-
1.发明申请COMPOSITIONS BASED ON SEMI-CRYSTALLINE FLUORINATED POLYMER AND NUCLEATING AGENT USEFUL FOR PREPARING HIGH GLOSS COATINGS 审中-公开基于半晶体荧光聚合物的组合物和用于制备高胶层涂料的核化剂公开(公告)号：WO2017007645A1
公开(公告)日：2017-01-12
申请号：PCT/US2016/039928
申请日：2016-06-29
Applicant: ARKEMA INC.
Inventor： ZHENG, Min , WOOD, Kurt A. , YEN, Jeffrey H. , DURALI, Mehdi , GABOURY, Scott
IPC: C08L27/16 , C08L27/18 , C08L33/08 , C09D127/16 , C09D127/18
CPC classification number: C08L27/16 , C08J3/16 , C08K5/0083 , C08K2201/005 , C08L27/18 , C08L33/08 , C08L33/12 , C08L2205/02 , C08L2205/03 , C08L2205/24 , C09D5/033 , C09D127/16 , C09D133/12 , C08L33/06
Abstract: Fluoropolymer-based coatings with enhanced gloss are obtained by using a semi-crystalline fluorinated polymer having a very small particle size, in combination with a nucleating agent (such as PTFE) and, optionally, an acrylic polymer.
Abstract translation: 通过使用具有非常小粒径的半结晶氟化聚合物与成核剂（例如PTFE）和任选的丙烯酸聚合物组合，获得具有增强光泽度的含氟聚合物基涂层。
-
公开(公告)号：WO2013158360A1
公开(公告)日：2013-10-24
申请号：PCT/US2013/034885
申请日：2013-04-02
Applicant: ARKEMA INC.
Inventor： ZHENG, Min , WEN, Mei , GABOURY, Scott , WOOD, Kurt A. , PARTRIDGE, Ronald
IPC: C09D127/12
CPC classification number: C03C17/30 , C03C17/001 , C03C2217/29 , C03C2218/32 , C08G18/10 , C08G18/289 , C08G18/6279 , C08G18/73 , C08G18/758 , C08L2205/04 , C09D127/16 , C09D151/003 , C09D175/04 , Y10T428/3154 , C08K5/29 , C08K5/54 , C08L75/04
Abstract: The invention relates to an aqueous fluoropolymer coating composition for direct application to glass without the need for pre-treatment of the glass surface. The coating composition can also be used with other non-porous and porous substrates. The fluoropolymer coating contains a hydroxyl-functional fluoropolymer, and polyisocyanates. Preferably the coating composition also contains a water-dispersible hydroxyl functional polyurethane. The coating composition may exist as a 1-pack or a multi-pack coating system. The coating has excellent wet adhesion to glass, good weathering, chalking resistance, chemical resistance, and dirt pickup resistance.
Abstract translation: 本发明涉及直接应用于玻璃而不需要预处理玻璃表面的含氟聚合物水性涂料组合物。 涂料组合物也可以与其它无孔和多孔的基材一起使用。 含氟聚合物涂层含有羟基官能的含氟聚合物和多异氰酸酯。 优选地，涂料组合物还含有水分散性羟基官能聚氨酯。 涂料组合物可以以1包或多包装涂料体系的形式存在。 该涂层对玻璃具有优异的湿粘附性，良好的耐候性，抗粉化性，耐化学性和耐污垢性。
-
3.发明申请HIGH TOUGHNESS HOLLOW FIBER MEMBRANES BASED ON VINYLIDENE FLUORIDE POLYMERS 审中-公开基于乙烯基氟化物聚合物的高韧性中空纤维膜
公开(公告)号：WO2016014446A1
公开(公告)日：2016-01-28
申请号：PCT/US2015/041219
申请日：2015-07-21
Applicant: ARKEMA INC.
Inventor： KOSAR, Walter , REBER, III, Roderick , O'BRIEN, Gregory S. , GABOURY, Scott , WILLE, Roice A.
IPC: B01D71/34
CPC classification number: B01D71/38 , B01D69/02 , B01D69/08 , B01D71/32 , B01D71/34 , B01D71/36 , B01D71/76 , B01D2323/12 , B01D2323/18 , B01D2325/24 , B29C47/0004 , B29C47/0014 , B29C47/0026 , B29K2027/16 , B29L2023/00 , B29L2031/755 , D01D5/247 , D01F1/08 , D01F6/12
Abstract: Hollow fiber membranes having improved toughness and durability are prepared using a vinylidene fluoride polymer-containing component, such as Kynaro resins, having relatively low crystallinity. One aspect of the invention provides a membrane in the form of a fiber, wherein i) the fiber has a porous wall of a polymeric component enclosing a central hollow space extending the length of the fiber, ii) the polymeric component has a crystallinity as determined by wide angle x-ray diffraction of less than about 35%, iii) the polymeric component is comprised of at least one homopolymer or copolymer of vinylidene fluoride and iv) the membrane has an energy to break of at least about 0.5 J per square mm of membrane cross section.
