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    Transition metal complex, process for producing the same, olefin polymerization catalyst containing the transition metal complex and process for producing olefin polymers
    2.
    发明公开
    Transition metal complex, process for producing the same, olefin polymerization catalyst containing the transition metal complex and process for producing olefin polymers 失效
    Übergangsmetallkomplexund Verfahren zu seiner Herstellung

    公开(公告)号：EP1498178A2

    公开(公告)日：2005-01-19

    申请号：EP04021924.8

    申请日：1996-07-15

    申请人： Sumitomo Chemical Company, Limited

    发明人： Katayama, Hiroaki ,  Nabika, Masaaki ,  Imai, Akio ,  Miyashita, Akira ,  Watanabe, Tsuyoshi ,  Johohji, Hirofumi ,  Oda, Yoshiaki ,  Hanaoka, Hidenori

    IPC分类号： B01J31/22 ,  C07B61/00 ,  C07C41/30 ,  C07C43/215 ,  C07F7/08 ,  C07F7/12 ,  C07F7/28 ,  C07F17/00 ,  C08F4/642 ,  C08F10/00

    CPC分类号： B01J31/143 ,  B01J31/146 ,  B01J31/2204 ,  B01J31/2226 ,  B01J31/2295 ,  B01J31/26 ,  B01J2531/40 ,  B01J2531/46 ,  C07F5/00 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F210/14 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/10

    摘要： A transition metal complex represented by the formula (1)
    wherein M 1 is a transition metal atom of the group 4 of the periodic table of elements; A is an atom of the group 16 of the periodic table of elements, and B is an atom of the group 14 of the periodic table of elements; Cp 1 is a group having a cyclopentadiene type anionic skeleton; and X 1 , X 2 , R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are each independently a hydrogen atom, halogen atom, alkyl group with the number of carbon atoms of 1-20 optionally substituted with at least one halogen atom, aralkyl group with the number of carbon atoms of 7-20 optionally substituted with at least one halogen atom, aryl group with the number of carbon atoms of 6-20 optionally substituted with at least one halogen atom, substituted silyl group with the number of carbon atoms of 1-20 optionally substituted with at least one halogen atom, alkoxy group with the number of carbon atoms of 1-20 optionally substituted with at least one halogen atom, aralkyloxy group with the number of carbon atoms of 7-20 optionally substituted with at least one halogen atom or aryloxy group with the number of carbon atoms of 6-20 optionally substituted with at least one halogen atom, or di-substituted amino group with the number of carbon atoms of 2-20, provided that R 1 , R 2 , R 3 , R 4 , R 5 and R 6 may optionally combine with each other to form a ring; a process for producing the same; an olefin polymerization catalyst containing the transition metal complex; and a process for producing olefin polymers.

    摘要翻译： 由式（1）表示的过渡金属络合物其中M 1是元素周期表第4族的过渡金属原子; A是元素周期表中第16族的原子，B是元素周期表第14族的原子; Cp 1是具有环戊二烯型阴离子骨架的基团; 和X 1，X 2，R 1，R 2，R 3，R 4，R 5和R 6各自独立地为氢原子，卤素原子， 具有任选被至少一个卤素原子取代的碳原子数1-20的烷基，任选被至少一个卤素原子取代的碳原子数为7-20的芳烷基，具有碳原子数的芳基 任选被至少一个卤素原子取代的，任选被至少一个卤素原子取代的碳原子数为1-20的取代甲硅烷基，任选被至少一个卤素原子取代的碳原子数1-20的烷氧基，任选被 至少一个卤素原子，具有任选被至少一个卤素原子取代的碳原子数为7〜20的芳烷氧基或任选被至少一个卤素原子取代的碳原子数为6〜20的芳氧基，或二 取代的氨基，碳原子数为2-20，条件是R 1，R 2，R 3，R 4，R 5和R 5， 6>可以任选地彼此结合形成环; 其制造方法; 含有过渡金属络合物的烯烃聚合催化剂; 和烯烃聚合物的制造方法。

    Alpha-olefin polymerization catalyst and process for producing alpha-olefin polymer
    3.
    发明公开
    Alpha-olefin polymerization catalyst and process for producing alpha-olefin polymer 失效
    卡塔尔计算机模拟Alpha-Olefinpolymerisation和Verfahren zur Herstellung von Alpha-Olefinpolymeren

    公开(公告)号：EP0748820A1

    公开(公告)日：1996-12-18

    申请号：EP96109024.8

    申请日：1996-06-05

    申请人： SUMITOMO CHEMICAL COMPANY LIMITED

    发明人： Fujiwara, Yasuki ,  Satoh, Makoto ,  Imai, Akio

    IPC分类号： C08F10/00 ,  C08F4/646

    CPC分类号： C08F10/00 ,  C08F4/6465

    摘要： An α-olefin polymerization catalyst which comprises:

