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1.发明申请CATALYST COMPOSITION AND PROCESS FOR DI-, TRI- AND/OR TETRAMERIZATION OF ETHYLENE 审中-公开催化剂组合物和乙烯二异氰酸酯和/或叔丁基化方法公开(公告)号：WO2009006979A3
公开(公告)日：2009-03-26
申请号：PCT/EP2008004815
申请日：2008-06-16
Applicant: LINDE AG , SAUDI BASIC IND CORP , MUELLER BERND H , FRITZ PETER M , BOELT HEINZ , WOEHL ANINA , MUELLER WOLFGANG , WINKLER FLORIAN , WELLENHOFER ANTON , ROSENTHAL UWE , HAPKE MARKO , PEULECKE NORMEN , AL-HAZMI MOHAMMED HASSAN , ALIYEV VUGAR O , MOSA FUAD MOHAMMED
Inventor： MUELLER BERND H , FRITZ PETER M , BOELT HEINZ , WOEHL ANINA , MUELLER WOLFGANG , WINKLER FLORIAN , WELLENHOFER ANTON , ROSENTHAL UWE , HAPKE MARKO , PEULECKE NORMEN , AL-HAZMI MOHAMMED HASSAN , ALIYEV VUGAR O , MOSA FUAD MOHAMMED
CPC classification number: B01J31/2495 , B01J31/143 , B01J31/1885 , B01J31/189 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07F9/224 , C07F9/46 , C07F9/4883 , C07F9/65848 , C07F9/6587 , Y02P20/52 , C07C11/107
Abstract: The present invention relates to a catalyst composition and a process for di-, tri- and/or tetramerization of ethylene, wherein the catalyst composition comprises a chromium compound, a ligand of the general structure (A) R1R2P -N(R3)-P(R4)-N(R5)-H or (B) R1R2P- N(R3-P(R4)-N(R5)-PR6R7, or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNPNP -unit is member of a ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution and a co-catalyst or activator.
Abstract translation: 本发明涉及一种催化剂组合物和乙烯二，三和/或四聚的方法，其中催化剂组合物包含铬化合物，通式结构的配体（A）R 1 R 2 P -N（R 3）-P （R4）-N（R5）-H或（B）R1R2P-N（R3-P（R4）-N（R5）-PR6R7或（A）和（B））的任何环状衍生物，其中至少一个 PNPN单元或PNPNP单元的P或N原子是环系的成员，环体系由一种或多种结构（A）或（B）的组成化合物通过取代和助催化剂或活化剂 。
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2.发明申请CATALYST FOR OLIGOMERIZATION OF ETHYLENE, METHOD FOR PREPARATION THEREOF AND PROCESS FOR OLIGOMERIZATION USING IT 审中-公开用于乙烯低聚的催化剂，其制备方法和使用其的低分子化方法
公开(公告)号：WO2009121456A8
公开(公告)日：2010-10-21
申请号：PCT/EP2009001518
申请日：2009-03-04
Applicant: LINDE AG , SAUDI BASIC IND CORP , ALIYEV VUGAR O , AL-HAZMI MOHAMMED , MOSA FUAD , ROSENTHAL UWE , MUELLER BERND H , HAPKE MARKO , PEULECKE NORMEN , WOEHL ANINA , FRITZ PETER M , BOELT HEINZ , MUELLER WOLFGANG , WINKLER FLORIAN , WELLENHOFER ANTON
Inventor： ALIYEV VUGAR O , AL-HAZMI MOHAMMED , MOSA FUAD , ROSENTHAL UWE , MUELLER BERND H , HAPKE MARKO , PEULECKE NORMEN , WOEHL ANINA , FRITZ PETER M , BOELT HEINZ , MUELLER WOLFGANG , WINKLER FLORIAN , WELLENHOFER ANTON
CPC classification number: B01J31/1658 , B01J31/189 , B01J2231/20 , B01J2531/62
Abstract: The present invention relates to a catalyst for oligomerization of ethylene, comprising a functionalized solid support; a ligand immobilized on the solid support by chemical bonding, wherein the immobilized ligand has, the structure (R1)(R2)P-N(R3)-P(R4)-Y-support or (R1)(R2)P-N(R3)-P(R4)-N(R5)-P(R6)-Y-support, wherein R1 R2, R3, R4, R5 and R6 are independently selected from aliphatic group, aryl group, amino group and trimethylsilyl group and Y is the functional group of the support or a derivative thereof; and a chromium compound reacted with the ligand.; and to a method for its preparation and a process for oligomerization of ethylene utilizing the catalyst.