Abstract translation: 具有改善的韧性和耐久性的中空纤维膜使用具有相对较低结晶度的含偏氟乙烯聚合物的组分如Kynaro树脂来制备。 本发明的一个方面提供一种纤维形式的膜，其中i）所述纤维具有包围延伸纤维长度的中心中空空间的聚合物组分的多孔壁，ii）聚合物组分具有如所确定的结晶度 通过广角X射线衍射小于约35％，iii）聚合物组分由至少一种偏二氟乙烯的均聚物或共聚物组成，以及iv）膜具有至少约0.5J /平方毫米的能量 的膜截面。
-
公开(公告)号：WO2006078425A2
公开(公告)日：2006-07-27
申请号：PCT/US2005/047118
申请日：2005-12-27
Applicant: ARKEMA INC. , ZHENG, Min , WOOD, Kurt, A. , GABOURY, Scott
Inventor： ZHENG, Min , WOOD, Kurt, A. , GABOURY, Scott
CPC classification number: C09D127/16 , C08K5/42 , C08L33/06 , C08L61/32 , C08L63/00 , Y10T428/12569 , Y10T428/1355 , Y10T428/1393 , Y10T428/31511 , Y10T428/31529 , Y10T428/3154 , Y10T428/31678 , Y10T428/31935 , C08L2666/02
Abstract: The invention relates to a one-step fluoropolymer, especially polyvinylidene fluoride (PVDF), coating for use on metals, especially use on metal fuel line and brake tubes, etc, to provide a protective barrier with superior chemical resistance, impact resistance and heat resistance as well as good flexibility. The coating composition contains, on a resin solids basis, 75-94 percent polyvinylidene fluoride resin, 5-20 percent acrylic resin, and 1-15 percent polyepoxide polyepoxide resin. The coating has excellent adhesion on metal substrates, particularly on non-pretreated galvanized steel, without the need for a primer coating.
Abstract translation: 本发明涉及一步氟聚合物，特别是聚偏二氟乙烯（PVDF），用于金属的涂料，尤其用于金属燃料管线和制动管等，以提供具有优异的耐化学性，耐冲击性和耐热性的保护屏障 以及良好的灵活性。 涂料组合物含有75-94％聚偏二氟乙烯树脂，5-20％丙烯酸树脂和1-15％聚环氧化物聚环氧树脂。 该涂层对金属基材，特别是未经预处理的镀锌钢板具有优异的粘附性，而不需要底漆涂层。
-
公开(公告)号：WO2015042555A1
公开(公告)日：2015-03-26
申请号：PCT/US2014/056897
申请日：2014-09-23
Applicant: ARKEMA INC.
Inventor： BERTELO, Christopher A. , GABOURY, Scott , PARTRIDGE, Ronald
IPC: C23C16/27
CPC classification number: H02S40/22 , B05D3/007 , C08K3/04 , C09D5/00 , C09D7/61 , C09D7/65 , C09D127/12 , H01L31/02168 , H01L31/0488 , H01L31/054 , H01L31/0543 , Y02E10/52
Abstract: A nanodiamond coating for use on a solar cell, the coating including a nanodiamond material suspended in a liquid, wherein the nanodiamond material has a size range from about 1 nm to about 10 nm. Methods for improving the efficiency of a solar cell are provided, including, mixing a nanodiamond material with a liquid polymer or non-polymer solvent to form a nanodiamond-polymer suspension, forming a coating of the suspension on a top surface of a solar cell, and drying the coating such that a dried nanodiamond-polymer layer remains bonded to the solar cell. Useful nanodiamond coating compositions may include a nanodiamond material, a fluoropolymer, a liquid solvent for the fluoropolymer and at least one additive selected from the group consisting of dispersing agents, adhesion promoters, and coupling agents. The fluoropolymer may also be used in the form of an aqueous dispersion.
