The cationic emulsifier wax includes paraffin, cationic surfactant, coemulsifier and water. It is prepared through the process including smelting and mixing paraffin and coemulsifier in the containerwith stirrer and heating to emulsifying temperature; heating to dissolve cationic surfactant in water inside one other container and heating to emulsifying temperature to prepare water solution of surfactant; adding the water solution of surfactant slowly into reactor while stirring for some period; cooling while stirring to room temperature and packing the product. The product may be stored stably for at least 60 days. It may be used as antistatic agent and softening agent for fabric.