公开(公告)号：WO2017205327A1

公开(公告)日：2017-11-30

申请号：PCT/US2017/033927

申请日：2017-05-23

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： WENZEL, Jeffrey, D. ,  PETR, Michael, T. ,  MIRGON, Mark ,  TUDOR, Jay, M. ,  CRABTREE, Sam, L. ,  FENG, Jie

IPC: B29C57/04

Abstract: An apparatus comprising: (a) a mandrel; (b) an internal guide spaced apart from the mandrel; (c) an external guide extending around all or a portion of the internal guide and being spaced apart from the mandrel; wherein a pipe extends between the internal guide and the external guide and then over the mandrel so that the mandrel changes one or more dimensions of the pipe.

Abstract translation: 一种装置，包括：（a）心轴; （b）与心轴间隔开的内部导向件; （c）围绕所述内部引导件的全部或一部分延伸并且与所述心轴间隔开的外部引导件; 其中管在内部引导件和外部引导件之间延伸，然后在心轴上方延伸，使得心轴改变管道的一个或多个尺寸。

公开(公告)号：WO2016106055A1

公开(公告)日：2016-06-30

申请号：PCT/US2015/066230

申请日：2015-12-17

Applicant: ROHM AND HAAS COMPANY

Inventor： PETR, Michael, T. ,  CRUZ, Carlos, A.

IPC: C08F12/08 ,  C08L51/00 ,  C08F265/06 ,  C08F285/00 ,  C08K5/57 ,  C08L27/06

CPC classification number: C08F265/06 ,  C08F285/00 ,  C08L27/06 ,  C08L51/003 ,  C08F2/22 ,  C08F220/12

Abstract: An impact modifier composition comprising one or more core/shell polymers which comprise a crosslinked core having from 98 to 99.9 wt% units derived from one or more acrylate monomers and from 0.1 to 2 wt% units derived from a crosslinker containing a vinylically unsaturated moiety with an acrylate free radical reactivity ratio from 0.8 to 1.2 and one or more non- acrylate vinylically unsaturated moiety(ies) with an acrylate free radical reactivity ratio(s) greater than 1, wherein the crosslinked core has a swell ratio in THF between 7 and 15 and a Tg equal to less than 10°C; and a shell having from 20 to 100 wt% units derived from one or more (meth)acrylate monomers and having a Tg of greater than 20 °C is provided. Also provided is a polymer composition comprising the impact modifier composition and a base structural polymer.

Abstract translation: 一种抗冲改性剂组合物，其包含一种或多种芯/壳聚合物，其包含交联核心，其具有98至99.9重量％的衍生自一种或多种丙烯酸酯单体的单元和0.1至2重量％的衍生自含有乙烯基不饱和部分的交联剂的单元， 丙烯酸酯自由基活性比为0.8至1.2，以及一种或多种丙烯酸酯自由基反应比（s）大于1的非丙烯酸酯乙烯基不饱和部分，其中交联核的THF中的溶胀比在7至 15和Tg等于小于10℃; 并且提供具有源自一种或多种（甲基）丙烯酸酯单体并且具有大于20℃的Tg的20至100重量％的单元的壳。 还提供了包含抗冲改性剂组合物和基础结构聚合物的聚合物组合物。

公开(公告)号：WO2017040677A1

公开(公告)日：2017-03-09

申请号：PCT/US2016/049719

申请日：2016-08-31

Applicant: ROHM AND HAAS COMPANY

Inventor： PETR, Michael, T. ,  VAN RHEENEN, Paul

IPC: C08K5/00 ,  C08L27/06 ,  C08F110/02 ,  C08F110/06 ,  C08F220/18

CPC classification number: C08L27/06 ,  C08F110/02 ,  C08F110/06 ,  C08F2220/1808 ,  C08F2220/1816 ,  C08K5/00 ,  C08F220/14 ,  C08L33/10

Abstract: A processing aid for foam molding comprising a copolymer obtained by the polymerization of from 50% to 100% by weight total of one or more monomers selected from the group consisting of ethyl methacrylate and propyl methacrylate, and 0 to 50% by weight of other copolymerizable monomers, the copolymer having the following properties: (a) a reduced viscosity measured according to ASTM D2857 at 1 mg/mL in chloroform at 25°C of greater than 8dL/g and (b) a Tg equal to or less than 77 °C is provided.

Abstract translation: 一种用于发泡成型的加工助剂，包括通过聚合反应而获得的共聚物，所述共聚物由总共50％至100％重量的一种或多种选自甲基丙烯酸乙酯和丙烯酸甲酯的单体和0至50％重量的其它可共聚的 单体，所述共聚物具有以下性质：（a）根据ASTM D2857在25℃下在氯仿中以1mg / mL测量的比例大于8dL / g和（b）等于或小于77°的Tg 提供C。

公开(公告)号：WO2016100167A1

公开(公告)日：2016-06-23

申请号：PCT/US2015/065467

申请日：2015-12-14

Applicant: ROHM AND HAAS COMPANY

Inventor： PETR, Michael, T. ,  CRUZ, Carlos, A.

IPC: C08F265/06 ,  C08F285/00 ,  C08L27/06 ,  C08L51/00

CPC classification number: C08F220/12 ,  C08F2/22 ,  C08F265/06 ,  C08F285/00 ,  C08L27/06 ,  C08L51/003 ,  C08F220/40 ,  C08F220/18 ,  C08F2220/1825 ,  C08F220/14

Abstract: A process of emulsion polymerization comprising (a) adding a reactive mixture to a reaction vessel, said reactive mixture comprising water, one or more emulsifiers, one or more acrylate monomers, and a crosslinker having a free radical reactivity ratio of less than 1, (b) providing conditions in which said reactive mixture undergoes emulsion polymerization to form a crosslinked core having a glass transition temperature, Tg, of less than or equal to 10 °C, or in the alternative, wherein the crosslinker is in an amount sufficient such that the crosslinked core has a swell ratio between 8 and 15 in THF and forming a polymer having an original ratio of units derived from the crosslinker to units derived from the acrylate monomer(s); and (c) feeding additional crosslinker during polymerization in an amount sufficient to maintain the original ratio of crosslinker to acrylate monomer(s) is provided. Further disclosed is an impact modifier composition and a polymer composition comprising an impact modifier.

Abstract translation: 一种乳液聚合方法，包括（a）向反应容器中加入反应性混合物，所述反应混合物包含水，一种或多种乳化剂，一种或多种丙烯酸酯单体和具有小于1的自由基反应性比率的交联剂（ b）提供所述反应混合物进行乳液聚合以形成具有小于或等于10℃的玻璃化转变温度Tg的交联核心的条件，或者替代地，其中交联剂的量足以使得 交联核心在THF中具有8-15之间的溶胀比，并形成具有原始交联剂单元与衍生自丙烯酸酯单体的单元的原始比例的聚合物; 和（c）在聚合期间以足以维持交联剂与丙烯酸酯单体的原始比例的量提供额外的交联剂。 进一步公开的是抗冲改性剂组合物和包含抗冲改性剂的聚合物组合物。