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公开(公告)号：WO2015038300A1
公开(公告)日：2015-03-19
申请号：PCT/US2014/051809
申请日：2014-08-20
Applicant: HRD CORPORATION
Inventor： HASSAN, Abbas , HASSAN, Aziz , ANTHONY, Rayford G. , BORSINGER, Gregory G.
IPC: C10K3/02
CPC classification number: C10G49/22 , B01F7/00766 , B01F13/1016 , B01J8/222 , B01J19/1806 , B01J2208/00283 , B01J2219/0011 , B01J2219/00189 , C01B3/22 , C01B3/24 , C01B3/26 , C01B3/50 , C01B2203/0272 , C01B2203/0277 , C01B2203/10 , C01B2203/1041 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247 , C01B2203/1276 , C01B2203/148 , C10G2/30 , C10G2/342 , C10G9/00 , C10G45/00 , C10G45/02 , C10G45/12 , C10G47/00 , C10G47/24 , C10G49/10 , C10G49/20 , C10G50/00
Abstract: Herein disclosed is a method of producing value-added product from light gases, the method comprising: (a) providing light gases comprising at least one compound selected from the group consisting of C1-C6 compounds and combinations thereof; (b) intimately mixing the light gases with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the dispersion is supersaturated with the light gases and comprises gas bubbles at least some of which have a mean diameter of less than or equal to about 5 micron(s); (c) allowing the value-added product to form and utilizing vacuum to extract unreacted light gases from the liquid carrier; (d) extracting the value-added product; wherein the value-added product comprises at least one component selected from the group consisting of higher hydrocarbons, hydrogen, olefins, alcohols, aldehydes, and ketones. A system for producing value-added product from light gases is also disclosed.
Abstract translation: 本文公开了一种从轻质气体生产增值产品的方法，该方法包括：（a）提供包含至少一种选自C1-C6化合物及其组合的化合物的轻质气体; （b）将轻质气体与高剪切装置中的液体载体紧密混合以形成液体载体中的气体分散体，其中该分散体与轻质气体过饱和，并且包括气泡，其中至少一些具有平均直径 小于或等于约5微米; （c）允许增值产品形成和利用真空从液体载体中提取未反应的轻质气体; （d）提取增值产品; 其中所述增值产物包含至少一种选自高级烃，氢，烯烃，醇，醛和酮的组分。 还公开了一种从轻质气体生产增值产品的系统。
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2.发明申请
公开(公告)号：WO2011017118A2
公开(公告)日：2011-02-10
申请号：PCT/US2010/043424
申请日：2010-07-27
Applicant: HRD CORPORATION , HASSAN, Aziz , HASSAN, Abbas , ANTHONY, Rayford, G. , BORSINGER, Gregory
Inventor： HASSAN, Aziz , HASSAN, Abbas , ANTHONY, Rayford, G. , BORSINGER, Gregory
CPC classification number: B01J19/0066 , B01F7/00766 , B01F7/00791 , B01F13/1013 , B01F13/1016 , B01J8/222 , B01J10/00 , B01J10/002 , B01J19/18 , B01J19/1806 , B01J2219/00006 , B01J2219/00168 , B01J2219/00189 , C07C29/152 , C07C31/04
Abstract: A method of producing value-added product from refinery-related gas, the method comprising: providing a refinery-related gas comprising at least one selected from C1-C8 compounds; intimately mixing the refinery-related gas with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the gas bubbles in the dispersion have a mean diameter of less than or equal to about 5m; and extracting value-added product comprising at least one component selected from higher hydrocarbons, olefins and alcohols. A system for producing value-added product from refinery-related gas comprising: at least one high shear device comprising at least one rotor and at least one complementarily-shaped stator; apparatus for the production of a refinery-related gas comprising one or more of C1-C8 compounds; and a pump configured for delivering a liquid stream comprising the liquid carrier to the high shear device.
