The invention relates to a block copolymer and the use thereof as a cold resistance additive of a fuel or combustible. The block copolymer comprises: (i) a block A consisting of a chain of structural motifs derived from at least one [alpha],[beta]-unsaturated alkyl methacrylate or acrylate monomer; and (ii) a block B consisting of a chain of structural motifs derived from at least one [alpha],[beta]-unsaturated monomer selected from styrene derivatives, the aromatic ring of which is substituted by at least one group R selected from the groups: C1 to C24 alkyl esters, and preferably acyclic linear or branched C1 to C12 hydrocarbonated chains, the chain being substituted by at least one group containing a quaternary ammonium salt. The invention also relates to an additive concentrate containing such a copolymer and to the use thereof as an anti-sedimentation additive, and advantageously, as a TLF booster additive.