The invention belongs to the technical field of chemical engineering, and particular relates to anti-electrostatic organic/inorganic composite anticorrosive pigment. The anti-electrostatic anticorrosive pigment is prepared from graphene, benzotriazole and zinc tungstate. A product is synthesized through an in-situ self-heating synthesis method. The anti-electrostatic organic/inorganic composite anticorrosive pigment prepared by the method has the advantages of being good in anti-electrostatic property, strong in corrosion resistance, good in mechanical property, and the like; and a conductivefilm prepared from conductive filler has the characteristics of being lasting and stable in conductive performance, fine and wear-resisting, strong in corrosion resistance and mechanical impact resistance and the like. Requirements on anti-static electricity capacity and corrosion resistance of anti-electrostatic anticorrosive pigment are met by regulating adding amount of graphene, so that novelfunctional filler and a preparation method thereof are provided for the fields such as anti-electric field and corrosion resistance field.