公开(公告)号：WO2011011098A1

公开(公告)日：2011-01-27

申请号：PCT/US2010/029654

申请日：2010-04-01

申请人： STEPAN COMPANY ,  BERNHARDT, Randal, J. ,  ALONSO, Lourdes, R. ,  DADO, Gregory, P. ,  FILIPOVIC, Eddie, I. ,  GARIEPY, Christopher, A. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  PYTEL, Jacqueline, Maas ,  SAJIC, Branko ,  WEITGENANT, Jeremy, Aaron ,  SHAPIRO, Irene

发明人： BERNHARDT, Randal, J. ,  ALONSO, Lourdes, R. ,  DADO, Gregory, P. ,  FILIPOVIC, Eddie, I. ,  GARIEPY, Christopher, A. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  PYTEL, Jacqueline, Maas ,  SAJIC, Branko ,  WEITGENANT, Jeremy, Aaron ,  SHAPIRO, Irene

IPC分类号： C11D17/00

CPC分类号： C07C309/17 ,  C11D1/143 ,  C11D1/28 ,  C11D1/83 ,  C11D3/0026 ,  C11D3/2093 ,  C11D3/3757

摘要： Compositions comprising sulfo-estolides and alkyl ester sulfonates are described. Detergent formulations, such as laundry detergents, softeners, and other materials, containing any of these materials are disclosed, as well as personal care formulations, hard surface cleaner formulations, and automatic dishwasher detergent formulations. Laundry methods employing these formulations are also disclosed. These formulations are useful as laundry detergents and can be biodegradable, heavy duty liquids, 2X or 3X and up to 6X concentrates, low foaming, and/or effective in a high efficiency washing machine. Methods for laundering fabrics with the compositions are also disclosed.

摘要翻译： 描述了包含磺基内酯和烷基酯磺酸盐的组合物。 公开了含有任何这些材料的洗涤剂制剂，例如衣物洗涤剂，软化剂和其它材料，以及个人护理制剂，硬表面清洁剂制剂和自动洗碗机洗涤剂配方。 还公开了使用这些制剂的洗涤方法。 这些制剂可用作衣物洗涤剂，并且可以是可生物降解的，重载液体，2X或3X和高达6X的浓缩物，低发泡和/或在高效洗衣机中有效。 还公开了用组合物洗涤织物的方法。

公开(公告)号：WO2011010997A1

公开(公告)日：2011-01-27

申请号：PCT/US2009/051294

申请日：2009-07-21

申请人： STEPAN COMPANY ,  BERNHARDT, Randal, J. ,  DADO, Gregory, P. ,  FILIPOVIC, Eddie, I. ,  WEITGENANT, Jeremy, Aaron

发明人： BERNHARDT, Randal, J. ,  DADO, Gregory, P. ,  FILIPOVIC, Eddie, I. ,  WEITGENANT, Jeremy, Aaron

IPC分类号： C07C309/17 ,  C11D1/12 ,  C11D1/28

CPC分类号： C07C309/17 ,  C11D1/123 ,  C11D1/28

摘要： Sulfo-estolides and methods of making them are described. Also described are phase-stable compositions formed from mixtures of different salts of sulfo-estolides, particularly mixtures of sodium and potassium salts of sulfo-estolides, and methods of obtaining phase-stable sulfo-estolide mixed salt compositions. The sulfo-estolide mixed salt compositions can be used in detergent formulations, such as laundry detergents, household, industrial and institutional cleaning formulations, and person care products.

摘要翻译： 描述了磺胺类药物及其制备方法。 还描述了由磺基内酯的不同盐的混合物形成的相稳定组合物，特别是磺基 - 内酯的钠盐和钾盐的混合物，以及获得相稳定的磺基 - 内酯盐混合盐组合物的方法。 磺基 - 内酯混合盐组合物可用于洗涤剂配方中，例如衣物洗涤剂，家用，工业和机构清洁制剂以及人体护理产品。

公开(公告)号：WO1998003262A1

公开(公告)日：1998-01-29

申请号：PCT/US1997012034

申请日：1997-07-17

申请人： STEPAN COMPANY ,  NEPRAS, Marshall, J. ,  BERNHARDT, Randal, J. ,  SPORER, Cathy, J.

