The invention discloses nitrogen doped graphene with a regular morphology and a preparation method thereof. The nitrogen doped graphene is prepared by adopting a chemical vapor deposition method. The preparation method comprises the following steps of: placing a metal catalyst into a reactor; heating in the non-oxidizing atmosphere to ensure the temperature of the catalyst rises to 200 to 600 DEG C; and then filling carbon and nitrogen sources into the reactor to perform the reaction to obtain the nitrogen doped graphene. The nitrogen doped graphene prepared by the invention is regular nitrogen doped graphene with a quadrangular structure. The layer number of the nitrogen doped graphene can be 1 to 10. The nitrogen doped graphene not only can be of a polycrystal structure, but also can be of a single crystal structure. The method for preparing the nitrogen doped graphene with the regular morphology, which is provided by the invention, has simple process and low economic cost and is environmental-friendly. The nitrogen doped graphene with the regular morphology can be produced in a large scale.