发明公开
EP0013144A1 Substituted diphenylamine derivatives, compositions and herbicidal uses thereof, and processes for their preparation 失效
取代的二苯基胺衍生物,它们的除草组合物和它们的制备的用途和方法。

Substituted diphenylamine derivatives, compositions and herbicidal uses thereof, and processes for their preparation
摘要:
The compounds are herbicides. Herbicidal compositions containing as active ingredient a compound of formula I, a process for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I, processes for the preparation of compounds of formula I and intermediates useful in the preparation of compounds of formula I are described.
Prepared are compounds of formula I
or a salt thereof wherein:

A, B, D, E, T, U and V are independently chosen from the group consisting of hydrogen, halogen, nitro, cyano, thiocyano, possibly halogenated alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, possibly alkylated amino, sulfo, sulfamoyl, carboxy, carbamoyl, C 2 to C 6 alkenyl, C 3 to C 7 cyclo-alkyl, possibly substituted phenyl, phenoxy, phenylthio groups, and wherein at least one of A, B, D, E and T is not hydrogen, the alkyl groups containing 1 to 6 carbon atoms,
R' is chosen from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, alkoxyalkyl, haloalkyl, alkanoyl, all containing at most 10 carbon atoms, or possibly substituted phenyl, benzyl, benzoyl,
R 2 is chosen from the group consisting of hydrogen, alkyl, alkenyl, alkoxyalkyl, haloalkyl, all containing at most 6 carbon atoms, and acetyl, propionyl, and C 2 to C 6 alkoxy-carbonyl, R 3 is chosen from the group consisting of hydrogen, alkyl, alkenyl, alkoxyalkyl, all containing at most 6 carbon atoms, and C 1 to C 4 haloalkyl, or R 2 and R 3 together may form a C 1 to C 3 alkylidene group,
W is chosen from the group consisting of cyano, thiocar- bamoyl, -C-G and CH 2 Z wherein:
G is chosen from the group consisting of hydroxy, mercapto, possibly substituted C 1 to C 10 alkoxy, and C 2 to C 10 alkenyloxy, C 2 to C 10 alkynyloxy, C 1 to C 10 alkylthio, C 2 to C 10 alkenylthio, C 2 to C 10 alkynylthio, possibly substituted C 3 to C 7 cycloalkoxy, possibly substituted phenoxy, phenylthio, benzyloxy, benzylthio, the group OM wherein M is the cation of an inorganic or organic base, the group-NNSO 2 R 4 wherein R 4 is chosen from C 4 to C 10 , alkyl and C, to C 10 haloalkyl, and the group -NR 5 R 6 wherein R 5 and R 6 are independently chosen from the group consisting of hydrogen, C 1 to C 6 alkyl, phenyl and benzyl or R 5 and R 6 together form a heterocyclic ring and
Z is chosen from the group consisting of halogen, hydroxy, mercapto, possibly substituted C 1 to C 10 alkoxy, possibly substituted C 1 to C 10 alkylthio, formyl, and the group NR 5 R 6 wherein R 5 and R 6 are as hereinbefore defined:
X is chosen from oxygen and sulfur and
n is 0, 1 or 2.
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