The invention provides a polymer with the following hydrogen bond supermolecule net-structure, which has significant thermal restoring performance and good mechanical strength and elasticity, and facilitates the low temperature shaping process and cyclic utilization of the material. The synthesized oligomer is used as the skeleton of the hydrogen bond net-structured supermolecule polymer, and themain chain of the synthesized oligomer is provided with groups of hydrogen bond-forming factors such as carbonyl group (C=O), amino-group (-NH- or -NH2), sulfonyl group (O=S=O) and the like. Because the acting force of the hydrogen bond is much smaller than the force of the covalent bond, the length of the hydrogen bond is increased and the association speed is accelerated during the process of raising the temperature, so that the hydrogen bond supermolecule polymer has a lower melting point, thereby having better thermal restoring performance. In addition, though the single hydrogen bond force is smaller, the hydrogen bond supermolecule net-structure has good mechanical strength and elasticity due to the stable structure of the hydrogen bond supermolecule net-structure.