发明人： STEPAN COMPANY

IPC分类号： B01J31/12

CPC分类号： C07C209/50 ,  C07C211/08

摘要： Disclosed is a process for the preparation of primary, secondary and tertiary amines with high conversion and high selectivity via low pressure catalytic hydrogenation of unsubstituted, N-substituted, and N,N-disubstituted amides. Amide hydrogenation is conducted using a catalyst system comprising copper chromite and a nucleophilic reagent, in combination with hydrogen gas. The process allows for production of amines which may be directly used as chemical intermediates in the manufacture of surfactants, quaternary ammonium compounds, bactericides, disinfectants, lubricants, petroleum additives, ion exchange resins and the like, without the need of purification, such as distillation.

摘要翻译： 公开了通过未取代的N-取代的和N，N-二取代的酰胺的低压催化氢化制备具有高转化率和高选择性的伯，仲和叔胺的方法。 酰胺氢化使用包含亚铬酸铜和亲核试剂的催化剂体系与氢气组合进行。 该方法允许生产可直接用作制造表面活性剂，季铵化合物，杀菌剂，消毒剂，润滑剂，石油添加剂，离子交换树脂等的化学中间体的胺，而不需要纯化如蒸馏 。

公开(公告)号：WO1997014676A1

公开(公告)日：1997-04-24

申请号：PCT/US1996016648

申请日：1996-10-17

申请人： STEPAN COMPANY ,  TULLY, Paul, S. ,  NEPRAS, Marshall, J. ,  BERNHARDT, Randal, J. ,  HARTLAGE, James, A. ,  MOHRING, William, R.

发明人： STEPAN COMPANY

IPC分类号： C07C303/06

CPC分类号： C07C303/44 ,  C07C303/06 ,  C07C309/31

摘要： Disclosed are processes for preparing linear alkylbenzene sulfonic acids and their corresponding salts comprising: (a) treating a linear alkylbenzene with a sulfonating agent, where the linear alkylbenzene is produced by a reaction between an olefin and benzene; and (b) contacting the sulfonation product of (a) with a mixture of a protic reagent and hydrogen peroxide to result in a sulfonic acid/peroxide mixture.

摘要翻译： 公开了制备直链烷基苯磺酸及其相应盐的方法，其包括：（a）用磺化剂处理直链烷基苯，其中直链烷基苯通过烯烃和苯之间的反应产生; 和（b）使（a）的磺化产物与质子试剂和过氧化氢的混合物接触以产生磺酸/过氧化物混合物。

公开(公告)号：WO1992000283A2

公开(公告)日：1992-01-09

申请号：PCT/US1991000890

申请日：1991-02-14

申请人： STEPAN COMPANY ,  GOZE, Jean, M. ,  BERNHARDT, Randal, J. ,  SAJIC, Branko ,  ROCKWELL, Ned, Miles ,  McCONNELL, Nina, Montserrat ,  MOHRING, William, Richard

发明人： STEPAN COMPANY

IPC分类号： C07D233/86

CPC分类号： D06M15/693 ,  A01N25/30 ,  A23L29/10 ,  A61K8/06 ,  A61K8/445 ,  A61Q5/006 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/00 ,  B01F17/0042 ,  C07C211/63 ,  C07C215/40 ,  C07C233/65 ,  C07C233/69 ,  C08F2/26 ,  C10L1/328 ,  C11D1/10 ,  C11D1/88 ,  C11D3/001 ,  D06M7/00 ,  D06M13/415 ,  D06M2200/40

