The present invention relates to a catalyst for hydrogenation treatment of naphtha containing olefine and its preparation method, which mainly uses macroporous or mesoporous acidic zeolite molecular sieve, and its composition includes 40-80 wt% of acitic zeolite molecular sieve, 0-60 wt%, of gamma-Al2O3 and 0-20 wt% of metal of group VIB and group VIII. Said catalyst has excellent hydrogenation desulfurization property and aromatization property, not only can reduce sulfur content of naphtha containing olefine, but also can obviously reduce its olefine content at the same time. It has excellent catalystic activity and good stability.