发明公开
EP0371882A2 Abscisic acid-related plant growth regulators - germination promoters
失效
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- 专利标题: Abscisic acid-related plant growth regulators - germination promoters
- 专利标题(中): 。isine he he he。。。。。。。。。。。。。。。。
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申请号: EP89403331.5申请日: 1989-11-30
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公开(公告)号: EP0371882A2公开(公告)日: 1990-06-06
- 发明人: Abrams, Suzanne R. , Gusta, Lawrence V.
- 申请人: HER MAJESTY IN RIGHT OF CANADA AS REPRESENTED BY THE NATIONAL RESEARCH COUNCIL OF CANADA
- 申请人地址: Montreal Road Ottawa Ontario K1A 0R6 CA
- 专利权人: HER MAJESTY IN RIGHT OF CANADA AS REPRESENTED BY THE NATIONAL RESEARCH COUNCIL OF CANADA
- 当前专利权人: HER MAJESTY IN RIGHT OF CANADA AS REPRESENTED BY THE NATIONAL RESEARCH COUNCIL OF CANADA
- 当前专利权人地址: Montreal Road Ottawa Ontario K1A 0R6 CA
- 代理机构: Gutmann, Ernest
- 优先权: US280102 19881201
- 主分类号: C07C403/16
- IPC分类号: C07C403/16 ; C07C403/20 ; A01N49/00 ; C07D303/38
摘要:
Composition for enhancing germination and growth of plants which comprises an effective amount of at least one abscisic acid-related compound having the following formula (I):
wherein
R may be carboxyl aldehyde, hydroxy, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl, loweralkyl sulphinyl, amino, carbonyl halogen, thio, phosphate, sulfoxide, sulfone or deuterium;
R' may be hydrogen, oxo, hydroxyloweralkyl, loweralkoxy, halogen, thio, sulfoxide, sulfone, phosphate or deuterium;
R 2 may be hydrogen, oxo, hydroxy, halogen thio, phosphate, sulfoxide, sulfone or deuterium;
R 3 may be. carboxyl, aldehyde, loweralkyl, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl, loweralkyl sulphinyl, or carbonyl;
and when R 2 is oxo or thio, R 2 may be linked to both C 1 and C 2 carbon atoms to form an epoxy or a thioepoxy ring;
R 4 may be hydrogen, oxo, halogen, thio, phosphate, sulfoxide, sulfone, deuterium, hydroxy, loweralkylsiloxane, carboxyl, aldehyde, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl; loweralkyl suiphinyl, amino, carbonyl, cycloalkyl or cycloalkoxy having from 4 to 6 carbon atoms which is optionally substituted by loweralkyl, halogen, oxygen, hydroxy or loweralkoxy;
R 5 may be carboxyl, hydroxy, aldehyde, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, acetoxyloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl, loweralkyl sulphinyl, amino, carbonyl, halogen, hydrogen, oxo, thio, phosphate, sulfoxide, sulfone or deuterium, and when R 5 is oxo, it may be linked to the carbon atom bearing R 3 ;
R 6 may be hydrogen, oxo, hydroxyloweralkyl, loweralkoxy, halogen, thio, sulfoxide, sulfone, phosphate or deuterium;
R 7 may be carboxyl, hydroxy, aldehyde, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, acetoxyloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl, loweralkyl sulphinyl, amino, carbonyl, halogen, hydrogen, oxo, thio, phosphate, sulfoxide, sulfone or deuterium, and when R 7 is oxo, it may be linked to the carbon atom bearing R 3 ; and wherein
the dotted lines may each represent a single bond and the double dotted line represents either a double bond or a triple bond,
R 1 or R 6 is absent if the dotted line adjacent to R 1 and R 6 is a single bond, and isomers and functional derivatives thereof,
in admixture with an acceptable agricultural carrier comprising an agriculturally acceptable carrier cation when R, R 1 , R 2 , R 4 , R 5 , R 6 or R 7 are phosphate, sulfoxide or sulfone.
wherein
R may be carboxyl aldehyde, hydroxy, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl, loweralkyl sulphinyl, amino, carbonyl halogen, thio, phosphate, sulfoxide, sulfone or deuterium;
R' may be hydrogen, oxo, hydroxyloweralkyl, loweralkoxy, halogen, thio, sulfoxide, sulfone, phosphate or deuterium;
R 2 may be hydrogen, oxo, hydroxy, halogen thio, phosphate, sulfoxide, sulfone or deuterium;
R 3 may be. carboxyl, aldehyde, loweralkyl, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl, loweralkyl sulphinyl, or carbonyl;
and when R 2 is oxo or thio, R 2 may be linked to both C 1 and C 2 carbon atoms to form an epoxy or a thioepoxy ring;
R 4 may be hydrogen, oxo, halogen, thio, phosphate, sulfoxide, sulfone, deuterium, hydroxy, loweralkylsiloxane, carboxyl, aldehyde, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl; loweralkyl suiphinyl, amino, carbonyl, cycloalkyl or cycloalkoxy having from 4 to 6 carbon atoms which is optionally substituted by loweralkyl, halogen, oxygen, hydroxy or loweralkoxy;
R 5 may be carboxyl, hydroxy, aldehyde, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, acetoxyloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl, loweralkyl sulphinyl, amino, carbonyl, halogen, hydrogen, oxo, thio, phosphate, sulfoxide, sulfone or deuterium, and when R 5 is oxo, it may be linked to the carbon atom bearing R 3 ;
R 6 may be hydrogen, oxo, hydroxyloweralkyl, loweralkoxy, halogen, thio, sulfoxide, sulfone, phosphate or deuterium;
R 7 may be carboxyl, hydroxy, aldehyde, hydroxyloweralkyl, alkoxyloweralkyl, loweralkoxycarbonyl, loweracyloxyloweralkyl, acetylloweralkyl, acetoxyloweralkyl, loweralkanoyl, loweralkylamino, diloweralkylamino, loweralkoxy, loweracyloxy, loweralkylthio, loweralkyl sulphonyl, loweralkyl sulphinyl, amino, carbonyl, halogen, hydrogen, oxo, thio, phosphate, sulfoxide, sulfone or deuterium, and when R 7 is oxo, it may be linked to the carbon atom bearing R 3 ; and wherein
the dotted lines may each represent a single bond and the double dotted line represents either a double bond or a triple bond,
R 1 or R 6 is absent if the dotted line adjacent to R 1 and R 6 is a single bond, and isomers and functional derivatives thereof,
in admixture with an acceptable agricultural carrier comprising an agriculturally acceptable carrier cation when R, R 1 , R 2 , R 4 , R 5 , R 6 or R 7 are phosphate, sulfoxide or sulfone.
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