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1.发明申请BIS-BIPHENYLPHENOXY CATALYSTS FOR POLYMERIZATION OF LOW MOLECULAR WEIGHT ETHYLENE-BASED POLYMERS 审中-公开用于低分子量乙烯基聚合物聚合的双 - 二苯基氧化催化剂公开(公告)号：WO2016014749A1
公开(公告)日：2016-01-28
申请号：PCT/US2015/041664
申请日：2015-07-23
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： EWART, Sean W. , KEATON, Richard J. , KLOSIN, Jerzy , FIGUEROA, Ruth
IPC: C08F210/16 , C08F4/64
CPC classification number: C08F210/16 , B01J31/2226 , C07F7/00 , C07F7/006 , C08F4/65904 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F4/64193 , C08F2500/02 , C08F2500/08 , C08F2500/17
Abstract: The invention provides a process, and transition metal complex, to form an ethylene-based polymer, said process comprising polymerizing ethylene, and optionally at least one comonomer, in the presence of at least one molecular transition metal complex selected from Formula 1, as described herein.
Abstract translation: 本发明提供一种方法和过渡金属络合物，以形成基于乙烯的聚合物，所述方法包括在所述的至少一种选自式1的分子过渡金属络合物的存在下聚合乙烯和任选的至少一种共聚单体，如所述 于此。
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公开(公告)号：WO2019191068A1
公开(公告)日：2019-10-03
申请号：PCT/US2019/024034
申请日：2019-03-26
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： KEATON, Richard J. , HUACUJA, Rafael , WILSON, David R. , KLOSIN, Jerzy , PEARSON, David M. , SENECAL, Todd D. , MUKHOPADHYAY, Sukrit , WOODWARD, William H. H.
IPC: B01J31/02 , C08F110/14 , C08F210/16 , C08F4/659
Abstract: Embodiments of this disclosure include processes of polymerizing olefins, the process comprising contacting ethylene and a (C 3 -C 40 )alpha-olefin comonomer in the presence of a catalyst system, the catalyst system comprising a Group IV metal-ligand complex and an ionic metallic activator complex, the ionic metallic activator complex comprising an anion and a countercation, the anion having a structure according to formula (I):formula (I)
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公开(公告)号：WO2022015638A1
公开(公告)日：2022-01-20
申请号：PCT/US2021/041254
申请日：2021-07-12
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： GRZESIAK, Adam L. , STROTHER, Jacob W. , MCDOUGAL, Nolan T. , KEATON, Richard J. , LAITAR, David S. , ROSEN, Mari S. , AOU, Kaoru , WILLUMSTAD, Thomas P.
IPC: C08G18/16 , C08G18/18 , C08G18/24 , C08G18/30 , C08G18/48 , C08G18/76 , C08K5/098 , C08K5/17 , C08K5/54 , C08L75/08 , B01J27/26 , B01J31/06 , C08G65/26
Abstract: Polyurethanes are made by curing a reaction mixture containing a polyether polyol that contains residues of a zinc hexacyanocobaltate catalyst complex. The reaction mixture contains certain chelating agents in small quantities. The amount of cobalt that is extractable from the polyurethane is reduced.
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4.发明申请
公开(公告)号：WO2020198196A1
公开(公告)日：2020-10-01
申请号：PCT/US2020/024397
申请日：2020-03-24
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： SENECAL, Todd D. , MUKHOPADHYAY, Sukrit , KEATON, Richard J. , KLOSIN, Jerzy , HUACUJA, Rafael , PEARSON, David M. , WOODWARD, William H. H.
IPC: C08F4/659 , C08F210/16 , C08F4/64 , C08F4/6592
Abstract: Embodiments include activators having a structure according to formula (I).
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公开(公告)号：WO2021226423A1
公开(公告)日：2021-11-11
申请号：PCT/US2021/031233
申请日：2021-05-07
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： HUACUJA, Rafael , KEATON, Richard J. , KLOSIN, Jerzy , MUKHOPADHYAY, Sukrit , PEARSON, David M. , SENECAL, Todd D. , WOODWARD, William H.H.
IPC: C08F210/16 , C07F5/02 , C08F4/64 , C08F2/06
Abstract: Processes of polymerizing olefins. The process includes polymerizing contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presence of a catalyst system comprising a procatalyst and a bimetallic activator complex. The bimetallic activator complex includes an anion and a countercation. The anion having a structure according to formula (I).
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公开(公告)号：WO2019190925A1
公开(公告)日：2019-10-03
申请号：PCT/US2019/023643
申请日：2019-03-22
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： KEATON, Richard J. , HUACUJA, Rafel , WILSON, David R. , KLOSIN, Jerzy , PEARSON, David M. , SENECAL, Todd D. , MUKHOPADHYAY, Sukrit , WOODWARD, William H.H.