Abstract translation: 一种用于太阳能电池的纳米金刚石涂层，所述涂层包括悬浮在液体中的纳米金刚石材料，其中所述纳米金刚石材料的尺寸范围为约1nm至约10nm。 提供了提高太阳能电池效率的方法，包括将纳米金刚石材料与液体聚合物或非聚合物溶剂混合以形成纳米金刚石 - 聚合物悬浮液，在太阳能电池的顶表面上形成悬浮液的涂层， 并干燥涂层，使得干燥的纳米金刚石 - 聚合物层保持结合到太阳能电池。 有用的纳米金刚石涂料组合物可以包括纳米金刚石材料，含氟聚合物，用于含氟聚合物的液体溶剂和至少一种选自分散剂，粘合促进剂和偶联剂的添加剂。 含氟聚合物也可以以水分散体的形式使用。
-
6.发明申请
公开(公告)号：WO2013158361A1
公开(公告)日：2013-10-24
申请号：PCT/US2013/034886
申请日：2013-04-02
Applicant: ARKEMA INC.
Inventor： ZHENG, Min , WEN, Mei , GABOURY, Scott , WOOD, Kurt A. , PARTRIDGE, Ronald
IPC: C09D127/12
CPC classification number: C03C17/3405 , B05D1/38 , B05D3/007 , B05D3/0254 , B05D3/0272 , C03C25/50 , C03C2217/78 , C08G18/10 , C08G18/2885 , C08G18/289 , C08G18/3206 , C08G18/48 , C08G18/6279 , C08G18/706 , C08G18/758 , C08G18/80 , C09D5/002 , C09D127/16 , C09D175/04 , Y10T428/3154 , C08L75/04
Abstract: The invention relates to an process for coating a glass substrate with an environmentally friendly aqueous, fluoropolymer coating composition. The process involves applying a polyurethane primer to the glass substrate, and partially, but not completely crosslinking this primer coating. An aqueous hydroxyl-functional fluoropolymer coating is then applied to the partially cross-linked primer coating, and the coating allowed to fully cure. The invention also relates to the intertwined multilayer primer/fluoropolymer coating on the glass substrate. The final coating has excellent wet adhesion to glass, good weathering, durability, chalking resistance, chemical resistance, and dirt pickup resistance.
Abstract translation: 本发明涉及用环保的含氟聚合物涂料组合物涂覆玻璃基材的方法。 该方法包括将聚氨酯底漆涂布在玻璃基材上，部分但不完全交联该底涂层。 然后将羟基官能的含氟聚合物水性涂层施加到部分交联的底漆涂层上，并使涂层完全固化。 本发明还涉及玻璃基板上相互缠绕的多层底漆/含氟聚合物涂层。 最终的涂层具有优异的与玻璃的湿粘合性，良好的耐候性，耐久性，抗粉化性，耐化学性和耐污垢性。
-
公开(公告)号：WO2008097684A1
公开(公告)日：2008-08-14
申请号：PCT/US2008/050731
申请日：2008-01-10
Applicant: ARKEMA INC. , ZHENG, Min , GABOURY, Scott , WOOD, Kurt A.
Inventor： ZHENG, Min , GABOURY, Scott , WOOD, Kurt A.
Abstract: The invention relates to a heat-stabilized fluoropolymer composition that resists discoloration, especially in extended heat applications. The composition includes at least one phosphoaryl compound having phosphorous in a P +3 or P +5 oxidation state. This additive reduces the yellowing effect that can occur during extended heat exposure, especially of polyvinylidene fluoride and polyvinyl fluoride polymers and copolymers.
Abstract translation: 本发明涉及耐热变色的热稳定的含氟聚合物组合物，特别是在延长的热应用中。 该组合物包含至少一种具有P + 3或P + 5 +氧化态的磷的磷酰芳基化合物。 该添加剂减少了在延长的热暴露期间可能发生的泛黄效应，特别是聚偏二氟乙烯和聚氟乙烯聚合物和共聚物。
-
公开(公告)号：WO2013126490A1
公开(公告)日：2013-08-29
申请号：PCT/US2013/026996
申请日：2013-02-21
Applicant: ARKEMA INC.
Inventor： AMIN-SANAYEI, Ramin , GABOURY, Scott
IPC: H01M2/14
CPC classification number: H01M2/1686 , H01G9/02 , H01G11/52 , H01M2/145 , H01M2/162 , H01M2/166 , H01M2/1666 , H01M10/052 , Y02E60/13
Abstract: The invention relates to a separator for non-aqueous-type electrochemical device that has been coated with an aqueous fluoropolymer coating. The fluoropolymer is preferably polyvinylidene fluoride (PVDF), and more preferably a copolymer of polyvinylidene fluoride. The fluoropolymer coating provides a porous coating on porous substrate separator used in non-aqueous-type electrochemical devices, such as batteries and electric double layer capacitors. The fluoropolymer coating improves the thermal resistance and mechanical integrity, and lowers the interfacial electrical impedance of the porous separator. The fluoropolymer composition optionally contains powdery particles that are held together on the separator by the fluoropolymer binder. In one embodiment, the starting fluoropolymer dispersion is free of fluorinated surfactant. In another embodiment, one or more fugitive adhesion promoters are added.