Abstract translation: 本发明涉及乙烯低聚催化剂，其包括官能化固体载体; 结构（R1）（R2）PN（R3）-P（R4）-Y-支持或（R1）（R2）PN（R3） - 的固定化配位体固定在固体支持体上的配体， P（R4）-N（R5）-P（R6）-Y-支持物，其中R1R2，R3，R4，R5和R6独立地选自脂族基团，芳基，氨基和三甲基甲硅烷基，Y是官能团 一组支持或其衍生物; 与配位体反应的铬化合物。 以及其制备方法和利用该催化剂使乙烯低聚的方法。
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3.发明申请CATALYST COMPOSITION AND PROCESS FOR DI-, TRI- AND/OR TETRAMERIZATION OF ETHYLENE 审中-公开乙烯的二元，三元和/或四元化催化剂组合物和方法
公开(公告)号：WO2009006979A8
公开(公告)日：2009-12-23
申请号：PCT/EP2008004815
申请日：2008-06-16
Applicant: LINDE AG , SAUDI BASIC IND CORP , FRITZ PETER M , BOELT HEINZ , WOEHL ANINA , MUELLER WOLFGANG , WINKLER FLORIAN , WELLENHOFER ANTON , ROSENTHAL UWE , MUELLER BERND H , HAPKE MARKO , PEULECKE NORMEN , AL-HAZMI MOHAMMED HASSAN , ALIYEV VUGAR O , MOSA FUAD MOHAMMED
Inventor： FRITZ PETER M , BOELT HEINZ , WOEHL ANINA , MUELLER WOLFGANG , WINKLER FLORIAN , WELLENHOFER ANTON , ROSENTHAL UWE , MUELLER BERND H , HAPKE MARKO , PEULECKE NORMEN , AL-HAZMI MOHAMMED HASSAN , ALIYEV VUGAR O , MOSA FUAD MOHAMMED
CPC classification number: B01J31/2495 , B01J31/143 , B01J31/1885 , B01J31/189 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07F9/224 , C07F9/46 , C07F9/4883 , C07F9/65848 , C07F9/6587 , Y02P20/52 , C07C11/107
Abstract: The present invention relates to a catalyst composition and a process for di-, tri- and/or tetramerization of ethylene, wherein the catalyst composition comprises a chromium compound, a ligand of the general structure (A) R1R2P -N(R3)-P(R4)-N(R5)-H or (B) R1R2P- N(R3-P(R4)-N(R5)-PR6R7, or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNPNP -unit is member of a ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution and a co-catalyst or activator.
Abstract translation: 本发明涉及催化剂组合物和乙烯的二 - ，三 - 和/或四聚的方法，其中所述催化剂组合物包含铬化合物，通式结构（A）R 1 R 2 NP（R 3）-P （R）-N（R 5）-H或（B）R 1 R 2 P -N（R 3 -P（R 4）-N（R 5）-PR 6 R 7，或（A）和（B）的任何环状衍生物， PNPN-单元或PNPNP-单元的P或N原子是环体系的成员，所述环体系由结构（A）或（B）的一种或多种构成化合物通过取代和助催化剂或活化剂形成 。
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4.发明申请CATALYST COMPOSITION AND PROCESS FOR DI-, TRI- AND/OR TETRAMERIZATION OF ETHYLENE 审中-公开乙烯的二元，三元和/或四元化催化剂组合物和方法
公开(公告)号：WO2009006979A2
公开(公告)日：2009-01-15
申请号：PCT/EP2008/004815
申请日：2008-06-16
Applicant: LINDE AG , SAUDI BASIC INDUSTRIES CORPORATION , MÜLLER, Bernd, H. , FRITZ, Peter, M. , BÖLT, Heinz , WÖHL, Anina , MÜLLER, Wolfgang , WINKLER, Florian , WELLENHOFER, Anton , ROSENTHAL, Uwe , HAPKE, Marko , PEULECKE, Normen , AL-HAZMI, Mohammed, Hassan , ALIYEV, Vugar, O , MOSA, Fuad, Mohammed
Inventor： MÜLLER, Bernd, H. , FRITZ, Peter, M. , BÖLT, Heinz , WÖHL, Anina , MÜLLER, Wolfgang , WINKLER, Florian , WELLENHOFER, Anton , ROSENTHAL, Uwe , HAPKE, Marko , PEULECKE, Normen , AL-HAZMI, Mohammed, Hassan , ALIYEV, Vugar, O , MOSA, Fuad, Mohammed
CPC classification number: B01J31/2495 , B01J31/143 , B01J31/1885 , B01J31/189 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07F9/224 , C07F9/46 , C07F9/4883 , C07F9/65848 , C07F9/6587 , Y02P20/52 , C07C11/107
Abstract: The present invention relates to a catalyst composition and a process for di-, tri- and/or tetramerization of ethylene, wherein the catalyst composition comprises a chromium compound, a ligand of the general structure (A) R 1 R 2 P -N(R 3 )-P(R 4 )-N(R 5 )-H or (B) R 1 R 2 P- N(R 3 -P(R 4 )-N(R 5 )-PR 6 R 7 , or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNPNP -unit is member of a ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution and a co-catalyst or activator.
