发明公开
- 专利标题: Process for the preparation of quinones
- 专利标题(中): 制备醌的方法
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申请号: EP86308264.0申请日: 1986-10-23
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公开(公告)号: EP0220948A1公开(公告)日: 1987-05-06
- 发明人: Griggs, Colin George
- 申请人: The British Petroleum Company p.l.c.
- 申请人地址: Britannic House Moor Lane London EC2Y 9BU GB
- 专利权人: The British Petroleum Company p.l.c.
- 当前专利权人: The British Petroleum Company p.l.c.
- 当前专利权人地址: Britannic House Moor Lane London EC2Y 9BU GB
- 代理机构: Fawcett, Richard Fennelly
- 优先权: GB8526630 19851029
- 主分类号: C07C50/04
- IPC分类号: C07C50/04 ; C07C46/06 ; C07C37/07 ; C07C39/08
摘要:
A process for the production of quinones from an aromatic alcohol is described. The process uses a hydrocarbyl hydroperoxide, e.g t-butylhydroperoxide, and a copper catalyst to effect the reaction. The use of a hydrocarbyl hydroperoxide improves the rate of reaction relative to the use of hydrogen peroxide. The process is particularly useful as a first stage in the production of 2, 3, 6-trimethylhydroquinone, a Vitamin E precursor, from cheap, readily available starting materials.
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