The invention discloses a power distribution station building navigation addressing system and an addressing method based on the system. The power distribution station building navigation addressing system comprises a plurality of mobile phones, a map service station, a housing estate access control system, a plurality of power distribution station monitoring systems and a power distribution service station. The map service station is used for serving the operation of Amap; the housing estate access control system comprises an access control server, an access control WiFi device and an accesscontrol Bluetooth device; the access control WiFi device and the access control Bluetooth device are connected with the access control server; each power distribution station building is provided withone power station monitoring system; each power station monitoring system comprises a monitoring device, a control device and a power station WiFi device; each monitoring device and each power station WiFi device are connected to each control device; the access control servers of all housing estate access control systems are in communication connection with the power distribution service station.The power distribution station building navigation addressing system and the addressing method based on the system solve the problem that in the prior art, the power distribution station building tobe maintained cannot be found conveniently.