of lithium ions in the lithium salt to oxygen atoms in ether bonds of the polyether polymer is more than 1/4; the polyether polymer comprises polymer of Formula 1: A-Rn;



A is a hydrocarbyl group or an oxygen-containing hydrocarbyl group, n is an integer, and n≥1;
R is










Ra and Rb are selected from alkylene, and Rx is selected from organic functional groups and halogen; m1 is a natural number greater than 0, n1 is a natural number, and when n1 is 0, n≥3. Preferably, the ratio of the total number of carbon atoms in all repeating units of the polyether polymer to the total number of repeating units is over 4; More preferably, the polyether polymer has a branched structure.

公开(公告)号：US20240304860A1

公开(公告)日：2024-09-12

申请号：US18595466

申请日：2024-03-05

申请人： Nano and Advanced Materials Institute Limited

发明人： Soon Yee LIEW ,  Ho Mei LAW ,  Fei ZHANG ,  Yu Tat TSE ,  Shengbo LU ,  Li FU ,  Yong ZHU ,  Chenmin LIU ,  Yan Lung WONG

IPC分类号： H01M10/0565 ,  H01M4/66

CPC分类号： H01M10/0565 ,  H01M4/661 ,  H01M2300/0082

摘要： A quasi-solid-state battery formed from non-gas evolving in-situ curing of a quasi-solid-state electrolyte that includes a high swelling polymer made from a monomer with good compatibility with liquid electrolytes, and has a good reactivity for facile non-gas evolving in-situ polymerization. The monomer can be based on acrylate polymerization chemistry or an allyl group polymerization chemistry. Non-gas evolving initiators are used for non-gas evolving in-situ polymerization of acrylate or allyl monomer-based QSE. The resulting QSE additionally has high ionic conductivity, allowing for a high battery output, and a wide electrochemical window (stable for lithium metal anode and high-voltage cathodes). The resulting quasi solid electrolyte battery is not only easy to fabricate using conventional battery manufacturing practices, the non-gas evolving in-situ polymerization causes the QSE to be uniformly distributed within the battery, ensuring high-quality, safe battery performance and longevity.

公开(公告)号：US20240301145A1

公开(公告)日：2024-09-12

申请号：US18667185

申请日：2024-05-17

申请人： Blue Current, Inc.

发明人： Joanna Burdynska ,  Alexander Teran ,  Benjamin Rupert ,  Eduard Nasybulin

IPC分类号： C08G81/02 ,  C08K3/30 ,  C08K3/40 ,  H01B1/22 ,  H01M4/04 ,  H01M4/50 ,  H01M4/505 ,  H01M4/52 ,  H01M4/525 ,  H01M4/58 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/056 ,  H01M10/0562 ,  H01M10/0565 ,  H01M50/403

CPC分类号： C08G81/024 ,  C08K3/30 ,  C08K3/40 ,  H01B1/22 ,  H01M4/04 ,  H01M4/50 ,  H01M4/52 ,  H01M4/5805 ,  H01M4/622 ,  H01M10/0525 ,  H01M10/056 ,  H01M10/0562 ,  H01M10/0565 ,  H01M50/403 ,  C08K2003/3009 ,  H01M4/505 ,  H01M4/525 ,  H01M2300/0068 ,  H01M2300/0074 ,  H01M2300/0082

摘要： Provided herein are methods of forming solid-state ionically conductive composite materials that include particles of an inorganic phase in a matrix of an organic phase. The methods involve forming the composite materials from a precursor that is polymerized in-situ after being mixed with the particles. The polymerization occurs under applied pressure that causes particle-to-particle contact. In some embodiments, once polymerized, the applied pressure may be removed with the particles immobilized by the polymer matrix. In some implementations, the organic phase includes a cross-linked polymer network. Also provided are solid-state ionically conductive composite materials and batteries and other devices that incorporate them. In some embodiments, solid-state electrolytes including the ionically conductive solid-state composites are provided. In some embodiments, electrodes including the ionically conductive solid-state composites are provided.

公开(公告)号：US20240297354A1

公开(公告)日：2024-09-05

申请号：US18595391

申请日：2024-03-04

申请人： The Regents of the University California

发明人： Jennifer Lu ,  Michael Leveille ,  Han-Lin Kuo ,  Lexi Hefner

IPC分类号： H01M10/42 ,  C08F292/00 ,  C08G81/00 ,  H01M10/0565 ,  H01M50/383

CPC分类号： H01M10/4235 ,  C08F292/00 ,  C08G81/00 ,  H01M10/0565 ,  H01M50/383 ,  H01M2300/0082

摘要： Solid-state polymer electrolyte systems and methods of making the same are disclosed. The solid-state polymer electrolyte can be a multi-segmented polymer that includes two high-contrast segments. The high-contrast segments can be, respectively, soft segments and one or more hard segments. Batteries with a solid-state polymer electrolyte system is also disclosed.

公开(公告)号：US12074285B2

公开(公告)日：2024-08-27

申请号：US17457971

申请日：2021-12-07

申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA ,  SHANGHAI JIAO TONG UNIVERSITY

发明人： Jun Yang ,  Zhixin Xu ,  Yixi Kuai ,  Koji Suto

IPC分类号： H01M10/056 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/44

CPC分类号： H01M10/0565 ,  H01M10/052 ,  H01M10/44 ,  H01M2300/0082 ,  H01M2300/0085

摘要： The present disclosure provides an aqueous polymer electrolyte comprising a polymer electrolyte of a polymer of a single lithium salt, or a polymer of a single lithium salt and short-chain dimethylsiloxane or single fluoro ether, and water. The present disclosure further provides a lithium rechargeable battery comprising such an aqueous polymer electrolyte.