摘要： The invention encompasses formulated shampoos, surfactant solutions, emulsifier solutions and suspensions comprising effective amounts of salts of general formula (I) wherein R1 and R2 are the same or different and represent alkyl or alkene having 8 to 40 carbon atoms, R3 and R4 are the same as R1 and R2, and R5 and R6 are hydrogen; or R3, R4, R5, and R6 are independently hydrogen, alkyl or alkene having 1 to 40 carbon atoms when R1 and R2 are alkyl or alkene having 14-22 carbon atoms; and X represents ortho, para, or meta substituted phenyl, or alkylene or alkenylene having 0-6 carbon atoms, or cycloalkylene having 5 to 7 carbon atoms. The invention also encompasses formulated conditioning shampoos, surfactant solutions, emulsifier solutions and suspensions comprising effective amounts of mixtures of a salt of formula (I) and an acid of formula (II) wherein R1 and R2 are the same or different and represent alkyl or alkene having 8 to 40 carbon atoms, and X represents ortho, para, or meta substituted phenyl, or alkylene or alkenylene having 0-6 carbon atoms, or cycloalkylene having 5 to 7 carbon atoms.

公开(公告)号：WO2012061101A8

公开(公告)日：2013-05-16

申请号：PCT/US2011057609

申请日：2011-10-25

申请人： STEPAN CO ,  ALLEN DAVE R ,  BERNHARDT RANDAL J ,  BROWN AARON ,  LUEBKE GARY ,  LUKA RENEE ,  MALEC ANDREW D ,  MASTERS RONALD A ,  SKELTON PATTI ,  SOOK BRIAN ,  WEITGENANT JEREMY AARON ,  WOLFE PATRICK SHANE

发明人： ALLEN DAVE R ,  BERNHARDT RANDAL J ,  BROWN AARON ,  LUEBKE GARY ,  LUKA RENEE ,  MALEC ANDREW D ,  MASTERS RONALD A ,  SKELTON PATTI ,  SOOK BRIAN ,  WEITGENANT JEREMY AARON ,  WOLFE PATRICK SHANE

IPC分类号： C11D1/28

CPC分类号： C07C303/32 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61K2800/10 ,  A61Q5/12 ,  A61Q19/00 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C07C309/17 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K8/524 ,  C09K8/74 ,  C09K15/28 ,  C11C3/00 ,  C11C3/003 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/143 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

摘要： Sulfonate compositions are disclosed. The compositions include alkanesulfonates, alkenesulfonates, sultones, and hydroxy-substituted alkanesulfonates. The sulfonates comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1, 18-dioic acid, or their ester derivatives with a sulfonating or sulfitating agent. In one aspect, the sulfonate composition is a sulfo-estolide made by reacting a metathesis-derived C10-C17 monounsaturated acid or octadecene-1,18-dioic acid with a sulfonating agent, optionally in the presence of a saturated fatty acid. The sulfonates are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), paint additives, antimicrobial compositions, agricultural uses, and oil field applications.

摘要翻译： 公开了磺酸盐组合物。 组合物包括烷基磺酸盐，烷基磺酸盐，磺内酯和羟基取代的烷基磺酸盐。 磺酸盐包含一种由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与磺化或硫酸化剂的反应产物。 在一个方面，磺酸盐组合物是通过使选择性衍生的C10-C17单不饱和酸或十八碳烯-1,18-二酸与磺化剂任选在饱和脂肪酸存在下反应而制备的磺基内酯。 磺化物对于各种最终用途是有价值的，包括清洁剂，织物处理，头发调理，个人护理（液体清洁产品，调理棒，口腔护理产品），涂料添加剂，抗微生物组合物，农业用途和油田应用。

公开(公告)号：WO2012061108A1

公开(公告)日：2012-05-10

申请号：PCT/US2011/057622

申请日：2011-10-25

申请人： STEPAN COMPANY ,  ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  MURPHY, Dennis, S. ,  WOLFE, Patrick, Shane ,  BROWN, Aaron

发明人： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  MURPHY, Dennis, S. ,  WOLFE, Patrick, Shane ,  BROWN, Aaron

