公开(公告)号：WO2004007561A3

公开(公告)日：2004-08-05

申请号：PCT/US0321913

申请日：2003-07-15

Applicant: UNIVATION TECH LLC

Inventor： WAGNER BURKHARD E ,  JORGENSEN ROBERT J ,  HEPBURN CYNTHIA A

IPC: C01G23/02 ,  C01F5/26 ,  C01F5/30 ,  C01F5/36 ,  C07F3/00 ,  C07F7/00 ,  C08F4/00 ,  C08F4/02 ,  C08F4/50 ,  C08F4/654 ,  C08F110/02 ,  C07F3/02

CPC classification number: C07F3/003 ,  C07F7/006 ,  C08F110/02 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/12

Abstract: A method for increasing the solubility of a magnesium halide includes providing an electron donating solvent, contacting a magnesium halide with the solvent; and providing an electron donor compound to form a magnesium halide composition. The composition is characterized by solubility in the electron donor solvent that does not decrease up to the boiling point of the solvent. A polymerization catalyst precursor composition comprises the product of mixing the magnesium halide composition with a transition metal compound. Active catalysts prepared from such precursors and a method of polymerization using such catalysts are also disclosed.

Abstract translation: 提高卤化镁溶解度的方法包括提供给电子溶剂，使卤化镁与溶剂接触; 并提供电子给体化合物以形成卤化镁组合物。 该组合物的特征在于在电子给体溶剂中的溶解度不降低至溶剂的沸点。 聚合催化剂前体组合物包含将卤化镁组合物与过渡金属化合物混合的产物。 还公开了由这样的前体制备的活性催化剂和使用这种催化剂的聚合方法。