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    MAGNESIUM-TITANIUM-HAFNIUM FOR HIGH TEMPERATURE POLYMERIZATION
    3.
    发明申请
    MAGNESIUM-TITANIUM-HAFNIUM FOR HIGH TEMPERATURE POLYMERIZATION 审中-公开
    用于高温聚合的镁 - 钛 - 铪

    公开(公告)号：WO2009129598A1

    公开(公告)日：2009-10-29

    申请号：PCT/CA2009/000421

    申请日：2009-04-03

    Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A. ,  WANG, Qinyan ,  ZORICAK, Peter ,  RONNE NEWMAN, Joanna

    Inventor： WANG, Qinyan ,  ZORICAK, Peter ,  RONNE NEWMAN, Joanna

    IPC: C08F4/646 ,  C08F4/02 ,  C08F4/16 ,  C08F4/643

    CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F2410/03 ,  C08F4/6557 ,  C08F4/6545 ,  C08F210/14

    Abstract: A magnesium titanium olefin polymerization procatalyst is prepared by A) reacting a diorganomagnesium compound with a source of active chlorine, (with the proviso that the amount of chlorine is insufficient to completely convert the diorganomagnesium to magnesium dichloride); then B) removing unreacted diorganomagnesium from the reaction product; then C) adding a tetravalent hafnium species to the washed MgCl2 support; then D) depositing a tetravalent titanium species on the supported Hf. This procatalyst is highly active for the solution polymerization of olefins when combined with a cocatalyst.

    Abstract translation: 通过A）使二有机镁化合物与活性氯源反应（条件是氯的量不足以完全将二有机镁完全转化为二氯化镁）来制备镁钛烯烃聚合主催化剂; B）从反应产物中除去未反应的二有机镁; 然后C）向洗涤的MgCl 2载体中加入四价铪物质; 然后D）在负载的Hf上沉积四价钛物质。 当与助催化剂组合时，该前催化剂对烯烃的溶液聚合具有高度的活性。

    P-N-P LIGAND
    4.
    发明申请
    P-N-P LIGAND 审中-公开
    P-N-P配对

    公开(公告)号：WO2013110170A1

    公开(公告)日：2013-08-01

    申请号：PCT/CA2013/000038

    申请日：2013-01-17

    Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A. ,  GAO, Xiaoliang ,  ZORICAK, Peter

    Inventor： GAO, Xiaoliang ,  ZORICAK, Peter

    IPC: C07F9/50 ,  C07C2/36 ,  C08F4/69

    CPC classification number: C08F10/02 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/24 ,  C07C2531/34 ,  C07F9/4883 ,  C07F9/5325 ,  C08F4/69 ,  C08F210/16 ,  C08F210/14 ,  C07C11/02 ,  C07C11/107

    Abstract: A new P-N-P ligand is useful in ethylene oliogomenzation. The ligand is characterized by having at least one aromatic fiuorocarbyl alkoxide group bonded to a P atom, hi combination with 1) a source of chromium and 11) an activator such as methylalumoxane, the ligand of this invention may be used to prepare an oligomer product that contains a mixture of high purity alpha olefins, hi a preferred emobidment, the ligand of this invention enables a selective oligomerization in which the majority of the liquid product is a mixture of hexene and octene. The amount of byproduct polymer that is produced in preferred oligomerization reactions is advantegeously low.

    Abstract translation: 新的P-N-P配体可用于乙烯嗅觉。 该配体的特征在于具有至少一个与P原子键合的芳族氟代烷基烷氧基基团。与1）铬源和11）活化剂如甲基铝氧烷组合使用，本发明的配体可用于制备低聚物产物 其含有高纯度α-烯烃的混合物。在优选的方案中，本发明的配体能够进行选择性低聚，其中大部分液体产物是己烯和辛烯的混合物。 在优选的低聚反应中产生的副产物聚合物的量是非常低的。

    CATALYST FOR HIGH TEMPERATURE OLEFIN POLYMERIZATION
    5.
    发明申请
    CATALYST FOR HIGH TEMPERATURE OLEFIN POLYMERIZATION 审中-公开
    催化剂用于高温烯烃聚合

    公开(公告)号：WO2011116455A1

    公开(公告)日：2011-09-29

    申请号：PCT/CA2011/000248

    申请日：2011-03-08

    Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A. ,  WANG, Qinyan ,  ZORICAK, Peter

    Inventor： WANG, Qinyan ,  ZORICAK, Peter

    IPC: C08F4/646 ,  C08F10/02

    CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F2/06 ,  C08F210/14 ,  C08F2500/12 ,  C08F4/6555 ,  C08F4/6546

    Abstract: An olefin polymerization catalyst is prepared by (a) in a diluent, combining a diorganomagnesium compound with less than 2 molar equivalents of a first source of chloride to produce a "chloride deficient" magnesium chloride support; (b) without isolating any solids, adding a second source of chloride which reduces the amount of soluble un-reacted diorganomagnesium compound present; (c) without isolating any solids present, adding a tetravalent titanium species and; (d) adding an activator. The catalyst is active for solution polymerization of olefins.

    Abstract translation: 通过（a）在稀释剂中制备烯烃聚合催化剂，将二有机镁化合物与少于2摩尔当量的第一氯化物源组合以产生“氯化物缺乏”氯化镁载体; （b）不分离任何固体，加入第二氯化物源，减少可溶性未反应的二有机镁化合物的存在量; （c）不分离任何存在的固体，加入四价钛物质; （d）加入活化剂。 该催化剂对烯烃的溶液聚合是有活性的。

    CONTINUOUS ETHYLENE TETRAMERIZATION PROCESS
    6.
    发明申请
    CONTINUOUS ETHYLENE TETRAMERIZATION PROCESS 审中-公开
    连续乙烯四面体方法

    公开(公告)号：WO2014094114A1

    公开(公告)日：2014-06-26

    申请号：PCT/CA2013/001003

    申请日：2013-12-04

    Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A. ,  ZORICAK, Peter ,  BROWN, Stephen John ,  CHISHOLM, P., Scott

    Inventor： ZORICAK, Peter ,  BROWN, Stephen John ,  CHISHOLM, P., Scott

    IPC: C07C2/36

    CPC classification number: C07C2/34 ,  C07C2/36 ,  C07C2523/26 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24 ,  Y02P20/52 ,  C07C11/02

    Abstract: A continuous flow process for the oligomerization of ethylene using a chromium catalyst having a phosphorus - nitrogen - phosphorus ("P-N-P") ligand provides high selectivity to the desired tetramer (1-octene) with reduced production of coproduct C 10+ oligomers. Prior art processes that maximize catalyst activity have provided comparatively poor product selectivity. In particular, the production of larger amounts of C 10+ oligomers have been observed under conditions that maximize activity. The present process resolves this problem through the use of a combination of low catalyst concentration and by limiting the octene concentration in the reactor.

    Abstract translation: 使用具有磷 - 氮 - 磷（“P-N-P”）配体的铬催化剂使乙烯低聚的连续流动方法对所需的四聚体（1-辛烯）提供了高选择性，同时产生了副产物C10 +低聚物。 使催化剂活性最大化的现有技术方法提供了较差的产物选择性。 特别地，在活性最大化的条件下观察到产生更大量的C10 +低聚物。 本方法通过使用低催化剂浓度和限制反应器中辛烯浓度的组合来解决这个问题。

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