IPC分类号： C11D3/32

CPC分类号： C11D1/92 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/29 ,  C11D1/62 ,  C11D1/652 ,  C11D1/72 ,  C11D1/74 ,  C11D1/75 ,  C11D1/83 ,  C11D1/86 ,  C11D1/88 ,  C11D1/90 ,  C11D1/94 ,  C11D3/30 ,  C11D3/32 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00 ,  C07C209/14

摘要： Laundry detergents useful for cold-water cleaning and boosted bargain detergents are disclosed. The detergents include a surfactant composition derived from a metathesis-derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. For fatty alkyl ester sulfonate-containing detergents, the composition is selected from C 10 betaines, C 12 or C 16 amidoamines, C 1 2 ethanolamine amides, C 16 amidoamine sulfonates, C 18 diamidoamine dioxides, quaternized C 18 diamidoamine betaines, sulfonated C 18 low-EO fatty ester alkoxylates, C 18 amidoamine carboxylates, and amidoamine oxides and sulfobetaines derived from cross- metathesis of palm or soybean oil. The bargain detergents include a performance booster selected from C 12 low-EO fatty ester alkoxylate sulfonates, C 18 amidoamine oxide esters, C 18 amidoamine oxide carboxylates, and amidoamine sulfobetaines made from self metathesized palm or soybean oil.

摘要翻译： 公开了用于冷水清洗和增强的便宜清洁剂的洗涤剂。 洗涤剂包括衍生自复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物的表面活性剂组合物。 对于含脂肪烷基酯磺酸盐的洗涤剂，组合物选自C10甜菜碱，C12或C16酰氨基胺，C1 2乙醇胺酰胺，C16酰胺胺磺酸盐，C18二酰胺胺二氧化物，季铵化C18二酰胺胺甜菜碱，磺化C18低EO脂肪酸烷基酯，C18 衍生自棕榈油或大豆油的交叉复分解的酰氨基胺氧化物和磺基甜菜碱。 讨价还价洗涤剂包括选自C12低EO脂肪酸酯烷氧基化物磺酸盐，C18酰氨基胺氧化物酯，C18酰氨基胺氧化物羧酸盐和由自身复分解的棕榈油或大豆油制成的酰氨基胺磺基甜菜碱的性能增强剂。

公开(公告)号：WO2012061103A2

公开(公告)日：2012-05-10

申请号：PCT/US2011/057612

申请日：2011-10-25

申请人： STEPAN COMPANY ,  ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  MASTERS, Ronald, A. ,  WOLFE, Patrick, Shane

发明人： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  MASTERS, Ronald, A. ,  WOLFE, Patrick, Shane

IPC分类号： C11D1/12

CPC分类号： C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

摘要： Aqueous hard surface cleaner compositions derived from metathesized natural oil feedstocks are disclosed. In one aspect, the compositions comprise at least one anionic surfactant derived from a metathesis-derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. Particular classes of sulfonated materials (e.g., certain amide sulfonates, sulfonated fatty ester alkoxylates, amidoamine sulfonates, amidoamine betaine sulfonates, sulfo-estolides) are identified as having value as the anionic surfactant. In another aspect, aqueous hard surface cleaners comprising at least one nonionic or amphoteric surfactant derived from a metathesis- derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. Particular classes of these surfactants (e.g., certain amides, imidazoline quat sulfonates, fatty ester alkoxylates, and amine oxides, betaines, amidoamine sulfobetaines) are also identified. The aqueous cleaners noted above rival or outperform commercial baselines in a Gardner straight-line washability test. Industrial degreasers comprising a C 10 or C 12 amide solvent and derived from a metathesis-derived C 10 -C 17 monounsaturated acid are superior to commercial standards.