IPC: C08F210/16 , C08F4/642
Abstract: Embodiments of the disclosure include processes of polymerizing olefins. The process includes contacting ethylene and a (C 3 −C 40 )alpha-olefin comonomer in the presences of a catalyst system. The catalyst system comprises a procatalyst and a bimetallic activator complex. The bimetallic activator complex comprises an anion and a countercation, and the anion has a structure according to formula (I).
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公开(公告)号：WO2017062252A1
公开(公告)日：2017-04-13
申请号：PCT/US2016/054300
申请日：2016-09-29
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： DE VRIES, Timothy S. , JIALANELLA, Gary L. , KRISHNAN, Bindu , KEATON, Richard J.
CPC classification number: C08G18/4841 , C08G18/10 , C08G18/1816 , C08G18/246 , C08G18/3206 , C08G18/4816 , C08G18/4833 , C08G18/6674 , C08G18/7664 , C09J175/08 , C08G18/48
Abstract: An adhesive formulation including: (a) at least one polyol having an average functionality number of greater than 3 and a hydroxyl equivalent weight of from about 300 g/mol OH to about 3,000 g/mol OH; and (b) at least one tin catalyst compound; wherein the adhesive formulation exhibits a latency of greater than 10 minutes open time; and a process for preparing the adhesive formulation.
Abstract translation: 一种粘合剂制剂，其包含：（a）至少一种平均官能度大于3且羟基当量为约300g / mol OH至约3,000g / mol OH的多元醇; 和（b）至少一种锡催化剂化合物; 其中所述粘合剂制剂表现出大于10分钟开放时间的潜伏期; 以及制备粘合剂制剂的方法。
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公开(公告)号：WO2022086946A1
公开(公告)日：2022-04-28
申请号：PCT/US2021/055589
申请日：2021-10-19
Applicant: DOW GLOBAL TECHNOLOGIES LLC , DOW SILICONES CORPORATION
Inventor： SUZUKI, Masayuki , RAGHURAMAN, Arjun , WESTON, John W. , KAGA, An , KEATON, Richard J. , BIRCH, Adrian J. , COTANDA, Maria-Jose
IPC: C08G18/08 , C08G18/10 , C08G18/48 , C09D175/08
Abstract: Embodiments relate to a coating, adhesive, sealant, elastomer, or reaction injection molded material forming polyurethane composition that comprises an isocyanate component that includes at least one isocyanate-terminated prepolymer, and an isocyanate reactive component that includes at least one Lewis acid catalyst polymerized polyether polyol having a weight average molecular weight from 200 g/mol to 1,000 g/mol, an average primary hydroxyl group content of at least 30 %, and an average acetal content of at least 0.05 wt%.
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公开(公告)号：WO2021154783A1
公开(公告)日：2021-08-05
申请号：PCT/US2021/015182
申请日：2021-01-27
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： BÉDARD, Anne-Catherine , BELOWICH, Matthew E. , ROSEN, Mari S. , CANDIA, Sandra Varinia Bernales , BABB, David A. , CUMMINS, Clark H. , KEATON, Richard J. , YONKEY, Matthew M. , WALLER, Peter J.
IPC: C08G65/26
Abstract: Polyethers are prepared by polymerizing an alkylene oxide in the presence of a starter, an aluminum compound that has at least one hydrocarbyl substituent, and a phosphorus-nitrogen base. The phosphorus-nitrogen base is present in only a small molar ratio relative to the amount of starter. The presence of such small amounts of phosphorus-nitrogen base greatly increases the catalytic activity of the system, compared to the case in which the aluminum compound is used by itself. The product polyethers have low amounts of unsaturated polyether impurities and little or no unwanted high molecular weight fraction. Polymers of propylene oxide have very low proportions of primary hydroxyl groups.
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公开(公告)号：WO2021154780A1
公开(公告)日：2021-08-05
申请号：PCT/US2021/015179
申请日：2021-01-27
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： BÉDARD, Anne-Catherine , BELOWICH, Matthew E. , ROSEN, Mari S. , CANDIA, Sandra Varinia Bernales , BABB, David A. , CUMMINS, Clark H. , KEATON, Richard J. , YONKEY, Matthew M.
IPC: C08G65/26
Abstract: Polyethers are prepared by polymerizing an alkylene oxide in the presence of a starter, an aluminum compound that has at least one hydrocarbyl substituent, and a cyclic amidine. The phosphorus-nitrogen base is present in only a small molar ratio relative to the amount of starter. The presence of such small amounts of cyclic amidine greatly increases the catalytic activity of the system, compared to the case in which the aluminum compound is used by itself. The product polyethers have low amounts of unsaturated polyether impurities and little or no unwanted high molecular weight fraction. Polymers of propylene oxide have very low proportions of primary hydroxyl groups.
