The invention relates to a bisphenol monomer containing anthracene ketone substituent and the preparation method and application, belonging to the technical field of macromolecular materials. The bisphenol monomer containing anthracene ketone substituent is a new compound which is denominated as 4-(2, 6-hydroxyphenoxy phenyl) carbonyl-9-anthracene and of which the preparation method comprises three reaction steps: acylation, preparing semi-finished product containing methoxy group, and attaining bisphenol monomer. The double phenol monomer synthesizes with the double fluorine monomer polymerization to obtain polyetheretherketone resin. The homopolymers and the copolymers are polymers with auto heat cross-bonding property and outstanding optical property, capable of controlling the cross-bonding density through the control of the ratio of mixture of monomers. The the preparation method for the bisphenol monomer containing anthracene ketone substituent has both the proccessibility of thethermoplastic resin and the high thermal stability and corrosion resistance of thermosetting resin.