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公开(公告)号：WO2018138705A1
公开(公告)日：2018-08-02
申请号：PCT/IB2018/050565
申请日：2018-01-30
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： AL-JABER, Ahmad , BABKOOR, Mohammed , KOROBKOV, Ilia , AL-BAHILY, Khalid , AL-AHAMADI, Khalid , VIDJAYACOUMAR, Balamurugan
Abstract: Processes for producing cesium oxalate are disclosed. The process includes contacting cesium carbonate, cesium hydrogenbicarbonate or a mixture thereof with carbon dioxide and carbon monoxide, carbon dioxide and hydrogen or carbon monoxide and oxygen at elevenated temperatures and pressures.
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2.发明申请NITROGEN RICH CARBON NITRIDE MATERIALS WITH A THREE DIMENSIONAL CUBIC MESOPOROSITY FROM DIAMINOTETRAZINE 审中-公开富含氮的富氮碳氮化物材料与二氨基四氮唑三维多孔介质
公开(公告)号：WO2018020356A1
公开(公告)日：2018-02-01
申请号：PCT/IB2017/054290
申请日：2017-07-14
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： TALAPANENI, Siddulu Naidu , VINU, Ajayan , RAVON, Ugo , AL-BAHILY, Khalid
IPC: B01J35/00 , C01B21/06 , B01J27/24 , C01B3/04 , C25B1/00 , B01J35/04 , B01J37/06 , B01J35/10 , B01J37/00
CPC classification number: C01B21/0605 , B01J21/185 , B01J23/42 , B01J27/24 , B01J35/004 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0018 , B01J37/06 , C01B3/042 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2006/12 , C01P2006/14
Abstract: Embodiments are directed to carbon nitride materials that provide appropriate characteristics for photocatalytic water splitting. The carbon nitride materials have a three dimensional CN material with a high nitrogen content that is stable under photocatalytic conditions. A method of producing a photocatalytic CN material comprises (a) contacting a mesoporous template having a selected porosity with an aminoguanidine hydrochloride solution, forming a template reactant mixture; and (b) heating the template reactant mixture, forming a carbon nitride material/template composite; (c) heating the CN/template composite in an inert gas atmosphere to about 350 °C to 450 °C, forming a cubic mesoporous carbon nitride material/template complex; and (d) removing the template from the mesoporous carbon nitride material/ template complex. The carbon nitrogen matrix is a based on C3N6diamino-s-tetrazine.
Abstract translation: 实施方式涉及为光催化水分解提供适当特性的碳氮化物材料。 氮化碳材料具有三维CN材料，其具有在光催化条件下稳定的高氮含量。 生产光催化CN材料的方法包括（a）使具有选定孔隙度的介孔模板与氨基胍盐酸盐溶液接触，形成模板反应物混合物; 和（b）加热模板反应混合物，形成碳氮化物材料/模板复合材料; （c）在惰性气体气氛中将CN /模板复合物加热至约350℃至450℃，形成立方形中孔碳氮化物材料/模板复合物; 和（d）从中孔氮化碳材料/模板复合物中除去模板。 碳氮基质是基于C3N6二氨基-s-四嗪。
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3.发明申请
公开(公告)号：WO2018220474A1
公开(公告)日：2018-12-06
申请号：PCT/IB2018/053617
申请日：2018-05-22
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： PARK, Dae-Hwan , LAKHI, Kripal S. , RAVON, Ugo , AL-BAHILY, Khalid , SCARANTO, Jessica , VINU, Ajayan
Abstract: Certain embodiments of the invention are directed to nitrogen rich two dimensional hexagonal C 3 N 4.6 mesoporous graphitic carbon nitride (gMCN) material formed from cyclic amino-triazole precursors, the gMCN having a rod shape morphology and an average pore diameter between 4 to 6 nm.
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公开(公告)号：WO2018037322A1
公开(公告)日：2018-03-01
申请号：PCT/IB2017/055017
申请日：2017-08-18
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： LAKHI, Kripal S. , AL-BAHILY, Khalid , RAVON, Ugo , VINU, Ajayan
IPC: C01B21/06
CPC classification number: C01B21/0605 , B01D53/04 , B01D2253/10 , B01D2257/504 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2004/12 , C01P2006/12 , C01P2006/14 , C01P2006/16
Abstract: Methods of producing rod-shaped mesoporous carbon nitride (MCN) materials are described. The method includes (a) obtaining a template reactant mixture comprising an uncalcined rod-shaped SBA-15 template, a carbon source compound, and a nitrogen source compound; (b) subjecting the template reactant mixture to conditions suitable to form a rod-shaped template carbon nitride composite; (c) heating the rod-shaped template carbon nitride composite to a temperature of at least 500 °C to form a rod-shaped mesoporous carbon nitride material/SB A-15 (MCN-SBA-15) complex; and (d) removing the SBA-15 template from the MCN-SBA-15 complex to produce a rod-shaped mesoporous carbon nitride material.
