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    OLEFIN TRIBLOCK POLYMERS VIA RING-OPENING METATHESIS POLYMERIZATION
    2.
    发明申请
    OLEFIN TRIBLOCK POLYMERS VIA RING-OPENING METATHESIS POLYMERIZATION 审中-公开
    OLEFIN TRIBLOCK聚合物通过开环METATHESIS聚合

    公开(公告)号：WO2012134713A2

    公开(公告)日：2012-10-04

    申请号：PCT/US2012/027670

    申请日：2012-03-05

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC. ,  STEWART, Ian, C.

    Inventor： STEWART, Ian, C.

    IPC: C08L45/00 ,  C08L53/00 ,  C08F32/00 ,  C08F297/08

    CPC classification number: C08F32/00 ,  C08F297/08 ,  C08G61/04 ,  C08G61/08 ,  C08G2261/126 ,  C08G2261/3323 ,  C08G2261/418 ,  C08L53/00 ,  C08L65/00

    Abstract: This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-(-C=C-Z-)n-C=C-PO* (I) or PO-(-C-C-Z-)n-C-C-PO* (la) wherein Z is the portion of a cyclic monomer having at least one internal double bond that remains after a ring-opening metathesis reaction; PO and PO* are each independently polyolefins; and n is 1 to 10,000; and a process to produce such comprising contacting an alkene metathesis catalyst with a dimer of vinyl terminated polyolefins, and a cyclic hydrocarbyl monomer comprising at least one internal double bond.

    Abstract translation: 本发明涉及一种组合物，其包含由下式表示的多嵌段聚烯烃：PO - （ - C = CZ-）nC = C-PO *（I）或PO - （ - CCZ-）nCC-PO *（Ia） 是具有在开环复分解反应后保留的至少一个内部双键的环状单体的部分; PO和PO *各自独立地为聚烯烃; n为1〜10,000; 以及生产这种方法的方法包括使烯烃易位催化剂与乙烯基封端的聚烯烃的二聚体和包含至少一个内部双键的环状烃基单体接触。

    SILICA TREATING OF FUNCTIONALIZED RESINS IN TIRES
    4.
    发明申请
    SILICA TREATING OF FUNCTIONALIZED RESINS IN TIRES 审中-公开
    功能性树脂在轮胎中的二氧化硅处理

    公开(公告)号：WO2015153057A2

    公开(公告)日：2015-10-08

    申请号：PCT/US2015/019190

    申请日：2015-03-06

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： HARRIS, David, T. ,  STEWART, Ian, C. ,  GEORJON, Olivier, J.F. ,  BLOK, Edward, J.

    IPC: C09C1/30

    CPC classification number: C08K3/36 ,  B60C1/0016 ,  C08F8/42 ,  C08F2810/40 ,  C08G61/02 ,  C08G83/001 ,  C08G2261/3325 ,  C08G2261/726 ,  C08K3/06 ,  C08K3/22 ,  C08K5/09 ,  C08K5/18 ,  C08K5/31 ,  C08K5/47 ,  C08K9/06 ,  C08K9/08 ,  C08K9/10 ,  C08K2003/2296 ,  C08L9/00 ,  C08L9/06 ,  C08L45/00 ,  C08L91/00 ,  C09C1/3072 ,  C09C1/3081 ,  C09C1/309 ,  Y02T10/862 ,  C08F132/08

    Abstract: This invention relates to a process for the preparation of a silica-treated functionalized resin composition comprising the steps of reacting a polymer backbone with a hydros ilylation agent to produce a silane-functionalized resin composition, wherein the polymer backbone is selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C 5 homopolymers and copolymer resins, C 5 -styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C 9 homopolymers and copolymer resins, C 5 /C 9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof; and mixing the silane-functionalized resin composition with a silica to produce a silica-treated functionalized resin composition.

    Abstract translation: 本发明涉及一种制备二氧化硅处理的官能化树脂组合物的方法，包括以下步骤：使聚合物主链与氢化硅烷化反应产生硅烷官能化的树脂组合物，其中聚合物骨架选自以下的至少一种： 基于二环戊二烯（DCPD）的聚合物，环戊二烯（CPD）的聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯均聚物或共聚物树脂，C9均聚物和共聚物树脂 ，C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂，及其组合; 并将硅烷官能化的树脂组合物与二氧化硅混合以制备二氧化硅处理的官能化树脂组合物。

    PROCESS OF PRODUCING POLYOLEFINS USING METALLOCENE POLYMERIZATION CATALYSTS AND COPOLYMERS THEREFROM
    5.
    发明申请
    PROCESS OF PRODUCING POLYOLEFINS USING METALLOCENE POLYMERIZATION CATALYSTS AND COPOLYMERS THEREFROM 审中-公开
    使用金属聚合催化剂和其共聚物生产聚烯烃的方法

    公开(公告)号：WO2014169017A1

    公开(公告)日：2014-10-16

    申请号：PCT/US2014/033457

    申请日：2014-04-09

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： STEWART, Ian, C. ,  BROWN, Steven, D. ,  ATIENZA, Crisita, Carmen, H. ,  HARRIS, David, T. ,  HOLLAS, Aaron, M.

