发明公开
EP0362852A2 Information-recording thin film and method for recording and reproducing information
失效
Informationsaufzeichnungsdünnschichtund Methode zur Aufnahme und Wiedergabe von Information。
- 专利标题: Information-recording thin film and method for recording and reproducing information
- 专利标题(中): Informationsaufzeichnungsdünnschichtund Methode zur Aufnahme und Wiedergabe von Information。
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申请号: EP89118519.1申请日: 1989-10-05
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公开(公告)号: EP0362852A2公开(公告)日: 1990-04-11
- 发明人: Tamura, Reiji Shihoryo, 1468-5 , Terao, Motoyasu , Miyauchi, Yasushi , Andoo, Keikichi , Nishida, Tetsuya
- 申请人: HITACHI, LTD. , Hitachi Maxell Ltd.
- 申请人地址: 6, Kanda Surugadai 4-chome Chiyoda-ku, Tokyo 101 JP
- 专利权人: HITACHI, LTD.,Hitachi Maxell Ltd.
- 当前专利权人: HITACHI, LTD.,Hitachi Maxell Ltd.
- 当前专利权人地址: 6, Kanda Surugadai 4-chome Chiyoda-ku, Tokyo 101 JP
- 代理机构: Patentanwälte Beetz - Timpe - Siegfried Schmitt-Fumian - Mayr
- 优先权: JP249890/88 19881005; JP306052/88 19881205
- 主分类号: G11B7/00
- IPC分类号: G11B7/00 ; G11B7/24
摘要:
An information recording thin film (21) capable of changing an atomic arrangement upon exposure to a recording beam, formed on a substrate (19) directly or through a protective layer (20) composed of at least one of inorganic materials and organic materials, an average composition in the film thickness direction of the information-recording thin film being represented by the following general formula:
Sn x Sb y Te z Se α A β B γ C δ
wherein x, y, z, α, β, γ and δ are in ranges of 3 ≦ x ≦ 50, 10 ≦ y ≦ 70, 10 ≦ z+α ≦ 87, 0.1 ≦ z/α ≦ 10, 0 ≦ β ≦ 20, 0 ≦ γ ≦ 30 and 0 ≦ δ ≦ 30 in atomic percentage, A is at least one element of Tl, halogen atoms and alkali metals, B is at least one element of Au, Ag, Cu, Pd, Ta, W, Ir, Sc, Y, Ti, Zr, V, Nb, Cr, Mo, Mn, Fe, Ru, Co, Rh and Ni, and C is at least one of other elements than Sn, Sb, Te, Se and those represented by A and B, or by the following general formula:
Sb x Te y A′ z B′ α C′ β D γ
wherein x y, z, α, β and γ are in ranges of 5 ≦ x ≦ 70, 10 ≦ y ≦ 85, 3 ≦ z ≦ 30, 0 ≦ α ≦ 20, 0 ≦ β ≦ 30, 0 ≦ γ ≦ 10, A′ is at least one element of Sn, Bi, Pb, Ga, Au and In, and B′ is at least one element of Tl, halogen atoms and alkali metals, C′ is at least one element of Ag, Cu, Pd, Ta, W, Ir, Sc, Y, Ti, Zr, V, Nb, Cr, Mo, Mn, Fe, Ru, Co, Rh and Ni, and D is at least one of other elements than Sb, Te and those represented by A′, B′, and C′, gives an information-recording member having good recording and reproducing characteristics with a good stability for a long time and capable of a large number of information rewriting.
Sn x Sb y Te z Se α A β B γ C δ
wherein x, y, z, α, β, γ and δ are in ranges of 3 ≦ x ≦ 50, 10 ≦ y ≦ 70, 10 ≦ z+α ≦ 87, 0.1 ≦ z/α ≦ 10, 0 ≦ β ≦ 20, 0 ≦ γ ≦ 30 and 0 ≦ δ ≦ 30 in atomic percentage, A is at least one element of Tl, halogen atoms and alkali metals, B is at least one element of Au, Ag, Cu, Pd, Ta, W, Ir, Sc, Y, Ti, Zr, V, Nb, Cr, Mo, Mn, Fe, Ru, Co, Rh and Ni, and C is at least one of other elements than Sn, Sb, Te, Se and those represented by A and B, or by the following general formula:
Sb x Te y A′ z B′ α C′ β D γ
wherein x y, z, α, β and γ are in ranges of 5 ≦ x ≦ 70, 10 ≦ y ≦ 85, 3 ≦ z ≦ 30, 0 ≦ α ≦ 20, 0 ≦ β ≦ 30, 0 ≦ γ ≦ 10, A′ is at least one element of Sn, Bi, Pb, Ga, Au and In, and B′ is at least one element of Tl, halogen atoms and alkali metals, C′ is at least one element of Ag, Cu, Pd, Ta, W, Ir, Sc, Y, Ti, Zr, V, Nb, Cr, Mo, Mn, Fe, Ru, Co, Rh and Ni, and D is at least one of other elements than Sb, Te and those represented by A′, B′, and C′, gives an information-recording member having good recording and reproducing characteristics with a good stability for a long time and capable of a large number of information rewriting.
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