公开(公告)号：WO2003100136A2

公开(公告)日：2003-12-04

申请号：PCT/EP2003/005394

申请日：2003-05-23

Applicant: WALTER HILLEBRAND GMBH & CO. GALVANOTECHNIK ,  HILLEBRAND, Ernst-Walter

Inventor： HILLEBRAND, Ernst-Walter

IPC: C25D3/00

CPC classification number: C25D3/562 ,  C25D3/565

Abstract: Die Erfindung betrifft ein alkalisches Galvanisierungsbad sowie ein Verfahren zur kathodischen Abscheidung von Zink-Nickel-Legierungsüberzügen, wobei das Bad ein oder mehrere Polyethylenamine als Komplexbildner enthält. Durch Zugabe eines Arylsulfonats wie etwa Cumolsulfonat oder Xylensulfonat wird die Löslichkeit des Komplexbildners erhöht, bzw. seine lokale Abscheidung an der Kathode vermindert. Hierdurch wird eine Erhöhung der anwendbaren Stromdichte und der Stromausbeute unter Abscheidung homogener Galvanisierungsschichten ermöglicht und die benötigte Arbeitsdauer verkürzt.

Abstract translation: 本发明涉及一种碱性电镀浴和锌 - 镍合金镀层的阴极沉积的方法，其中，所述浴包含一种或多种聚胺作为络合剂。 络合剂的溶解度增加通过加入芳基磺酸酯，如枯烯磺酸盐或二甲苯磺酸盐，或者在阴极处减小其局部沉积。 这将增加适用的电流密度和电流效率允许沉积均匀镀层，并缩短所需的工作时间。

公开(公告)号：WO2002063071A2

公开(公告)日：2002-08-15

申请号：PCT/FR2002/000459

申请日：2002-02-06

Applicant: COVENTYA ,  THIERY, Lionel ,  SCHIAVON, Gian, Luigi ,  POMMIER, Nicolas

Inventor： THIERY, Lionel ,  SCHIAVON, Gian, Luigi ,  POMMIER, Nicolas

IPC: C25D3/56

CPC classification number: C25D3/565

Abstract: Bain constitué d'une solution aqueuse acide, exempte d'ion ammonium, d'ions fluoroborate et d'ion citrate et comprenant par litre: de 10 à 60 g d'ions Zn 2+ ; de 20 à 100 g d'ions Mn 2+ ; caractérisé en ce qu'il comprend un agent tampon maintenant le pH à une valeur comprise entre 3,0 et 7 et, de préférence, entre 4,5 et 6 et mieux encore entre 4,8 et 5,5 et un autre agent, distinct de l'agent tampon, permettant de rapprocher les potentiels de déposition du couple Zn/Zn 2+ et du couple Mn/Mn 2+ . Ce bain est utile pour déposer un alliage de Zn et de Mn par électrolyse.

Abstract translation: 本发明涉及包含不含铵离子，氟硼酸根离子或柠檬酸根离子并含有每升的10至60g Zn 2+离子和20至100g Mn 2+离子的酸性水溶液的浸渍液。 本发明的特征在于其包含缓冲剂，其将pH值保持在3至7之间，优选4.5至6或更好，仍为4.8至5.5之间，另一种不同于所用缓冲剂的试剂 将Zn / Zn 2+耦合到Mn / Mn 2+的沉积电位。 本发明的浸渍用于通过电解沉积Zn和Mn合金。

公开(公告)号：WO0204713A3

公开(公告)日：2002-08-15

申请号：PCT/EP0107876

申请日：2001-07-09

Applicant: BASF AG ,  BRODT GREGOR ,  HAAS JENS ,  HESSE WERNER ,  JAEGER HANS-ULRICH

Inventor： BRODT GREGOR ,  HAAS JENS ,  HESSE WERNER ,  JAEGER HANS-ULRICH

IPC: C25D3/22 ,  C25D3/56 ,  C25D5/26

CPC classification number: C25D3/565 ,  C25D3/22

Abstract: The invention relates to a method for electrolytically coating metalswith zinc or a zinc alloy. Matt surfaces are obtained by depositing zinc from an electrolyte solution containing a zinc salt selected from zinc sulphate or an alkane sulphate of zinc or mixtures thereof and optionally other metal salts, an acid selected from sulphuric acid or an alkane sulphonic acid or a mixture of both acids and at least one additive for improving surface roughness and for avoiding dendritic edge growth, selected from surface active compounds containing nitrogen which can be ionic or non-ionic, anionic surface active compounds containing nitrogen, and surface active compounds derived from multi-fuctional alcohols with at least three hydroxy groups. The invention also relates to an electrolytic composition for an electrolytically coating of metals with zinc or zinc alloys, in addition to the use of the above-mentioned additives for improving surface roughness and avoiding dentritic edge growth when metals are electrolytically coated with zinc or a zinc alloy in an electrolyte containing alkane sulphonic acid.

