A resistive welding electrode includes at least a weld face constructed of a refractory-based material that exhibits an electrical conductivity that is less than or equal to 65% of the electrical conductivity of commercially pure annealed copper as defined by the International Annealed Copper Standard (IACS). A method of using the resistive welding electrode to resistance spot weld a workpiece stack-up that includes an aluminum alloy workpiece and steel workpiece that overlap and contact each other at a faying interface is also disclosed.