Abstract translation: 描述了生产棒状介孔碳氮化物（MCN）材料的方法。 该方法包括：（a）获得包含未煅烧的棒状SBA-15模板，碳源化合物和氮源化合物的模板反应物混合物; （b）使模板反应物混合物经受适于形成棒状模板碳氮化物复合材料的条件; （c）将棒状模板氮化碳复合材料加热到至少500℃的温度以形成棒状中孔氮化碳材料/ SB A-15（MCN-SBA-15）复合物; 和（d）从MCN-SBA-15复合物中除去SBA-15模板以产生棒状中孔碳氮化物材料。
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5.发明申请MESOPOROUS CARBON NITRIDE MATERIAL COMPRISING MONOMERIC UNITS OF 3-AMIMO-1,2,4,-TRIAZOLE AND UREA 审中-公开包含3-氨基-1,2,4， - 三唑和尿素单体单元的介孔碳氮化物材料
公开(公告)号：WO2018037320A1
公开(公告)日：2018-03-01
申请号：PCT/IB2017/055012
申请日：2017-08-18
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： VINU, Ajayan , MANE, Gurudas P. , RAVON, Ugo , AL-BAHILY, Khalid
IPC: B01J35/04 , B01J35/10 , B01J27/24 , B01J27/224 , B01J37/00 , B01J37/06 , C01B21/06 , B01J20/30 , B01D53/14 , B01D53/02
CPC classification number: C01B21/0605 , B01D53/02 , B01D53/047 , B01D2253/102 , B01D2253/202 , B01D2253/25 , B01D2253/308 , B01D2257/504 , B01D2258/0283 , B01D2258/06 , B01J20/0259 , B01J20/28057 , B01J20/28083 , B01J20/3057 , B01J20/3078 , B01J27/224 , B01J27/24 , B01J35/002 , B01J35/04 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0009 , B01J37/0018 , B01J37/06 , B01J37/082 , Y02C10/06 , Y02C10/08 , Y02P20/152
Abstract: Carbon nitride materials and method of making said carbon nitride materials is described. The carbon nitride materials can be a three dimensional C 3 N 5 3-amino-1,2,4,- triazole and urea based mesoporous carbon nitride matrix having an atomic carbon to nitrogen ratio of 0.55 to 0.8 and basic nitrogen containing groups of between 0.15 to 0.25 mmol per gram.
Abstract translation: 描述了氮化碳材料和制造所述氮化碳材料的方法。 氮化碳材料可以是具有原子碳的三维C 3 N 5 3-氨基-1,2,4， - 三唑和脲基中孔碳氮化物基体 氮比例为0.55-0.8，碱性含氮基团为0.15-0.25mmol /克。
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公开(公告)号：WO2017093880A1
公开(公告)日：2017-06-08
申请号：PCT/IB2016/057166
申请日：2016-11-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： ALMUSAITEER, Khalid A. , AL-BAHILY, Khalid , PARK, Sang-Eon
CPC classification number: C07C1/20 , C07C2529/40 , C07C15/04 , C07C15/06 , C07C15/08
Abstract: A method and systems capable of producing aromatic hydrocarbons from a C3 alcohol using a catalytic metal-containing zeolite catalyst are disclosed. The method and systems can include the use of carbon dioxide as a reactant. The aromatization reactions provide product streams with high single pass aromatic selectivity of benzene, toluene and xylenes (BTX).
Abstract translation: 公开了能够使用含催化金属的沸石催化剂由C3醇制备芳族烃的方法和系统。 该方法和系统可以包括使用二氧化碳作为反应物。 芳构化反应为产物流提供苯，甲苯和二甲苯（BTX）的高通量芳族选择性。
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公开(公告)号：WO2018163003A1
公开(公告)日：2018-09-13
申请号：PCT/IB2018/051156
申请日：2018-02-23
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： VIDJAYACOUMAR, Balamurugan , AL-BAHILY, Khalid , GAMBAROTTA, Sandro , PENEAU, Virginie , ALDERMAN, Nicholas P.
