The invention discloses a hybrid perovskite material with high stability. The hybrid perovskite material is of an ABO3 type perovskite structure formed by organic amine positive ions RnNH4-n, metal cations M and halide anions, and the formula of the hybrid perovskite material is RnNH4-nM(IyX1-y)3, wherein n is equal to 2 or 3 or 4, and y is more than 0 and less than or equal to 1. The hybrid perovskite material has strong stability for humidity and air, can be used for manufacturing an optical active layer in a solar cell device and can be used for manufacturing a perovskite solar cell device, also can be used for manufacturing a luminous layer in an electroluminescent device or manufacturing the electroluminescent device, and also can be used for manufacturing a photocatalytic active material or used for photocatalytically splitting water for generating hydrogen.