Abstract translation: 本发明涉及催化剂组合物和乙烯的二 - ，三 - 和/或四聚的方法，其中所述催化剂组合物包含铬化合物，通式结构（A）的配体， （R 3） - P（R 4） - N（R 3）2 - （R）-H或（B）R 1 R 2 -P N（R 3 -P（R 5） N（R 5） - PR 6 R 7，或（A）和（B）的任何环状衍生物， （B），其中PNPN-单元或PNPNP-单元的P或N原子中的至少一个是环体系的成员，所述环体系由结构（A）或（B）的一种或多种构成化合物形成， 通过取代和助催化剂或活化剂。
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5.发明申请CATALYST FOR OLIGOMERIZATION OF ETHYLENE, METHOD FOR PREPARATION THEREOF AND PROCESS FOR OLIGOMERIZATION USING IT 审中-公开用于乙烯低聚的催化剂，其制备方法和使用其的低分子化方法
公开(公告)号：WO2009121456A1
公开(公告)日：2009-10-08
申请号：PCT/EP2009/001518
申请日：2009-03-04
Applicant: LINDE AG , SAUDI BASIC INDUSTRIES CORPORATION , ALIYEV, Vugar, O. , AL-HAZMI, Mohammed , MOSA, Fuad , ROSENTHAL, Uwe , MÜLLER, Bernd, H. , HAPKE, Marko , PEULECKE, Normen , WÖHL, Anina , FRITZ, Peter, M. , BÖLT, Heinz , MÜLLER, Wolfgang , WINKLER, Florian , WELLENHOFER, Anton
Inventor： ALIYEV, Vugar, O. , AL-HAZMI, Mohammed , MOSA, Fuad , ROSENTHAL, Uwe , MÜLLER, Bernd, H. , HAPKE, Marko , PEULECKE, Normen , WÖHL, Anina , FRITZ, Peter, M. , BÖLT, Heinz , MÜLLER, Wolfgang , WINKLER, Florian , WELLENHOFER, Anton
CPC classification number: B01J31/1658 , B01J31/189 , B01J2231/20 , B01J2531/62
Abstract: The present invention relates to a catalyst for oligomerization of ethylene, comprising a functionalized solid support; a ligand immobilized on the solid support by chemical bonding, wherein the immobilized ligand has, the structure (R 1 )(R 2 )P-N(R 3 )-P(R 4 )-Y-support or (R 1 )(R 2 )P-N(R 3 )-P(R 4 )-N(R 5 )-P(R 6 )-Y-support, wherein R 1 R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from aliphatic group, aryl group, amino group and trimethylsilyl group and Y is the functional group of the support or a derivative thereof; and a chromium compound reacted with the ligand.; and to a method for its preparation and a process for oligomerization of ethylene utilizing the catalyst.
Abstract translation: 本发明涉及乙烯低聚催化剂，其包括官能化固体载体; 结构（R1）（R2）PN（R3）-P（R4）-Y-支持或（R1）（R2）PN（R3） - 的固定化配位体固定在固体载体上的配体， P（R4）-N（R5）-P（R6）-Y-支持物，其中R1R2，R3，R4，R5和R6独立地选自脂族基团，芳基，氨基和三甲基甲硅烷基，Y是官能团 一组支持或其衍生物; 与配位体反应的铬化合物。 以及其制备方法和利用该催化剂使乙烯低聚的方法。
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公开(公告)号：WO2007090412A3
公开(公告)日：2007-08-16
申请号：PCT/EA2007/000001
申请日：2007-02-06
Applicant: SAUDI BASIC INDUSTRIES CORPORATION , ALIYEV, Vugar O. , ABU-RAQABAH, Atieh , AL-KHODAIRI, Fahad , AZIZOV, Akif H. , KHANMETOV, Akber A. , GULIYEV, Bilal, V. , ALIYEVA, Reyhan, V. , RASULOV, Chingiz, K. , IBRAHIMOVA, Minavar, J.
