The invention discloses a method for removing harmful anions from an aqueous solution by adopting a Friedel salt or Kuzel salt. The method comprises a step of removing the harmful anions from the aqueous solution by adopting the Friedel salt or Kuzel salt, wherein the harmful anions comprise one or more of F<->, CN<->, SCN<->, As (III, V) and Cr (VI), and the aqueous solution comprises one or more of drinking water, underground water sources, industrial wastewater and tailings water containing harmful anions. According to the method disclosed by the invention, the Friedel salt or Kuzel salt is applied to the aqueous solution containing the harmful anions, the removal efficiency of the harmful anions is very high, and the effect is obvious; the materials required for preparing the Friedel salt or Kuzel salt are wide in source, low in preparation energy consumption and less in investment; by adopting the method to remove the anions from the aqueous solution, the flow is short and the cost is low, so that the method has a wide application prospect.