    (A) a solid catalyst component containing a tetra-valent titanium obtained by treating a magnesium compound having an Mg-O bond in its molecule with a titanium halide;
    (B) an organoaluminum compound; and
    (C) an organosilicon compound represented by the general formula R 1 R 2 Si(OR 3 ) 2
    wherein R 1 represents a hydrocarbon group having 4 to 30 carbon atoms wherein a carbon bonded directly to Si is a tertiary carbon, R 2 represents a straight chain hydrocarbon group having 2 to 20 carbon atoms and R 3 represents a hydrocarbon group having 1 to 10 carbon atoms, or the general formula R 4 R 5 Si(OR 6 ) 2
    wherein R 4 and R 5 are hydrocarbon groups having an alicyclic hydrocarbon having 5 carbon atoms as a basic structure, R 4 and R 5 may be the same or different, and R 6 represents a hydrocarbon group having 1 to 10 carbon atoms, and a process for producing α-olefin with said catalyst.

    摘要翻译： 一种α-烯烃聚合催化剂，其包括：（A）含有通过用卤化钛处理其分子中具有Mg-O键的镁化合物而获得的四价钛的固体催化剂组分; （B）有机铝化合物; 和（C）由通式R 1 R 2 Si（OR 3）2表示的有机硅化合物，其中R 1表示具有4至30个碳原子的烃基，其中直接与Si键合的碳 是叔碳，R 2表示碳原子数2〜20的直链烃基，R 3表示碳原子数1〜10的烃基，或通式R 4 R 5 Si （OR 6）2其中R 4和R 5是具有5个碳原子的脂环族烃基作为碱性结构的烃基，R 4和R 5可以相同或不同，并且 R 6表示碳原子数1〜10的烃基，和所述催化剂的α-烯烃的制造方法。

    Catalyst for olefinic hydrocarbon polymerization and process for producing olefinic hydrocarbon polymer
    7.
    发明公开
    Catalyst for olefinic hydrocarbon polymerization and process for producing olefinic hydrocarbon polymer 失效
    烯烃聚合催化剂和生产烯烃聚合物的方法

    公开(公告)号：EP0449583A3

    公开(公告)日：1992-04-08

    申请号：EP91302638.1

    申请日：1991-03-26

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Saba, Hayato ,  Yamamoto, Keisaku ,  Imai, Akio ,  Sugimori, Kiyoyuki ,  Wakatsuki, Kizuku

    IPC分类号： C08F10/00 ,  C08F4/68

    CPC分类号： C08F10/00 ,  C08F4/68

    摘要： An inert hydrocarbon catalyst is a mixture of 1 mol of (A) a reaction product obtained by reacting in an inert hydrocarbon solvent (a) 1 mol of at least one V compound VO(OR) m X 3-m wherein R is a hydrocarbon group, X a halogen atom and m a real number of from 0 to 3 (preferably 0), and (b) 0.5 to 1.4 mols of a dihydroxy hydrocarbon compound constituted of a C2-12 straight chain hydrocarbon skeleton having a hydroxyl group at each end terminal and at least one hydrocarbon branch bonded to said hydrocarbon skeleton, and 2 to 500 mols of (B) at least one organoaluminum compound represented by R′ n AℓX′ 3-n wherein R′ is a hydrocarbon group, X′ a halogen atom; and n a real number more than 0 and less than 3. The catalyst is dissolved in an aliphatic or alicyclic hydrocarbon solvent (e.g. hexane) to which is added an olefin (e.g. α-olefin alone or with ethylene and/or a polyene), to polymerise, at 0- 100°C under pressure of 5-50 kg/cm² to produce olefinic hydrocarbon polymers having narrow distributions of molecular weight and composition with high efficiency and high polymerization activity, without obstruction or contamination of equipment due to precipitation of catalyst.

    Modified diene polymer rubbers
    8.
    发明公开
    Modified diene polymer rubbers 失效
    改性二烯聚合物橡胶

    公开(公告)号：EP0334042A3

    公开(公告)日：1989-12-13

    申请号：EP89103120.5

    申请日：1989-02-23

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Imai, Akio ,  Seki, Tomoaki

    IPC分类号： C08C19/42

    CPC分类号： C08C19/42

    摘要： A process for preparing modified diene polymer rubbers having an increased impact resilience and a reduced hardness at low temperatures and useful as rubber materials for automobile tires and other industries which comprises producing an alkali metal-containing conjugated diene polymer, and reacting the alkali metal-containing polymer with a modifier selected from the group consisting of an acrylamide compound of the formula:
    wherein R¹ is hydrogen atom or methyl group, R² and R³ are independently an alkyl group and n is an integer, and an aminovinylsilane compound of the formula:
    wherein R⁴ to R⁸ are independently an alkyl group, said alkali metal-containing diene polymer being prepared by a living anionic polymerization using an alkali metal-based catalyst or by an addition reaction of a diene polymer having conjugated diene units and an alkali metal-based catalyst in a hydrocarbon solvent. The modified diene polymers can be incorporated with usual rubber additives and with or without other rubbers to provide rubber compositions for various purposes, and the cured products show an increased impact resilience and a reduced hardness at low temperatures.