Abstract translation: 本发明涉及的具有锌或锌合金，其特征在于，获得无光泽的表面的金属的电解涂覆的方法，通过从包含锌盐的电解质溶液从硫酸锌或锌或它们的混合物的链烷磺酸或其选定锌的沉积，并且任选地进一步 金属盐，从硫酸或链烷磺酸或两种酸的混合物中的酸，和用于改善表面粗糙度和防止树枝状边缘生长的至少一种添加剂，从含氮表面活性化合物选择了不能是离子或含阴离子表面活性化合物的硫和 表面活性化合物，选自具有至少三个羟基基团官能醇开始。 此外，本发明涉及的具有锌或锌合金的金属的电解涂覆的电解质组合物，以及作为用于提高表面粗糙度和防止与锌或锌合金的金属的电解涂覆树突边缘生长在链烷酸的使用，所述添加剂 电解质。

公开(公告)号：WO02022913A2

公开(公告)日：2002-03-21

申请号：PCT/EP2001/009452

申请日：2001-08-16

IPC: C22C13/00 ,  C22C18/00 ,  C25D3/56 ,  C25D3/60 ,  C25D5/26 ,  C25D7/00 ,  C25D3/00

CPC classification number: C25D3/565 ,  C22C13/00 ,  C22C18/00 ,  C25D3/60

Abstract: The invention relates to ternary tin zinc alloy coatings 30 - 65 wt. % tin, 30 - 65 wt. % zinc and 0.1 - 15 wt . % metal from the following group as a third alloy component; iron, cobalt, nickel. Correspondingly, alloy coatings can be produced by means of electrolytic deposition from aqueous galvanic electroplating solutions which contain the components of the alloy in a dissolved form. The alloy coatings are characterised in that they have a particularly high resistance to corrosion and are particularly suitable as anti-corrosion protective coatings on iron-based materials.

Abstract translation: 本发明涉及30至65重量％的锡，30至65重量％的锌和0.1〜15％（重量）选自铁，钴，镍合金作为第三成分的金属的组合物的三元锡 - 锌合金。 对应的合金层可以通过从含有溶解形式的合金组分水性镀电解槽电解沉积来制造。 合金层的特征在于特别高的耐腐蚀性，因此特别适合作为黑色金属材料的防腐蚀保护涂层。

公开(公告)号：WO02004713A2

公开(公告)日：2002-01-17

申请号：PCT/EP2001/007876

申请日：2001-07-09

IPC: C25D3/22 ,  C25D3/56 ,  C25D5/26

CPC classification number: C25D3/565 ,  C25D3/22

Abstract: The invention relates to a method for electrolytically coating metalswith zinc or a zinc alloy. Matt surfaces are obtained by depositing zinc from an electrolyte solution containing a zinc salt selected from zinc sulphate or an alkane sulphate of zinc or mixtures thereof and optionally other metal salts, an acid selected from sulphuric acid or an alkane sulphonic acid or a mixture of both acids and at least one additive for improving surface roughness and for avoiding dendritic edge growth, selected from surface active compounds containing nitrogen which can be ionic or non-ionic, anionic surface active compounds containing nitrogen, and surface active compounds derived from multi-fuctional alcohols with at least three hydroxy groups. The invention also relates to an electrolytic composition for an electrolytically coating of metals with zinc or zinc alloys, in addition to the use of the above-mentioned additives for improving surface roughness and avoiding dentritic edge growth when metals are electrolytically coated with zinc or a zinc alloy in an electrolyte containing alkane sulphonic acid.

