摘要:
There is described a polysiloxane having the structure: wherein R 1 , R 2 , and R 3 are independently a hydrocarbon radical, an unsaturated radical, an alkoxy radical, an aryl radical or an alkenyloxy radical, R 4 is independently a direct bond or hydrocarbon radical optionally substituted with oxygen and nitrogen, R 5 is independently a hydrogen, a halogen, an aliphatic group having from 1 to 6 carbon atoms, an aromatic group having 6 to 8 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, or an aryloxy group, R 6 is independently a hydroxyl group, an amine group, an acid chloride group, or a sulfonyl halide group, x is from 1 to 300; y is from 0 to 50; and z is from 0 to 50. The polysiloxane is used to make various copolymers and polymer blends. A variety of articles can be made using the polysiloxane described as a polymer blend or copolymer.
摘要:
The present invention relates to a process for preparing polysiloxane-polycarbonate block cocondensates proceeding from specific polycarbonates and hydroxyaryl-terminated polysiloxanes in presence of a salt of a weak acid.
摘要:
The present invention relates to a process for preparing polysiloxane-polycarbonate block cocondensates proceeding from specific polycarbonates and hydroxyaryl-terminated polysiloxanes. More particularly, the present invention relates to the preparation of the said block cocondensates by means of a reactive extrusion.
摘要:
본 발명은 폴리오르가노실록산 화합물, 제조방법 및 이를 포함하는 코폴리카보네이트 수지에 관한 것으로, 본 발명에 따르면 다양한 용도에 적용 가능하고, 특히 코폴리카보네이트 수지의 충격보강제, 개질제 또는 공단량체로 사용 가능한 폴리오르가노실록산 화합물 및 이를 포함하고 투명도를 유지하면서 저온 충격강도를 포함한 기계적 물성이 개선된 코폴리카보네이트 수지를 제공하는 효과가 있다.
摘要:
본 발명은 신규 폴리실록산, 그 제조방법 및 이를 포함하는 폴리카보네이트-폴리실록산 공중합체에 관한 것이다. 상기 폴리실록산은 청구항 1의 화학식 1로 표시되는 것을 특징으로 한다. 상기 폴리실록산은 전자 밀도를 감소시킨 말단기를 적용하여 저온 내충격성 및 황색도(yellowness index)를 개선할 수 있다.
摘要:
Disclosed herein is a process for preparing a linear hydroxyaryloxy-functional polydiorganosiloxanes having controlled structures. The process includes the step of reacting a linear α,ω-bisacyloxypolydiorganosiloxane with at least one bisphenolic compound, or hydroxy-functional oligomer thereof, in such a molar ratio that the phenolic groups in the bisphenolic compound or the hydroxy-functional oligomer thereof to the acyloxy groups in the α,ω-bisacyloxypolydiorganosiloxane is less than 2.0. Also disclosed are hydroxyaryloxy-functional polydiorganosiloxanes produced from the process and the polysiloxane/polyorgano block copolymers made using the hydroxyaryloxy-functional siloxanes.
摘要:
In some embodiments, a pressure vessel comprises a rounded container comprising a thermoplastic composition. The thermoplastic composition comprises a siloxane copolymer having a structural unit of the formula (11 )where x and y are integers representing the number of repeating units; and x is at least 1. The pressure vessel is configured to receive a fluid at an operating pressure of greater than or equal to 2 bar.
摘要:
Disclosed herein is a process for the production of a polysiloxane-polyorgano block copolymer. The process includes reacting a reaction mixture containing (a) an ester- functional polydiorganosiloxane and (b) a bisphenolic compound or a bisphenolic compound oligomer. This process has the advantage of yielding block copolymers with controlled block structures and avoiding the impurities that may be carried over from the conventional hydroxyaryloxy-terminated-polydiorganosiloxanes. Also disclosed are ester-functional polysiloxanes and polysiloxane-polyorgano block copolymers prepared by the process of the invention. These copolymers exhibit advantageous properties such as improved low temperature properties, improved rheological properties during molding, improved clarity, chemical, scratch resistance, and improved electrical insulation properties.
摘要:
Embodiments of the present invention provide various multipolymers and permselective membranes for use with biosensors and other implantable medical devices and prostheses. Embodiments of the present invention may provide structural strength and integrity, and further may control the influx of glucose, oxygen and/or water. Embodiments of the present invention may, for example, minimize or reduce the influx of glucose by minimizing the percentage of hydrophilic segments, which in turn minimizes the percentage of water uptake and the degree of glucose transport.