    IPC: C08F4/6592 ,  C08F10/00

    CPC classification number: C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65927 ,  C08F2420/02 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/20 ,  C08F10/00

    Abstract: An ethylene copolymer, a Group 4 transition metal catalyst compound, and methods for polymerization using such a compound, said compound represented by the formula: (L) p (R') z T(Cp)(A)MX 2 , where M is a Group 4 metal; z is 0 to 8; p is 1 to 3; X is an anionic leaving group; T is a bridging group; R. 1 to R 4 are hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, aryl group, substituted aryl group, or a heteroatom-containing group (where adjacent R groups can form rings); R' is hydrogen, a C 1 to C 10 alkyl group, a C 6 to C 24 aryl group, or a C 7 to C 40 alkylaryl group; and L is a heteroatom or heteroatom-containing group bound to T, Cp is a cyclopentadienyl ring substituted with 0 to 4 substituent groups (where adjacent groups can form C 4 to C 20 rings); A is Cp or (JS' z*-1-y ), where J is a Group 15 or 16 element; S' is a hydrocarbyl, substituted hydrocarbyl, or heteroatom; z* is 2 or 3, and y is 0 or 1, is provided.

    Abstract translation: 乙烯共聚物，第4族过渡金属催化剂化合物和使用这种化合物的聚合方法，由式（L）p（R'）zT（Cp）（A）MX2表示的所述化合物，其中M为 4金属; z为0〜8; p为1〜3; X是阴离子离去基团; T是一个桥接组; R 1至R 4是氢，烃基，取代的烃基，芳基，取代的芳基或含杂原子的基团（其中相邻的R基团可以形成环）; R'是氢，C 1至C 10烷基，C 6至C 24芳基或C 7至C 40烷基芳基; 并且L是与T结合的杂原子或含杂原子的基团，Cp是被0至4个取代基取代的环戊二烯基环（其中相邻基团可以形成C 4至C 20环）; A是Cp或（JS'z * -1-y），其中J是第15或16族; S'是烃基，取代的烃基或杂原子; z *为2或3，y为0或1。

    DUAL REACTIVE FUNCTIONAL GROUPS FOR RESINS IN TIRES
    7.
    发明申请
    DUAL REACTIVE FUNCTIONAL GROUPS FOR RESINS IN TIRES 审中-公开
    轮胎树脂的双重反应功能组合

    公开(公告)号：WO2015153059A2

    公开(公告)日：2015-10-08

    申请号：PCT/US2015/019214

    申请日：2015-03-06

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC. ,  BLOK, Edward, J. ,  STEWART, Ian, C. ,  DIAS, Anthony, J. ,  YANG, Yong ,  ZHANG, Jingwen

    Inventor： BLOK, Edward, J. ,  STEWART, Ian, C. ,  DIAS, Anthony, J. ,  YANG, Yong ,  ZHANG, Jingwen

    IPC: C08F8/42

    CPC classification number: C08F8/42 ,  B60C1/0016 ,  C08C19/25 ,  C08F8/00 ,  C08K3/00 ,  C08L9/00 ,  C08L21/00 ,  C08L57/06 ,  C08L101/02

    Abstract: This invention relates to a functionalized resin composition having the formula P-X- S-W where S is a spacer selected from at least one of C 2 -C 40 straight chain and branched alkyl, C 6 -C 40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C 5 homopolymers and copolymer resins, C 5 -styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C 9 homopolymers and copolymer resins, C 5 /C 9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, X is one or more reactive groups, and W is a silane.

    Abstract translation: 本发明涉及具有式PX-SW的官能化树脂组合物，其中S是选自C 2 -C 40直链和支链烷基，C 6 -C 40芳烃，丁二烯，异戊二烯及其组合中的至少一种的间隔基，P是 选自二环戊二烯（DCPD）基聚合物，环戊二烯（CPD）基聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂中的至少一种的聚合物主链，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯均聚物或 共聚物树脂，C9均聚物和共聚物树脂，C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂及其组合，X是一个或多个反应性基团，W是硅烷。

    FREE RADICAL GRAFTING OF FUNCTIONALIZED RESINS FOR TIRES
    8.
    发明申请
    FREE RADICAL GRAFTING OF FUNCTIONALIZED RESINS FOR TIRES 审中-公开
    轮胎功能性树脂的自由射击

    公开(公告)号：WO2015153058A1

    公开(公告)日：2015-10-08

    申请号：PCT/US2015/019200

    申请日：2015-03-06

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： BLOK, Edward, J. ,  HARRIS, David, T. ,  STEWART, Ian, C.