Abstract translation: 本发明涉及的具有锌或锌合金，其特征在于，获得无光泽的表面的金属的电解涂覆的方法，通过从包含锌盐的电解质溶液从硫酸锌或锌或它们的混合物的链烷磺酸或其选定锌的沉积，并且任选地进一步 金属盐，从硫酸或链烷磺酸或两种酸的混合物中的酸，和用于改善表面粗糙度和防止树枝状边缘生长的至少一种添加剂，从含氮表面活性化合物选择了不能是离子或含阴离子表面活性化合物的硫和 从具有至少三个羟基的多官能醇开始的表面活性化合物。 此外，本发明涉及的具有锌或锌合金的金属的电解涂覆的电解质组合物，以及作为用于提高表面粗糙度和防止与锌或锌合金的金属的电解涂覆树突边缘生长在链烷酸的使用，所述添加剂 电解质。

公开(公告)号：WO0068464A2

公开(公告)日：2000-11-16

申请号：PCT/GB0001703

申请日：2000-05-04

Applicant: ENTHONE OMI INC ,  KEARNEY KEVIN DAVID NICHOLAS ,  VERBERNE WILHEMUS MARIA JOHANN

Inventor： VERBERNE WILHEMUS MARIA JOHANN

IPC: C23C22/27 ,  C25D3/56 ,  C25D5/26

CPC classification number: C25D3/565

Abstract: There is disclosed an electroplating bath for depositing zinc/manganese alloys on a substrate characterized in that it comprises an aqueous bath free or substantially free of ammonium halide and of fluoroborate which is made up from 10-150 g/l, alkali metal salt, 30-90 g/l boric acid, 10-200 g/l water soluble zinc salt, 10-50 g/l water soluble manganese salt, 60-140 g/l alkali metal gluconate or tartrate and a base e.g. an alkali metal hydroxide to bring the pH to the range 6.1-7.1. Passivates are also disclosed.

Abstract translation: 公开了一种用于在基材上沉积锌/锰合金的电镀浴，其特征在于其包含不含或基本上不含卤化铵和氟硼酸盐的水浴，其由10-150g / l的碱金属盐，30 -90g / l硼酸，10-200g / l水溶性锌盐，10-50g / l水溶性锰盐，60-140g / l碱金属葡萄糖酸盐或酒石酸盐和碱例如 碱金属氢氧化物使pH达到6.1-7.1。 钝体也被披露。

公开(公告)号：WO00050669A2

公开(公告)日：2000-08-31

申请号：PCT/GB2000/000592

申请日：2000-02-21

IPC: C25D3/22 ,  C25D3/56

CPC classification number: C25D3/565 ,  C25D3/22

Abstract: A polymer additive for alkaline zinc and zinc alloy electrodepositing media and processes comprises the reaction product of one or both of (i) a first di-tertiary amine of formula (1) where R' represents (a) or (b), and q is 2 to 6, R represents CH3 or C2H5 and each R may be the same or different and m is 2 to 4, and a second di-tertiary amine of formula (2) where B is CgH2g+1 and g = 0 or an integer, the respective B groups being the same or different, and f = 0 or an integer, and R'' represents CH3 or C2H5 and each R'' may be the same or different, with (ii) a di-halo alkane of the formula (4): A - (CH2)n - A, where A represents a halogen atom and n is at least 2. The resulting polymer preferably has general structure (I) where 0

Abstract translation: 用于碱性锌和锌合金电沉积和工艺的聚合物助剂包括（i）和/或（ii）的反应产物，它们是：（i）第一二胺， 式（1）的叔化合物，其中R'表示结构（a）或（b）且q为2至6; R代表CH 3或C 2 H 5，每个R可以相同或不同; m在2和4之间; 和式（2）的第二种二叔胺，其中B是CgH2g + 1; 并且g是0或整数; 各组B可以相同或不同; f是0或整数; 和R“是CH3或C2H5; 每个R“相同或不同; 与（ii）式（4）的二卤代烷烃：A-（CH 2）n -A，其中A代表卤素原子且n至少为2.所得聚合物优选具有结构（I ）其中0≤x≤1且0≤y≤1; 并让（x或y）或（x和y）等于1; 当y为0时z至少为2; 并且n至少为3。

公开(公告)号：WO0011244A3

公开(公告)日：2000-06-29

申请号：PCT/EP9906035

申请日：1999-08-18

Applicant: SCHLOETTER FA DR ING MAX ,  FETZER KARL ,  PFIZ ROLAND ,  STRUBE GERNOT

Inventor： FETZER KARL ,  PFIZ ROLAND ,  STRUBE GERNOT

IPC: C25D3/56 ,  C25D5/10

CPC classification number: C25D5/10 ,  C25D3/565

Abstract: The invention relates to a coating for components made of hardened steel or cast iron, which comprises two layers. The inner layer consists of either a zinc-cobalt alloy preferably containing between 0.1 and 6 % by weight Co or a zinc-nickel alloy preferably containing between 0.5 and 15 % by weight Ni. The outer layer is a zinc-nickel alloy preferably containing between 6 and 18 % by weight Ni. The present invention further relates to a method for producing said coating, according to which the inner layer is electrodeposited from an acid bath and the outer layer is electrodeposited from an alkaline bath.