Inventor： ALIYEV, Vugar O. , ABU-RAQABAH, Atieh , AL-KHODAIRI, Fahad , AZIZOV, Akif H. , KHANMETOV, Akber A. , GULIYEV, Bilal, V. , ALIYEVA, Reyhan, V. , RASULOV, Chingiz, K. , IBRAHIMOVA, Minavar, J.
Abstract: The present invention relates to a catalyst composition for the oligomerization of ethylene comprising at least one transition metal bisphenolate compound and at least one cocatalyst. The transition metal bisphenolate is a zirconium bisphenolate. The invention also relates to a process for the oligomerization of ethylene in the presence of the catalyst composition according to the invention. The process results in a high yield of C 4 -C 18 linear alpha-olefm and C 6 -C 10 linear alpha-olefin.
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7.发明申请
公开(公告)号：WO2007090412A2
公开(公告)日：2007-08-16
申请号：PCT/EA2007000001
申请日：2007-02-06
Applicant: SAUDI BASIC IND CORP , ALIYEV VUGAR O , ABU-RAQABAH ATIEH , AL-KHODAIRI FAHAD , AZIZOV AKIF H , KHANMETOV AKBER A , GULIYEV BILAL V , ALIYEVA REYHAN V , RASULOV CHINGIZ K , IBRAHIMOVA MINAVAR J
Inventor： ALIYEV VUGAR O , ABU-RAQABAH ATIEH , AL-KHODAIRI FAHAD , AZIZOV AKIF H , KHANMETOV AKBER A , GULIYEV BILAL V , ALIYEVA REYHAN V , RASULOV CHINGIZ K , IBRAHIMOVA MINAVAR J
CPC classification number: B01J31/223 , B01J31/0214 , B01J31/0215 , B01J31/0235 , B01J31/143 , B01J2231/20 , B01J2531/48 , C07C2/32 , C07C2531/22 , C08F10/00 , C07C11/02 , C08F4/64058
Abstract: The present invention relates to a catalyst composition for the oligomerization of ethylene comprising at least one transition metal bisphenolate compound and at least one cocatalyst. The transition metal bisphenolate is a zirconium bisphenolate. The invention also relates to a process for the oligomerization of ethylene in the presence of the catalyst composition according to the invention. The process results in a high yield of C 4 -C 18 linear alpha-olefm and C 6 -C 10 linear alpha-olefin.
Abstract translation: 本发明涉及用于乙烯低聚的催化剂组合物，其包含至少一种过渡金属双酚盐化合物和至少一种助催化剂。 过渡金属双酚盐是双酚钛。 本发明还涉及在本发明催化剂组合物存在下乙烯低聚的方法。 该方法导致高产率的C 4 -C 18直链α-烯烃和C 6 -C 10亚烷基 >线性α-烯烃。
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8.发明申请PROCESS FOR THE PREPARATION OF LINEAR ALPHA-OLEFINS AND CATALYST USED THEREIN 审中-公开制备线性α-烯烃和其使用的催化剂的方法
公开(公告)号：WO2007026200A1
公开(公告)日：2007-03-08
申请号：PCT/IB2006/002185
申请日：2006-08-10
Applicant: SAUDI BASIC INDUSTRIES CORPORATION , ALIYEV, Vugar, O. , ABU-RAQABAH, Atieh , ZAHOOR, Mohammad
Inventor： ALIYEV, Vugar, O. , ABU-RAQABAH, Atieh , ZAHOOR, Mohammad
CPC classification number: B01J31/2226 , B01J31/04 , B01J31/143 , B01J2231/20 , B01J2531/48 , C07C2/30 , C07C11/02
Abstract: The present invention relates to a process for the preparation of linear low molecular weight alpha-olefins having 4 to 24 carbon atoms, comprising oligomerizing ethylene in an inert solvent in the presence of a catalyst system comprising: (i) zirconium car-boxylate of the formula (R 1 COO) m ZrCl 4-m , wherein R 1 is saturated or unsaturated ali-phatic C 1 -C 10 hydrocarbon or aromatic C 6 -C 14 hydrocarbon and m fulfills 1 ≤ m ≤ 4, (ii) at least one aluminum compound selected from organoaluminum compounds of the formula R 2 n A1X 3-n , wherein R2 is C 1 -C 20 alkyl, X is chlorine, bromine or iodine, and n fulfills 1 ≤ n ≤ 2, and/or aluminoxanes, and (iii) at least two different additives selected from the group consisting of hydrogen, esters, ketones, ethers, amines, anhydrides, phosphines and sulfur compounds; as well as to a catalyst used therein.
