The present invention discloses an organic light-emitting diode (OLED) and an electronic device, wherein the OLED includes a first carrier transport layer and a second carrier transport layer that are set opposite to each other, and a light-emitting layer; the light-emitting layer includes a first light-emitting sub-layer with a hollow structure, and a second light-emitting sub-layer which includes a body part and a projecting part, wherein the projecting part projects from the body part and is accommodated in the hollow structure; wherein a surface of the first light-emitting sub-layer and a surface of the projecting part form the first surface of the light-emitting layer, and a surface of the body part forms the second surface of the light-emitting layer. By the present invention, the working voltage is lowered, the power consumption is reduced, and in addition, the manufacturing process is simplified due to the reduction of the number of layers.