发明公开
EP0145288A2 Improved low severity hydrocarbon steam reforming process
失效
Verfahren vom“低度严重性”-Typ zur Dampfreformierung von Kohlenwasserstoffen。
- 专利标题: Improved low severity hydrocarbon steam reforming process
- 专利标题(中): Verfahren vom“低度严重性”-Typ zur Dampfreformierung von Kohlenwasserstoffen。
-
申请号: EP84307757.9申请日: 1984-11-09
-
公开(公告)号: EP0145288A2公开(公告)日: 1985-06-19
- 发明人: Osman, Robert Michael , Byington, Robert George
- 申请人: EXXON RESEARCH AND ENGINEERING COMPANY
- 申请人地址: P.O.Box 390, 180 Park Avenue Florham Park, New Jersey 07932-0390 US
- 专利权人: EXXON RESEARCH AND ENGINEERING COMPANY
- 当前专利权人: EXXON RESEARCH AND ENGINEERING COMPANY
- 当前专利权人地址: P.O.Box 390, 180 Park Avenue Florham Park, New Jersey 07932-0390 US
- 代理机构: Haigh, Charles Roy
- 优先权: US550553 19831110
- 主分类号: C01C1/04
- IPC分类号: C01C1/04 ; C01B3/02
摘要:
0 In a process for producing ammonia which comprises: primary (4) and secondary (60) catalytically reforming shift conversion (80 and 90); carbon oxides removal (115); and ammonia synthesis (110), wherein at least a portion of an ammonia-depleted gas stream is recycled to the synthesis zone (110); and sidestream (134) of the ammonia-depleted gas is treated to separate a stream (142) enriched in hydrogen for return to the ammonia synthesis zone; the improvement which comprises: (i) operating step (b) at a temperature in the outlet gas of not greater than about 946°C and with an amount of air sufficient to provide from about 3 to 11 molar % excess N 2 and to form a secondary reformer outlet gas containing at least 0.8 vol. % methane; (ii) operating step (e) under conditions sufficient to provide at least 10 vol. % inert gases in the ammonia-depleted gas stream; and (iii) introducing as synthesis gas feed to the ammonia synthesis zone a mixture comprising the synthesis gas formed in step (d) having a methane content of at least about 1.2 mol.% CH 4 , on a dry basis, the recycled gas produced in step (f) plus the hydrogen-enriched gas stream formed in step (g), whereby the H 2 loss from the process with the separated inerts enriched gas stream is minimized.
信息查询
IPC分类: