The invention discloses composite electrode materials for a high power lithium secondary battery and a preparation method thereof. The composite electrode materials take lithium-storage active material as an inner core, conductive polymer as an outer shell, the active material inner core is mainly used for carrying out electrochemical reaction and providing main capacity for a battery, the conductive polymer material is used as a conductive agent and an adhesive when preparing electrodes, and simultaneously provides a certain amount of battery capacity by electrochemical doping and undoping reaction. By using the composite electrode materials for preparing electrodes, adhesive and conductive agent with electrochemical inertia can not be used or be used in a small amount, and the lithium secondary battery based on the composite electrode materials has high specific capacity and fine rate performance.