The invention relates to a gas sensitive sensing monitoring probe with sampling resistors and application of the probe, and mainly solves the problems of low versatility and compatibility in the priorart. The gas sensitive sensing monitoring probe comprises a sensing plate of a gas sensitive material, a monitor probe, the sampling resistors, a cable and a monitor segment jack, an interface of themonitor probe includes four metal springs for making contact with an interdigital electrode on the sensing plate of the gas sensitive material, and in a circuit of the monitor of the monitor probe, Rk1 and Rk2 are the sampling resistors respectively, Rx represents a resistor of a gas-sensitive material membrane to be detected, the Rk1 and Rk2 are connected in parallel and then in series with theRx, and the Rk1 is integrated in the monitor probe. The above problems are effectively solved, and the probe can be applied to gas sensitive sensing monitoring.