Abstract:
This disclosure is directed to uses for a new crystalline molecular sieve designated SSZ-99. SSZ-99 is synthesized using a methylethyldiisopropylammonium cation as a structure directing agent.
Abstract:
A process for isomerizing light paraffins using a catalyst comprising an *SFV-type zeolite and at least one Group VIII metal. It has been found that the catalyst can selectively convert C 6 paraffins into the more favorable higher octane C 6 isomer, namely 2,3-dimethylbutane (RON = 105), over the less favorable C 6 isomer, namely octane 2,2-dimethylbutane (RON = 94).
Abstract:
A process of upgrading a heavy hydrocarbon feedstock comprising contacting a heavy hydrocarbon feedstock with a catalyst in the presence of hydrogen in a reactor system, containing the catalyst as the only catalyst, wherein the catalyst, is prepared by sulfiding a catalyst precursor obtained by mixing at reaction conditions, to form a precipitate or cogel, at least a Group VIII metal compound in solution; at least a Group VIB metal compound in solution; and, at least an organic oxygen containing ligand in solution, and thereby producing a fuel product.
Abstract:
A Fischer-Tropsch C 3 -C 4 olefin stream is simultaneously dehydrated and isomerized in a reactor (40) to convert alcohols to olefins and 1-butenes to 2-butenes and thereby lower the oxygenate content. Another Fischer-Tropsch fraction is hydrotreated and hydrocraked in a reactor (70) to provide an isobutane stream. The treated C 3 - C 4 olefin stream having an oxygenate content less than 4000 ppm is reacted with the isobutane stream to provide a highly branched, high octane isoparaffinic alkylate. The alkylate is useful as a blending component in motor gasoline.
Abstract:
Provided is a process for hydrocracking normal paraffins into lighter normal paraffins with minimal formation of iso-paraffins. The process comprises hydrocracking a hydrocarbon feedstock comprising normal paraffins under hydrocracking conditions. The reaction is run in the presence of a specific type of zeolite based catalyst which has been found to provide high conversion with minimal iso-paraffin products. In one embodiment, the zeolite is of the framework PWO. The reaction conducted in the presence of the zeolite based catalyst produces an n-paraffin rich product that needs no separation step before being fed to a steam cracker to produce lower olefins.
Abstract:
A method is provided for synthesizing molecular sieves of SZR framework type using 1,2,3-trimethylimidazolium cations as a structure directing agent and alumina-coated silica as a combined source of silicon and aluminum.
Abstract:
A small crystal size, high surface area aluminogermanosilicate molecular sieve material, designated SSZ-120, is provided. SSZ-120 can be synthesized using 3,3'-[2,6-naphthalenebis(methylene)]bis[1,2-dimethyl-1H-imidazolium] dications as a structure directing agent. SSZ-120 may be used in organic compound conversion reactions and/or sorptive processes.
Abstract:
A novel synthetic crystalline aluminogermanosilicate molecular sieve material, designated SSZ-117, is provided. SSZ-117 can be synthesized using N,N,N,3,5-pentamethyladamantan-1-ammonium cations as a structure directing agent. SSZ-117 may be used in organic compound conversion reactions and/or sorptive processes.
Abstract:
This disclosure is directed to a novel crystalline molecular sieve designated as SSZ-107, its synthesis using 1,1-diethylpyrrolidinium cations as a structure directing agent, and its use as an adsorbent and/or a catalyst.
Abstract:
A new crystalline molecular sieve designated SSZ-100 is disclosed. SSZ-100 is synthesized using a cationic nitrogen-containing organic compound having the following structure (I).