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    Process for the preparation of quinones
    5.
    发明公开
    Process for the preparation of quinones 失效
    制备醌的方法

    公开(公告)号：EP0220948A1

    公开(公告)日：1987-05-06

    申请号：EP86308264.0

    申请日：1986-10-23

    申请人： The British Petroleum Company p.l.c.

    发明人： Griggs, Colin George

    IPC分类号： C07C50/04 ,  C07C46/06 ,  C07C37/07 ,  C07C39/08

    CPC分类号： C07C46/06 ,  C07C37/07 ,  C07C39/08

    摘要： A process for the production of quinones from an aromatic alcohol is described. The process uses a hydrocarbyl hydroperoxide, e.g t-butylhydroperoxide, and a copper catalyst to effect the reaction. The use of a hydrocarbyl hydroperoxide improves the rate of reaction relative to the use of hydrogen peroxide. The process is particularly useful as a first stage in the production of 2, 3, 6-trimethylhydroquinone, a Vitamin E precursor, from cheap, readily available starting materials.

    摘要翻译： 描述了从芳香醇生产醌的方法。 该方法使用烃基氢过氧化物如叔丁基氢过氧化物和铜催化剂进行反应。 烃基氢过氧化物的使用相对于使用过氧化氢提高了反应速率。 该方法作为从廉价易得的原料生产2,3,6-三甲基对苯二酚，维生素E前体的第一阶段特别有用。

    Process for the preparation of quinones
    6.
    发明公开
    Process for the preparation of quinones 失效
    Verfahren zur Herstellung von Chinonen。

    公开(公告)号：EP0175574A1

    公开(公告)日：1986-03-26

    申请号：EP85306624.9

    申请日：1985-09-18

    申请人： The British Petroleum Company p.l.c.

    发明人： Griggs, Colin George

    IPC分类号： C07C50/02 ,  C07C46/06 ,  C07C37/07

    CPC分类号： C07C46/06

    摘要： A process for the production of quinones from an aromatic hydroxy compound is described. The process uses a hydrocarbyl hydroperoxide, e.g. t-butylhydroperoxide, a weak acid and a ruthenium catalyst to effect the reaction. The use of a hydrocarbyl hydroperoxide improves the rate of reaction relative to the use of hydrogen peroxide. The process is particularly useful as a first stage in the production of 2,3,6-trimethylhydroquinone, a Vitamin E precursor, from cheap, readily available starting materials.

    摘要翻译： 描述了由芳族羟基化合物制备醌的方法。 该方法使用烃基氢过氧化物，例如 叔丁基过氧化氢，弱酸和钌催化剂进行反应。 烃基氢过氧化物的使用提高了使用过氧化氢的反应速率。 该方法作为生产2,3,6-三甲基氢醌（一种维生素E前体）的廉价廉价起始材料的第一阶段是特别有用的。

    Process for the production of ethanol and/or acetaldehyde by the metal catalysed liquid phase reaction of methanol, carbon monoxide and hydrogen in the presence of a solvent
    7.
    发明公开
    Process for the production of ethanol and/or acetaldehyde by the metal catalysed liquid phase reaction of methanol, carbon monoxide and hydrogen in the presence of a solvent 失效
    在溶剂存在下，通过金属催化液相反应甲醇，一氧化碳和氢气生产乙醇和/或乙炔的方法

    公开(公告)号：EP0141535A3

    公开(公告)日：1985-06-26

    申请号：EP84306766

    申请日：1984-10-04

    申请人： The British Petroleum Company p.l.c.

    发明人： Griggs, Colin George ,  Lodge, Philip Geoffrey

    IPC分类号： C07C47/06 ,  C07C45/49 ,  C07C29/32 ,  C07C31/08

    CPC分类号： C07C29/32 ,  C07C45/49 ,  C07C47/06 ,  C07C31/08

    摘要： A recycle solvent for use in a metal catalysed process for the production of ethanol and/or acetaldehyde by the liquid phase reaction of methanol, carbon monoxide and hydrogen is provided. The solvent should (i) form a single phase with methanol and the liquid products of the process throughout the process; (2) be one in which the catalyst and any associated promoters are soluble; (3) have a boiling point at atmospheric pressure in excess of 120°C and (4) should be chemically stable under the reaction conditions and not interact in a deliterious manner with either the catalyst or the other components of the reaction. A preferred class of recycle solvent is sulpholane and its substituted derivatives.

    摘要翻译： 提供了用于通过甲醇，一氧化碳和氢气的液相反应生产乙醇和/或乙醛的金属催化方法中的再循环溶剂。 溶剂应（1）在整个过程中与甲醇形成单相和整个过程的液体产物; （2）是催化剂和任何相关促进剂可溶的催化剂; （3）的沸点在大气压下超过120℃，（4）在反应条件下应具有化学稳定性，并且不会与催化剂或反应的其它组分相互作用。 优选的一类再循环溶剂是环丁烷及其取代的衍生物。

    Process for the production of ethanol and/or acetaldehyde by the metal catalysed liquid phase reaction of methanol, carbon monoxide and hydrogen in the presence of a solvent
    10.
    发明公开
    Process for the production of ethanol and/or acetaldehyde by the metal catalysed liquid phase reaction of methanol, carbon monoxide and hydrogen in the presence of a solvent 失效
    一种用于通过在金属催化剂和溶剂的存在下甲醇，一氧化碳和氢的液相反应生产乙醇和/或乙醛的过程。

    公开(公告)号：EP0141535A2

    公开(公告)日：1985-05-15

    申请号：EP84306766.1

    申请日：1984-10-04

    申请人： The British Petroleum Company p.l.c.

    发明人： Griggs, Colin George ,  Lodge, Philip Geoffrey

    IPC分类号： C07C47/06 ,  C07C45/49 ,  C07C29/32 ,  C07C31/08

    CPC分类号： C07C29/32 ,  C07C45/49 ,  C07C47/06 ,  C07C31/08

    摘要： A recycle solvent for use in a metal catalysed process for the production of ethanol and/or acetaldehyde by the liquid phase reaction of methanol, carbon monoxide and hydrogen is provided. The solvent should (i) form a single phase with methanol and the liquid products of the process throughout the process; (2) be one in which the catalyst and any associated promoters are soluble; (3) have a boiling point at atmospheric pressure in excess of 120°C and (4) should be chemically stable under the reaction conditions and not interact in a deliterious manner with either the catalyst or the other components of the reaction. A preferred class of recycle solvent is sulpholane and its substituted derivatives.

    摘要翻译： 提供了一种通过甲醇，一氧化碳和氢的液相反应在金属催化过程中使用用于生产乙醇和/或乙醛的再循环的溶剂。 溶剂shoulderstand（1）形成具有甲醇单相并且该过程在整个过程中的液体产品; （2）是一个在其中催化剂和任何相关联的启动子是可溶的; （3）具有在超过120℃的，（4）应在反应条件下是化学稳定和以这样的方式与deliterious无论是催化剂或反应的其它组分不相互作用大气压下的沸点。 一类优选的循环溶剂的是环丁砜及其衍生物substituiertem。