An asbestos-free friction material includes inorganic and/or organic and/or metallic fibers, at least one binder, at least one friction modifier or lubricant, at least one filler or abrasive and a carbonaceous material constituted by a microstructure. The microstructure is in the form of flakes or scales of micrometric planar dimensions and of nanometric thickness consisting of a substantially pure graphene mono- or multilayers, preferably pre-blended with at least part of the organic binder.