    Modified diene polymer rubbers
    9.
    发明公开
    Modified diene polymer rubbers 失效
    Modifizierter Dienpolymerkautschuk。

    公开(公告)号：EP0290883A1

    公开(公告)日：1988-11-17

    申请号：EP88106872.0

    申请日：1988-04-29

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Takao, Hiroyoshi ,  Imai, Akio ,  Seki, Tomoaki

    IPC分类号： C08C19/42

    CPC分类号： C08C19/42

    摘要： A process for preparing modified diene polymer rubbers having an increased impact resilience and a reduced hardness at low temperatures and useful as rubber materials for automobile tires and other industries which comprises producing an alkali metal-containing conjugated diene polymer, and reacting the alkali metal-containing polymer with a modifier selected from the group consisting of a nitroalkyl acrylate of the formula:
    wherein R¹ and R² are independently an alkyl group and n is an integer, and a nitroamino compound of the formula:
    wherein R³ to R⁶ are independently an alkyl group, and m is an integer, said alkali metal-containing diene polymer being prepared by a living anionic polymerization using an alkali metal-based catalyst or by an addition reaction of a diene polymer having conjugated diene units and an alkali metal-based catalyst in a hydrocarbon solvent. The modified diene polymers can be incorporated with usual rubber additives to provide rubber compositions for various purposes, and the cured products show an increased impact resilience and a reduced hardness at low temperatures.

    摘要翻译： 一种制备改性二烯聚合物橡胶的方法，该改性二烯聚合物橡胶在低温下具有增加的冲击弹性和降低的硬度，并且可用作汽车轮胎和其它工业的橡胶材料，其包括制备含碱金属的共轭二烯聚合物，并使含碱金属的 聚合物与选自下式的硝基烷基丙烯酸酯的改性剂：其中R 1和R 2独立地是烷基，n是整数;和下式的硝基氨基化合物： CHEM>其中R 3至R 6独立地为烷基，m为整数，所述含碱金属的二烯聚合物通过使用碱金属类催化剂的活性阴离子聚合或通过加成反应制备 具有共轭二烯单元的二烯聚合物和在烃溶剂中的碱金属基催化剂。 改性二烯聚合物可以加入通常的橡胶添加剂以提供用于各种目的的橡胶组合物，并且固化产物在低温下表现出增加的冲击弹性和降低的硬度。

    Process for preparing modified diene polymer rubbers
    10.
    发明公开
    Process for preparing modified diene polymer rubbers 失效
    Verfahren zur Herstellung von modifizierten Kautschuk-Dienpolymeren。

    公开(公告)号：EP0270071A2

    公开(公告)日：1988-06-08

    申请号：EP87117741.6

    申请日：1987-12-01

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Takao, Hiroyoshi ,  Imai, Akio ,  Seki, Tomoaki ,  Tsuji, Mitsuji

    IPC分类号： C08C19/42

    CPC分类号： C08C19/42

    摘要： A process for preparing modified diene polymer rubbers having an increased impact resilience and a reduced hardness at low temperatures and useful as rubber materials for automobile tires and other industries which comprises producing an alkali metal-containing conjugated diene polymer, and reacting the alkali metal-containing polymer with a modifier selected from the group consisting of a nitro compound, a phosphoryl chloride compound of the formula:
    wherein R¹ to R⁴ are independently an alkyl group, and an aminosilane compound of the formula:
    wherein R⁵ to R⁷ are independently an alkyl group or an alkoxyl group, R⁸ and R⁹ are independently an alkyl group, and n is an integer,
    said alkali metal-containing diene polymer being prepared by a living anionic polymerization using an alkali metal-­based catalyst or by an addition reaction of a diene polymer having conjugated diene units and an alkali metal-based catalyst in a hydrocarbon solvent. The modified diene polymers can be incorporated with usual rubber additives to provide rubber compositions for various purposes, and the cured products show an increased impact resilience and a reduced hardness at low temperatures.

    摘要翻译： 一种制备改性二烯聚合物橡胶的方法，该改性二烯聚合物橡胶在低温下具有增加的冲击弹性和降低的硬度，并且可用作汽车轮胎和其它工业的橡胶材料，其包括制备含碱金属的共轭二烯聚合物，并使含碱金属的 聚合物与选自硝基化合物，下式的磷酰氯化合物：其中R 1至R 4独立地为烷基的下式的磷酰氯化合物和下式的氨基硅烷化合物： CHEM>其中R 5至R 7独立地为烷基或烷氧基，R 8和R 9独立地为烷基，n为整数，所述含碱金属的二烯聚合物 通过使用碱金属类催化剂的活性阴离子聚合或通过在烃溶剂中具有共轭二烯单元和碱金属类催化剂的二烯聚合物的加成反应制备。 改性二烯聚合物可以加入通常的橡胶添加剂以提供用于各种目的的橡胶组合物，并且固化产物在低温下表现出增加的冲击弹性和降低的硬度。