发明公开
EP0268985A3 A process for producing a modified ethylene-alpha-olefin copolymer rubber
失效
改性乙烯 - 丙烯共聚物橡胶及其制造方法
- 专利标题: A process for producing a modified ethylene-alpha-olefin copolymer rubber
- 专利标题(中): 改性乙烯 - 丙烯共聚物橡胶及其制造方法
-
申请号: EP87116991.8申请日: 1987-11-17
-
公开(公告)号: EP0268985A3公开(公告)日: 1990-03-21
- 发明人: Takao, Hiroyoshi , Imai, Akio , Tsuji, Mitsuji
- 申请人: SUMITOMO CHEMICAL COMPANY, LIMITED
- 申请人地址: Kitahama 4-chome 5-33 Chuo-ku Osaka 541 JP
- 专利权人: SUMITOMO CHEMICAL COMPANY, LIMITED
- 当前专利权人: SUMITOMO CHEMICAL COMPANY, LIMITED
- 当前专利权人地址: Kitahama 4-chome 5-33 Chuo-ku Osaka 541 JP
- 代理机构: Henkel, Feiler, Hänzel & Partner
- 优先权: JP279422/86 19861121
- 主分类号: C08F255/02
- IPC分类号: C08F255/02 ; C08F2/02
摘要:
A modified copolymer rubber obtained by kneading at 200-280°C
(A) at least one copolymer rubber material selected from the group consisting of an ethylene-α-olefin copolymer rubber having a number-average molecular weight of 10,000-100,000 and an ethylene content of 15-85% by weight and an ethylene-α-olefin-nonconjugated diene copolymer rubber having a number-average molecular weight of 10,000-100,000, an ethylene content of 15-85% by weight and a nonconjugated diene content of 3.0% by weight or less, (B) a free-radical initiator, (C) at least one vinyl aromatic monomer and (D) an unsaturated dicarboxylic anhydride, the bound vinyl aromatic monomer content and the bound unsaturated dicarboxylic anhydride content in the modified copolymer rubber being 0.1-5% by weight and 0.1-5% by weight, respectively, based on the weight of the copolymer rubber material and a process for producing the same are disclosed. This modified copolymer rubber obtained has so excellent properties such as a high bound unsaturated dicarboxylic anhydride content, a low gel formation property, a low tendency of increase of the Mooney viscosity [ML 1+4 (121°C)], and an excellent moldability and storage stability that it can be suitably used for thermoplastic elastomer, blending polymer, adhesive etc.
(A) at least one copolymer rubber material selected from the group consisting of an ethylene-α-olefin copolymer rubber having a number-average molecular weight of 10,000-100,000 and an ethylene content of 15-85% by weight and an ethylene-α-olefin-nonconjugated diene copolymer rubber having a number-average molecular weight of 10,000-100,000, an ethylene content of 15-85% by weight and a nonconjugated diene content of 3.0% by weight or less, (B) a free-radical initiator, (C) at least one vinyl aromatic monomer and (D) an unsaturated dicarboxylic anhydride, the bound vinyl aromatic monomer content and the bound unsaturated dicarboxylic anhydride content in the modified copolymer rubber being 0.1-5% by weight and 0.1-5% by weight, respectively, based on the weight of the copolymer rubber material and a process for producing the same are disclosed. This modified copolymer rubber obtained has so excellent properties such as a high bound unsaturated dicarboxylic anhydride content, a low gel formation property, a low tendency of increase of the Mooney viscosity [ML 1+4 (121°C)], and an excellent moldability and storage stability that it can be suitably used for thermoplastic elastomer, blending polymer, adhesive etc.
公开/授权文献
信息查询