The invention provides sulfoaluminate cement clinker using a tin tailing as a raw material. The sulfoaluminate cement clinker is prepared from the following raw materials in percentage by weight: 10 to 40 percent of the tin tailing, 20 to 50 percent of aluminum ash, 20 to 50 percent of carbide slag and 5 to 35 percent of desulfurization gypsum. A method utilizes the tin tailing to partially replace a part of sulfur raw material used for producing conventional sulfoaluminate cement clinker and to completely displace a siliceous raw material; after the tin tailing is pulverized until to certainfineness, the generation of essential minerals in cement clinker is controlled through a basicity factor Cm and an aluminum-to-sulfur ratio; the cement clinker is used for preparing the sulfoaluminatecement clinker together with accessories of the aluminum ash, the carbide slag and the desulfurization gypsum, and the like, and the sulfoaluminate cement clinker provided by the invention can be used for meeting a provision in a current national standard.