The invention discloses a super-hydrophobic film with a composite structure, which comprises a film matrix, an adhesive layer and a super-hydrophobic layer. The adhesive layer is adhered to the film matrix; and the super-hydrophobic layer consists of micro-scale powder particles and nano-scale powder particles which are arranged at intervals and embedded into the film matrix, have low surface energy or are modified by low surface energy substances, and micro-scale protrusions and nano-scale protrusions are formed on the surface of the adhesive layer. The super-hydrophobic film has the advantages of simple structure, easy preparation and lower cost; a water contact angle of the super-hydrophobic layer is between150 and 165 degrees, and a roll angle is less than 5 degrees; the super-hydrophobic film is provided with the adhesive layer and has no special requirement on a matrix material; and a super-hydrophobic structure can be arranged on the matrix with higher hardness; the super-hydrophobic film self has certain strength and hardness and excellent mechanical property, can be used in the occasions with higher mechanical requirements, and can also be used in the occasions needing water proofing, pollution prevention, mist resistance, snow cover resistance, ice coating resistance, oxidation prevention and the like; and the super-hydrophobic film adopts the film matrix, occupies little space, and is convenient and simple to use.