Abstract translation: 本发明涉及一种制备具有4至24个碳原子的线型低分子量α-烯烃的方法，包括在惰性溶剂中，在催化剂体系存在下使乙烯低聚，包括：（i）锆 - 式（R 1）COO），其中R 1是饱和或不饱和的脂肪族 C 1 -C 10烃基或芳族C 6 -C 14烃，m满足1 = m = 4 ，（ii）至少一种铝化合物，其选自式R 2的有机铝化合物。
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公开(公告)号：WO2012045426A1
公开(公告)日：2012-04-12
申请号：PCT/EP2011/004914
申请日：2011-10-04
Applicant: SAUDI BASIC INDUSTRIES CORPORATION , SABIC PETROCHEMICALS B.V. , ALIYEV, Vugar O. , HEADAN, Ali Saad , SAINANI, Jaiprakash Brijal
Inventor： ALIYEV, Vugar O. , HEADAN, Ali Saad , SAINANI, Jaiprakash Brijal
IPC: C08F110/02
CPC classification number: C08F10/02 , C08F110/02 , C08F2410/01 , C08F4/24 , C08F4/69 , C08F2500/07 , C08F2500/04 , C08F2500/18 , C08F2500/12
Abstract: The present invention is directed to a process for the production of high density polyethylene by polymerisation of ethylene in the presence of a supported chromium oxide based catalyst which is modified with an organic compound comprising oxygen and a nitrogen atom which is selected from the group consisiting of saturated heterocyclic organic compounds with a five or six membered ring, amino esters and amino alcohols. Such organic compounds allow manufacturing of HDPE with increases molecular weight distribution and increased molecular weight.
Abstract translation: 本发明涉及一种通过在负载的氧化铬基催化剂存在下聚合乙烯生产高密度聚乙烯的方法，该催化剂用包含氧和氮原子的有机化合物进行改性，该有机化合物选自： 具有五或六元环的饱和杂环有机化合物，氨基酯和氨基醇。 这样的有机化合物允许制备具有增加的分子量分布和分子量增加的HDPE。
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10.发明申请PROCESS FOR THE PREPARATION OF LINEAR ALPHA-OLEFINS AND CATALYST USED THEREIN 审中-公开用于制备线性α - 烯烃和其中使用的催化剂的方法
公开(公告)号：WO2007026200B1
公开(公告)日：2007-07-12
申请号：PCT/IB2006002185
申请日：2006-08-10
Applicant: SAUDI BASIC IND CORP , ALIYEV VUGAR O , ABU-RAQABAH ATIEH , ZAHOOR MOHAMMAD
Inventor： ALIYEV VUGAR O , ABU-RAQABAH ATIEH , ZAHOOR MOHAMMAD
CPC classification number: B01J31/2226 , B01J31/04 , B01J31/143 , B01J2231/20 , B01J2531/48 , C07C2/30 , C07C11/02
Abstract: The present invention relates to a process for the preparation of linear low molecular weight alpha-olefins having 4 to 24 carbon atoms, comprising oligomerizing ethylene in an inert solvent in the presence of a catalyst system comprising: (i) zirconium car-boxylate of the formula (R 1 COO) m ZrCl 4-m , wherein R 1 is saturated or unsaturated ali-phatic C 1 -C 10 hydrocarbon or aromatic C 6 -C 14 hydrocarbon and m fulfills 1 = m = 4, (ii) at least one aluminum compound selected from organoaluminum compounds of the formula R 2 n A
Abstract translation: 本发明涉及制备具有4-24个碳原子的直链低分子量α-烯烃的方法，该方法包括在催化剂体系存在下，在惰性溶剂中使乙烯低聚，所述催化剂体系包含：（i） 其中R 1是饱和的或不饱和的脂肪族的脂肪族基团（R 1 CON COO）m ZrCl 4 m m，其中R 1是饱和的或不饱和的脂肪族的 碳氢化合物或芳香族碳氢化合物，其中m满足1 = m = 4 ，（ii）至少一种选自式R 2 CON 2 N