Abstract translation: 本发明涉及一种已经涂覆含氟聚合物水性涂料的非水型电化学装置用隔膜。 氟聚合物优选为聚偏氟乙烯（PVDF），更优选为聚偏二氟乙烯的共聚物。 氟聚合物涂层在用于非水型电化学装置（例如电池和双电层电容器）中的多孔基材分离器上提供多孔涂层。 含氟聚合物涂层改善了耐热性和机械完整性，并降低了多孔分离器的界面电阻抗。 含氟聚合物组合物任选地含有通过氟聚合物粘合剂在隔膜上保持在一起的粉末状颗粒。 在一个实施方案中，起始含氟聚合物分散体不含氟化表面活性剂。 在另一个实施方案中，加入一种或多种短效粘合促进剂。
-
公开(公告)号：WO2013016110A1
公开(公告)日：2013-01-31
申请号：PCT/US2012/047298
申请日：2012-07-19
Applicant: ARKEMA INC. , AMIN-SANAYEI, Ramin , GABOURY, Scott
Inventor： AMIN-SANAYEI, Ramin , GABOURY, Scott
IPC: H01M4/96
CPC classification number: H01M10/0525 , C08K5/1565 , C09D127/16 , F04C15/0096 , H01G11/26 , H01G11/30 , H01G11/38 , H01G11/48 , H01G11/52 , H01M2/1686 , H01M4/0404 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/62 , H01M4/623 , Y02E60/13 , Y10T428/3154
Abstract: This invention relates to a waterborne fluoropolymer composition useful for the fabrication of Li-Ion-Battery (LIB) electrodes. The fluoropolymer composition contains an organic carbonate compound, which is more environmentally friendly than other fugitive adhesion promoters currently used in waterborne fluoropolymer binders. An especially useful organic carbonate compound is ethylene carbonate (EC) and vinylene carbonate (VC), which are solids at room temperature, and other carbonates which are liquid at room temperature such as propylene carbonate, methyl carbonate and ethyl carbonate. The composition of the invention is low cost, environmentally friendly, safer, and has enhanced performance compared to current compositions.
Abstract translation: 本发明涉及可用于制造锂离子电池（LIB）电极的水性氟聚合物组合物。 氟聚合物组合物含有有机碳酸酯化合物，其比目前在水性氟聚合物粘合剂中使用的其它短效粘合促进剂更环保。 特别有用的有机碳酸酯化合物是在室温下为固体的碳酸亚乙酯（EC）和碳酸亚乙烯酯（VC），以及其它在室温下为液体的碳酸酯，例如碳酸亚丙酯，碳酸甲酯和碳酸乙酯。 本发明的组合物低成本，环保，更安全，并且与现有组合物相比具有增强的性能。
-
公开(公告)号：WO2012112840A1
公开(公告)日：2012-08-23
申请号：PCT/US2012/025567
申请日：2012-02-17
Applicant: ARKEMA INC. , AMIN-SANAYEI, Ramin , LIN, Caiping , AIRAUD, Cedric , SCHMIDHAUSER, John , GABOURY, Scott
Inventor： AMIN-SANAYEI, Ramin , LIN, Caiping , AIRAUD, Cedric , SCHMIDHAUSER, John , GABOURY, Scott
IPC: B01D53/22
CPC classification number: B01D53/228 , B01D39/04 , B01D39/1692 , B01D53/22 , B01D69/02 , B01D71/32 , B01D71/34 , B01D71/36 , B01D2257/504 , B01D2258/0283 , B01D2325/20 , Y02C10/10
Abstract: The invention relates to a novel film, membrane or powder media made from fluoropolymers, especially PVDF-based and ETFE-based polymers, which are suitable for separating gases, especially carbon dioxide, from a gas mixture. The novel film has good selectivity, high permeance, good mechanical properties, and exhibits a high resistance to oxidant and acid attack. The separation film is especially useful in harsh and corrosive environments.
Abstract translation: 本发明涉及由氟聚合物，特别是PVDF基和基于ETFE的聚合物制成的新型膜，膜或粉末介质，其适用于从气体混合物中分离气体，特别是二氧化碳。 该新型薄膜具有选择性好，渗透性好，机械性能好，耐氧化和耐酸性高的优点。 分离膜在恶劣和腐蚀性环境中特别有用。
