The invention discloses a method for rapidly evaluating the adhesive property of interface between nitrate ester plasticized polyether propellant and a lining. The method comprises the following steps: step one, determining the detection conditions: preparing a sample, choosing equipment, and determining the standards; step two, carrying out detection: performing spectral detection, and marking the coordinate; step three, finishing performance evaluation: establishing an empirical formula, and analyzing the evaluation indexes. According to the method, a microscopic infrared spectrometer is utilized to measure the infrared spectroscopy of the area along the interface normal direction so as to obtain the diffusion layer position coordinates; then the empirical formula of diffusion layer thickness and macro-mechanical properties is established, the empirical formula can be used to evaluate the relationship between the basic formula and adhesive strength in interface adhesion, the rapid evaluation on the adhesive property of the interface between a propellant and lining can be achieved; and the provided method can be used to screen and adjust the formula of propellant/lining and evaluate the storage property of the adhesive interface. The provided method has the advantages of low labor cost, low detection fee, simple process, convenient operation, reasonable index, and accurate evaluation.