The invention provides an anti-static self-exhaust protection adhesive tape and a preparation method thereof. The anti-static self-exhaust protection adhesive tape successively comprises a base material (1), an adhesive layer (3) and a release film (4); and an anti-static layer (2) is arranged between the base material (1) and the adhesive layer (3). The anti-static self-exhaust protection adhesive tape possesses excellent anti-static performance, the anti-static performance also possesses excellent thermal stability, a defect of pollution caused by transference of ionic additives onto the surface of the anti-static self-exhaust protection adhesive tape is avoided, quick attachment can be realized when the anti-static self-exhaust protection adhesive tape is contacted with the surface of glass or a mirror plane, and the anti-static self-exhaust protection adhesive tape possesses self-exhaust performance.