The invention belongs to the technical field of photoelectric materials, and particularly relates to an organic photoelectric material and application thereof. The organic photoelectric material has amolecular structure shown as a formula I, wherein, R1 is selected from one of phenyl, alkyl phenyl, biphenyl, naphthyl, phenanthryl, anthryl, fluorenyl and dibenzofuran, R2, R3, R4, R5, R6 and R7 areindependently selected from hydrogen atom, fluorine atom, cyan, isothiocyanate and aromatic heterocyclic radical of 10-50 in carbon atom number and containing at least one of N, S and O. The organicphotoelectric material has high thermostability and high glass transition temperature and can serve as a luminous material to be applied in organic electroluminescence devices, so that maximum currentefficiency of the organic electroluminescence devices is improved, turn-on voltage of the organic electroluminescence devices is lowered, and spectrum covering range of visible light emitted by the organic electroluminescence devices is wide.