摘要翻译： 公开了衍生自复分解天然油原料的水性硬表面清洁剂组合物。 在一个方面，组合物包含衍生自复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物的至少一种阴离子表面活性剂。 特定类别的磺化材料（例如某些酰胺磺酸盐，磺化脂肪酸酯烷氧基化物，酰氨基胺磺酸盐，酰氨基胺甜菜碱磺酸盐，磺基 - 卤化物）被鉴定为具有值作为阴离子表面活性剂。 在另一方面，公开了包含衍生自复分解衍生的C10-C17单不饱和酸，十八烯-1,18-二酸或其酯衍生物的至少一种非离子或两性表面活性剂的水性硬表面清洁剂。 还鉴定了这些表面活性剂（例如某些酰胺，咪唑啉季铵盐，脂肪酸烷氧基化物和胺氧化物，甜菜碱，酰氨基胺磺基甜菜碱）的特定类别。 在Gardner直线可洗性试验中，上述水性清洁剂在竞争对手或优于商业基线中得到了证实。 由C10或C12酰胺溶剂组成的衍生自复分解衍生的C10-C17单不饱和酸的工业脱脂剂优于商业标准。

公开(公告)号：WO2011010997A9

公开(公告)日：2012-03-08

申请号：PCT/US2009051294

申请日：2009-07-21

申请人： STEPAN CO ,  BERNHARDT RANDAL J ,  DADO GREGORY P ,  FILIPOVIC EDDIE I ,  WEITGENANT JEREMY AARON

发明人： BERNHARDT RANDAL J ,  DADO GREGORY P ,  FILIPOVIC EDDIE I ,  WEITGENANT JEREMY AARON

IPC分类号： C07C309/17 ,  C11D1/12 ,  C11D1/28

CPC分类号： C07C309/17 ,  C11D1/123 ,  C11D1/28

摘要： Sulfo-estolides and methods of making them are described. Also described are phase-stable compositions formed from mixtures of different salts of sulfo-estolides, particularly mixtures of sodium and potassium salts of sulfo-estolides, and methods of obtaining phase-stable sulfo-estolide mixed salt compositions. The sulfo-estolide mixed salt compositions can be used in detergent formulations, such as laundry detergents, household, industrial and institutional cleaning formulations, and person care products.

摘要翻译： 描述了磺胺类药物及其制备方法。 还描述了由磺基内酯的不同盐的混合物形成的相稳定组合物，特别是磺基 - 内酯的钠盐和钾盐的混合物，以及获得相稳定的磺基 - 内酯盐混合盐组合物的方法。 磺基 - 内酯混合盐组合物可用于洗涤剂配方中，例如衣物洗涤剂，家用，工业和机构清洁制剂以及人体护理产品。

公开(公告)号：WO2010085281A1

公开(公告)日：2010-07-29

申请号：PCT/US2009/051464

申请日：2009-07-22

申请人： STEPAN COMPANY ,  BERNHARDT, Randal, J. ,  ALONSO, Lourdes, R. ,  DADO, Gregory, P ,  PYTEL, Jacqueline, Mass

发明人： BERNHARDT, Randal, J. ,  ALONSO, Lourdes, R. ,  DADO, Gregory, P ,  PYTEL, Jacqueline, Mass

IPC分类号： C11D1/12

CPC分类号： C07C309/17 ,  A61K8/46 ,  A61Q19/10 ,  C07C303/06 ,  C07C303/22 ,  C11D1/008 ,  C11D1/123 ,  C11D1/28 ,  C11D3/0026

摘要： Sulfo-estolides and formulations of sulfo-estolides in and as hard surface cleaners, glass cleaners, toilet bowl cleaners, carpet cleaners, all purpose cleaners, floor cleaners, and others are described. Further details of cleaning performance, stability of diluted and concentrated forms and contemplated cleaning applications are provided.

摘要翻译： 描述了磺基 - 耳塞内酯和作为硬表面清洁剂中的磺基 - 内酯的制剂，玻璃清洁剂，马桶清洁剂，地毯清洁剂，全能清洁剂，地板清洁剂等。 提供清洁性能，稀释和浓缩形式的稳定性以及考虑的清洁应用的更多细节。