CPC classification number: C07C45/41 , C01B3/26 , C01B2203/1047 , C01B2203/1058 , C01B2203/1076 , C01G9/02 , C01P2004/60 , C01P2004/61 , C07C29/147 , C07C47/04 , C07C31/20
Abstract: Disclosed is a method of producing formaldehyde from formic acid. The method includes obtaining a gaseous mixture comprising formic acid and water vapor and contacting the gaseous mixture with a metal catalyst in a reaction chamber under conditions sufficient to reduce the formic acid to formaldehyde and oxidize the metal to a metal oxide.
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8.发明申请HETEROGENEOUS CATALYSTS/PROCESS BASED ON SUPPORTED/GRAFTED TRANSITION METAL HYDRIDES FOR AMMONIA FORMATION FROM NITROGEN AND HYDROGEN 审中-公开非均相催化剂/基于负载/接枝的过渡金属氢化物用于氨和氢形成氨的过程
公开(公告)号：WO2018033833A1
公开(公告)日：2018-02-22
申请号：PCT/IB2017/054866
申请日：2017-08-09
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： BASSET, Jean Marie , MOHANDAS, Janet Chakkamadathil , VIDJAYACOUMAR, Balamurugan , AL-BAHILY, Khalid , SAMANTARAY, Manoja
Abstract: Disclosed is a catalyst and process for producing ammonia (NH 3 ). The process includes contacting a gaseous feed mixture comprising nitrogen (N 2 ) and hydrogen (H 2 ) with a metal hydride material under reaction conditions sufficient to produce a product stream comprising NH 3 .
Abstract translation: 公开了用于生产氨（NH 3 3）的催化剂和方法。 该方法包括使包含氮气（N 2）和氢气（H 2 2）的气态进料混合物与金属氢化物材料在足以产生包含NH <子> 3
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9.发明申请PREPARATION OF NITROGEN RICH THREE DIMENSIONAL MESOPOROUS CARBON NITRIDE AND ITS SENSING AND PHOTOCATALYTIC PROPERTIES 审中-公开富氮三维介质碳氮化物的制备及其感光和光催化性能
公开(公告)号：WO2018033829A1
公开(公告)日：2018-02-22
申请号：PCT/IB2017/054847
申请日：2017-08-08
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： MANE, Gurudas P. , VINU, Ajayan , RAVON, Ugo , AL-BAHILY, Khalid
CPC classification number: C01B21/0605 , C01B3/042 , C01P2002/72 , C01P2002/82 , C01P2002/84 , C01P2002/85 , C01P2004/03 , C01P2004/04 , C01P2006/12 , C01P2006/14 , C01P2006/16 , Y02E60/364
Abstract: Disclosed are compositions, processes, and methods directed to mesoporous carbon nitride materials having high nitrogen content. The mesoporous carbon nitride material has a three dimensional C 3 N 5 3-amino-1,2,4-triazole based mesoporous carbon nitride matrix having an atomic nitrogen to carbon ratio of 1.4 to 1.7, and a band gap of 1.8 to 3 eV.
Abstract translation: 公开了针对具有高氮含量的中孔氮化碳材料的组合物，方法和方法。 中孔氮化碳材料具有三维C 3 N 5 3-氨基-1,2,4-三唑基中孔氮化碳基体，其具有原子氮碳比 为1.4至1.7，带隙为1.8至3eV。
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10.发明申请
公开(公告)号：WO2017208098A1
公开(公告)日：2017-12-07
申请号：PCT/IB2017/052862
申请日：2017-05-15
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： VIDJAYACOUMAR, Balamurugan , AL-BAHILY, Khalid , GAMBAROTTA, Sandro , PENEAU, Virginie , ALDERMAN, Nicholas P.
IPC: C07C51/235 , C07C53/08
Abstract: Disclosed are methods and systems of producing acetic acid and hydrogen from a two carbon (C 2 ) alcohol source, the method comprising (a) obtaining a homogeneous aqueous solution comprising a C 2 alcohol source and an organoruthenium (II) halide catalyst; and (b) subjecting the homogeneous aqueous solution to conditions suitable to produce a product stream comprising acetic acid and hydrogen.
Abstract translation: 公开了从二碳（C 2 N 4）醇源生产乙酸和氢的方法和系统，所述方法包括（a）获得包含 C18醇源和卤化有机钌（II）催化剂; 和（b）使均匀的水溶液经受适于产生包含乙酸和氢的产物流的条件。