    IPC: C08F279/00 ,  C08F291/02 ,  C08L9/00 ,  C08L51/04 ,  B60C1/00 ,  C08K5/00 ,  C08L21/00

    CPC classification number: C08F8/42 ,  B60C1/0016 ,  C08F279/00 ,  C08F291/02 ,  C08K3/00 ,  C08K5/0025 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L51/04 ,  C08F230/08

    Abstract: This invention relates to a process for the preparation of a silane-functionalized resin composition comprising the steps of mixing a polymer backbone, a silane, and a free radical initiator; and producing a silane-functionalized resin composition. The polymer backbone is selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C 5 homopolymers and copolymer resins, C 5 -styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C 9 homopolymers and copolymer resins, C 5 /C 9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof.

    Abstract translation: 本发明涉及一种制备硅烷官能化树脂组合物的方法，包括以下步骤：混合聚合物骨架，硅烷和自由基引发剂; 并制备硅烷官能化树脂组合物。 聚合物主链选自二环戊二烯（DCPD）基聚合物，环戊二烯（CPD）基聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂中的至少一种，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯 均聚物或共聚物树脂，C 9均聚物和共聚物树脂，C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂，及其组合。

    SPACER GROUPS FOR FUNCTIONALIZED RESINS IN TIRES
    9.
    发明申请
    SPACER GROUPS FOR FUNCTIONALIZED RESINS IN TIRES 审中-公开
    轮胎中功能化树脂的间隔组

    公开(公告)号：WO2015153055A2

    公开(公告)日：2015-10-08

    申请号：PCT/US2015/019170

    申请日：2015-03-06

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： BLOK, Edward, J. ,  HARRIS, David, T. ,  STEWART, Ian, C.

    IPC: C08F8/42

    CPC classification number: C08F8/42 ,  B60C1/0016 ,  C08F2810/30 ,  C08F2810/40 ,  C08K3/36 ,  C08K5/548 ,  C08L9/00 ,  C08L9/06 ,  C08L45/00 ,  C08L2205/025 ,  C08F132/08

    Abstract: This invention relates to a functionalized resin composition having the formula P-S-X where S is a spacer selected from at least one of C 2 -C 40 straight chain and branched alkyl, C 6 - C 40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C 5 homopolymers and copolymer resins, C 5 -styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C 9 homopolymers and copolymer resins, C 5 /C 9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, and X is a silane.

    Abstract translation: 本发明涉及具有式PSX的官能化树脂组合物，其中S是选自C 2 -C 40直链和支链烷基，C 6 -C 40芳烃，丁二烯，异戊二烯及其组合中的至少一种的间隔基，P是聚合物主链 选自二环戊二烯（DCPD）基聚合物，环戊二烯（CPD）基聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂中的至少一种，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯均聚物或共聚物树脂 C9均聚物和共聚物树脂，C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂及其组合，X是硅烷。

    CHAIN END FUNCTIONALIZED POLYOLEFINS FOR IMPROVING WET TRACTION AND ROLLING RESISTANCE OF TIRE TREADS
    10.
    发明申请
    CHAIN END FUNCTIONALIZED POLYOLEFINS FOR IMPROVING WET TRACTION AND ROLLING RESISTANCE OF TIRE TREADS 审中-公开
    链端功能化聚烯烃，用于改善轮胎胎纹的湿牵引和抗滚动性

    公开(公告)号：WO2016093934A2

    公开(公告)日：2016-06-16

    申请号：PCT/US2015/054425

    申请日：2015-10-07

    Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

    Inventor： BLOK, Edward, J. ,  YANG, Yong ,  ZHANG, Jingwen ,  STEWART, Ian, C. ,  LUO, Shuji ,  TSOU, Andy, H.

    CPC classification number: C08L9/00 ,  B60C1/0016 ,  C08F8/42 ,  C08K3/36 ,  C08L15/00 ,  Y02T10/862 ,  C08F10/02 ,  C08F10/04

    Abstract: A functionalized polyolefin and a tire tread composition comprising the functionalized polyolefin is described. The functionalized polyolefin comprises a vinyl/vinylidene-terminated polyolefin in which the vinyl/vinylidene terminus is functionalized with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality. The invention is also directed to the synthesis of vinyl/vinylidene-terminated polyolefins, functionalization at the vinyl/vinylidene terminus with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality.

    Abstract translation: 描述了包含官能化聚烯烃的官能化聚烯烃和轮胎胎面组合物。 官能化聚烯烃包含乙烯基/亚乙烯基封端的聚烯烃，其中乙烯基/亚乙烯基末端用烷氧基硅烷或烷基硅烷官能化并任选具有醚，羟基和/或胺官能团。 本发明还涉及乙烯基/亚乙烯基封端的聚烯烃的合成，在乙烯基/亚乙烯基末端用烷氧基硅烷或烷基硅烷进行官能化并任选具有醚，羟基和/或胺官能团。

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