Abstract translation: 一种由炼油相关气体生产增值产品的方法，所述方法包括：提供炼油相关气体，所述炼油相关气体包含选自C 1 -C 8化合物中的至少一种; 将精炼相关气体与液体载体在高剪切装置中紧密混合以在液体载体中形成气体分散体，其中分散体中的气泡具有小于或等于约5μm的平均直径; 并提取含有至少一种选自高级烃，烯烃和醇的组分的增值产物。 一种用于由炼油相关气体生产增值产品的系统，包括：至少一个高剪切装置，其包括至少一个转子和至少一个互补形状的定子; 用于生产包含一种或多种C1-C8化合物的精炼厂相关气体的设备; 以及构造成将包含液体载体的液体流输送到高剪切装置的泵。
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公开(公告)号：WO2011031424A2
公开(公告)日：2011-03-17
申请号：PCT/US2010/045944
申请日：2010-08-18
Applicant: HRD CORPORATION , HASSAN, Abbas , HASSAN, Aziz , ANTHONY, Rayford , BORSINGER, Gregory
Inventor： HASSAN, Abbas , HASSAN, Aziz , ANTHONY, Rayford , BORSINGER, Gregory
IPC: C07C51/265 , C07C51/42 , C07C51/43 , C07C63/15 , B01J8/02
CPC classification number: B01F7/00766 , B01F13/1013 , B01F13/1016 , C07C51/265 , C07D307/89 , C07C63/16 , C07C63/06 , C07C63/24 , C07C63/26
Abstract: Herein disclosed is a method, comprising: forming a dispersion under high shear comprising gas bubbles of an oxidant dispersed in a liquid phase, wherein the bubbles have a mean diameter of less than 1.5 micron; and contacting the dispersion with an oxidation catalyst to produce a product stream, wherein the product stream comprises a substance selected from the group consisting of dicarboxylic acid, benzoic acid, 2- methylbenzoic acid, 3- methylbenzoic acid, 4-methylbenzoic acid, and phthalic anhydride. In some cases, forming the dispersion under high shear comprises introducing the oxidant and the liquid phase into a high shear device comprising at least one rotor and at least one complementarily-shaped stator. Herein also disclosed is a system for producing a substance selected from the group consisting of dicarboxylic acid, benzoic acid, 2- methylbenzoic acid, 3- methylbenzoic acid, 4-methylbenzoic acid, and phthalic anhydride.
Abstract translation: 本文公开了一种方法，包括：在高剪切下形成分散体，其包含分散在液相中的氧化剂气泡，其中气泡的平均直径小于1.5微米; 并使分散体与氧化催化剂接触以产生产物流，其中产物流包含选自二羧酸，苯甲酸，2-甲基苯甲酸，3-甲基苯甲酸，4-甲基苯甲酸和邻苯二甲酸的物质 酐。 在一些情况下，在高剪切下形成分散体包括将氧化剂和液相引入到包括至少一个转子和至少一个互补形状的定子的高剪切装置中。 本文还公开了一种制备选自二羧酸，苯甲酸，2-甲基苯甲酸，3-甲基苯甲酸，4-甲基苯甲酸和邻苯二甲酸酐的物质的体系。
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公开(公告)号：WO2011017158A3
公开(公告)日：2011-02-10
申请号：PCT/US2010/043532
申请日：2010-07-28
Applicant: HRD CORPORATION , HASSAN, Aziz , HASSAN, Abbas , ANTHONY, Rayford, G. , BORSINGER, Gregory
Inventor： HASSAN, Aziz , HASSAN, Abbas , ANTHONY, Rayford, G. , BORSINGER, Gregory
Abstract: Herein disclosed is a method of producing synthesis gas from carbonaceous material, the method comprising: (a) providing a mixture comprising carbonaceous material and a liquid medium; (b) subjecting the mixture to high shear under gasification conditions whereby a high shear-treated stream comprising synthesis gas is produced; and (c) separating a product comprising synthesis gas from the high shear-treated stream. Herein also disclosed is a method for producing a liquid product. The method comprises forming a dispersion comprising gas bubbles dispersed in a liquid phase in a high shear device, wherein the average gas bubble diameter is less than about 1.5 μm; contacting the dispersion with a multifunctional catalyst to form the liquid product; and recovering the liquid product. In an embodiment, the liquid product is selected from the group consisting of C2+ hydrocarbons, C2+ oxygenates, and combinations thereof.