Abstract translation: 本发明描述了由硬化钢或铸铁，其包括两个层的组分的涂层。 内层由任一锌 - 钴合金用的优选0.1-6重量％的Co或优选0.5-15重量％的Ni的锌 - 镍合金制成。 外层是锌 - 镍合金，优选6-18重量％的Ni。 本发明还描述了一种用于制备这种涂层的方法，其中所述内层由电解酸浴，并从碱性电解槽外层沉积的方法。

公开(公告)号：WO1997046733A1

公开(公告)日：1997-12-11

申请号：PCT/JP1996001537

申请日：1996-06-06

Applicant: SUMITOMO METAL INDUSTRIES, LTD. ,  NAGAI, Hiroyuki ,  KAWANISHI, Yoshihiro ,  KAJIYAMA, Eiji ,  KASHIWAGI, Hiroyuki ,  TSUCHIYA, Shinichi

Inventor： SUMITOMO METAL INDUSTRIES, LTD.

IPC: C23C28/00

CPC classification number: C23C28/3225 ,  C23C22/24 ,  C23C22/30 ,  C23C28/00 ,  C23C28/345 ,  C25D3/565 ,  C25D11/38 ,  Y10S428/935 ,  Y10T428/12493 ,  Y10T428/12569 ,  Y10T428/12611 ,  Y10T428/12799 ,  Y10T428/249923

Abstract: Object: to develop a material which can be improved in the resistance to corrosion caused by alcoholic fuels after working without detriment to the weldability and without any substantial cost increase. Constitution: a chromate coating is formed on Zn-X-alloy electroplated steel sheets (wherein X is at least one element selected among 3-18 wt.% Ni, 0.02-3 wt.% Co, 25-45 wt.% Mn, and 8-20 wt.% Cr). The crack density of the Zn-X-alloy coating present under the chromate coating is 1,000-150,000/mm in terms of the spot surrounded by the cracks, among which cracks having the maximum width of 0.5 mu m or less account for at least 90 % and cracks whose depths are at least 80 % of the coating thickness account for at least 80 %.

Abstract translation: 目的：开发可以改善在工作后由酒精燃料引起的耐腐蚀性的材料，而不损害可焊性并且没有任何显着的成本增加。 结构：在Zn-X合金电镀钢板上形成铬酸盐涂层（其中X是选自3-18重量％的Ni，0.02-3重量％的Co，25-45重量％的Mn中的至少一种元素， 和8-20重量％的Cr）。 存在于铬酸盐涂层下的Zn-X合金涂层的裂纹密度在由裂纹包围的点上为1,000-150,000 / mm 2，其中最大宽度为0.5μm或更小的裂纹占 至少90％，并且其深度至少为涂层厚度的80％的裂纹至少为80％。

公开(公告)号：WO1987000212A1

公开(公告)日：1987-01-15

申请号：PCT/US1986001396

申请日：1986-06-27

Applicant: SQUARE D COMPANY

Inventor： SQUARE D COMPANY ,  SIMON, Richard, B. ,  WOLSKI, Adam, M. ,  CHENG, Chintsai, T. ,  GAMBHIRWALA, Manoj, C.

IPC: C25D05/10

CPC classification number: C25D3/565 ,  C25D5/10 ,  C25D5/16 ,  H05K3/384 ,  H05K2201/0355 ,  H05K2203/0307 ,  H05K2203/0723 ,  Y10T428/12569 ,  Y10T428/12646 ,  Y10T428/12792 ,  Y10T428/1291 ,  Y10T428/12986

Abstract: An improved treatment for copper foil that is to be used for lamination to a board comprises electrodepositing a dendritic layer of copper on the side of the foil that is to be laminated to the board. The dendritic layer is secured by electrodepositing a gilding layer of copper over it. A barrier layer is next electrodeposited over the gilding layer. The barrier layer is formed by means such as electrodeposition from a solution containing ions of zinc, nickel and antimony. This in turn is covered with an anticorrosion layer that is formed of chromates or phosphates, disposed over the barrier layer.